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The interaction of biofuel sprays from an outward opening hollow cone injector and the flow field inside an internal combustion engine is analyzed by Mie-Scattering Imaging (MSI) and high-speed stereoscopic particle-image velocimetry (stereo-PIV). Two fuels (ethanol and methyl ethyl ketone (MEK)), four injection pressures (50, 100, 150, and 200 bar), three starting points of injection (60°, 277°, and 297° atdc), and two engine speeds (1,500 rpm and 2,000 rpm) define the parameter space of the experiments. The MSI measurements determine the vertical penetration length and the spray cone angle of the ethanol and MEK spray. Stereo-PIV is used to investigate the interaction of the flow field and the ethanol spray after the injection process for a start of injection at 60° atdc. These measurements are compared to stereo-PIV measurements without fuel injection performed in the same engine [19].

Current progress in the development of diesel engines substantially contributes to the reduction of NOx and Particulate Matter (PM) emissions but will not succeed to eliminate the application of Diesel Particulate Filters (DPFs) in the future. In the past we have introduced a Multi-Functional Reactor (MFR) prototype, suitable for the abatement of the gaseous and PM emissions of the Low Temperature Combustion (LTC) engine operation. In this work the performance of MFR prototypes under both conventional and advanced combustion engine operating conditions is presented. The effect of the MFR on the fuel penalty associated to the filter regeneration is assessed via simulation. Special focus is placed on presenting the performance assessment in combination with the existing differences in the morphology and reactivity of the soot particles between the different modes of diesel engine operation (conventional and advanced). The effect of aging on the MFR performance is also presented.

Within the Cluster of Excellence “Tailor-Made Fuels from Biomass” (TMFB) at the RWTH Aachen University, two novel biogenic fuels, namely 1-octanol and its isomer dibutyl ether (DBE), were identified and extensively analyzed in respect of their suitability for combustion in a Diesel engine. Both biofuels feature very different properties, especially regarding their ignitability. In previous works of the research cluster, promising synthesis routes with excellent yields for both fuels were found, using lignocellulosic biomass as source material. Both fuels were investigated as pure components in optical and thermodynamic single cylinder engines (SCE). For 1-octanol at lower part load, almost no soot emission could be measured, while with DBE the soot emissions were only about a quarter of that with conventional Diesel fuel. At high part load (2400 min-1, 14.8 bar IMEP), the soot reduction of 1-octanol was more than 50% and for DBE more than 80 % respectively.

The optimization study presented herein is aimed to minimize the fuel consumption and engine-out emissions using commercially available EN15940 compatible HVO (Hydrogenated Vegetable Oil) fuel. The investigations were carried out on FEV’s 3rd generation HECS (High Efficiency Combustion System) multi-cylinder engine (1.6L, 4 Cylinder, Euro 6). Using a global DOE approach, the effects of calibration parameters on efficiency and emissions were obtained and analyzed. This was followed by a global optimization procedure to obtain a dedicated calibration for HVO. The study was aiming for efficiency improvement and it was found that at lower loads, higher fractions of low pressure EGR in combination with lower fuel injection pressures were favorable. At higher loads, a combustion center advancement, increase of injection pressure and reduced pilot injection quantities were possible without exceeding the noise and NOx levels of the baseline Diesel.

In order to thoroughly investigate and improve the path from biofuel production to combustion, the Cluster of Excellence “Tailor-Made Fuels from Biomass” was installed at RWTH Aachen University in 2007. Since then, a variety of fuel candidates have been investigated. In particular, 2-methyl tetrahydrofurane (2-MTHF) has shown excellent performance w.r.t. the particulate (PM) / NOx trade-off [1]. Unfortunately, the long ignition delay results in increased HC-, CO- and noise emissions. To overcome this problem, the addition of di-n-butylether (DNBE, CN ∼ 100) to 2-MTHF was analyzed. By blending these two in different volumetric shares, the effects of the different mixture formation and combustion characteristics, especially on the HC-, CO- and noise emissions, have been carefully analyzed. In addition, the overall emission performance has been compared to EN590 diesel.

In this study the fuel influence of several bio-fuel candidates on homogeneous engine combustion systems with direct injection is investigated. The results reveal Ethanol and 2-Butanol as the two most knock-resistant fuels. Hence these two fuels enable the highest efficiency improvements versus RON95 fuel ranging from 3.6% - 12.7% for Ethanol as a result of a compression ratio increase of 5 units. Tetrahydro-2-methylfuran has a worse knock resistance and a decreased thermal efficiency due to the required reduction in compression ratio by 1.5 units. The enleanment capability is similar among all fuels thus they pose no improvements for homogeneous lean burn combustion systems despite a significant reduction in NOX emissions for the alcohol fuels as a consequence of lower combustion temperatures.

The HSDI Diesel engine contributes substantially to the decrease of fleet fuel consumption thus to the reduction of CO2 emissions. This results in the rising market acceptance which is supported by desirable driving performance as well as greatly improved NVH behavior. In addition to the above mentioned requirements on driving performance, fuel economy and NVH behavior, continuously increasing demands on emissions performance have to be met. From today's view the Diesel particulate trap presents a safe technology to achieve the required reduction of the particle emission of more than 95%. However, according to today's knowledge a further, substantial NOx engine-out emission reduction for the Diesel engine is counteracts with the other goal of reduced fuel consumption. To comply with current and future emission standards, Diesel engines will require DeNOx technologies.

Representative Interactive Flamelets (RIF) have proven successful in predicting Diesel engine combustion. The RIF concept is based on the assumption that chemistry is fast compared to the smallest turbulent time scales, associated with the turnover time of a Kolmogorov eddy. The assumption of fast chemistry may become questionable with respect to the prediction of pollutant formation; the formation of NOx, for example, is a rather slow process. For this reason, three different approaches to account for NOx emissions within the flamelet approach are presented and discussed in this study. This includes taking the pollutant mass fractions directly from the flamelet equations, a technique based on a three-dimensional transport equation as well as the extended Zeldovich mechanism. Combustion and pollutant emissions in a Common-Rail DI Diesel engine are numerically investigated using the RIF concept. Special emphasis is put on NOx emissions.

The future worldwide emission regulations will request a drastic decrease of Diesel engine tailpipe emissions. Depending on the planned application and the real official regulations, a further strong decrease of engine out emissions is necessary, even though the utilized exhaust after-treatment systems are very powerful. To reduce NOx emissions internally, the external exhaust gas recirculation (EGR) is known as the most effective way. Due to the continuously increasing requirements regarding specific power, dynamic behavior and low emissions, future air path systems have to fulfill higher requirements and, consequently, become more and more complex, e.g. arrangements with a 2-stage turbo charging or 2-stage EGR system with different stages of cooling performance.

In Common-Rail DI Diesel Engines, a low combustion temperature process is considered as one of the most important possibilities to achieve very small emissions and optimum performance. To reduce NOx and Soot strongly, it is necessary to achieve a homogenization of the mixture in order to avoid the higher local temperatures which are responsible for the NOx formation [1]. Through the homogenization it is also possible to obtain a stoichiometric air-fuel ratio in order to significantly reduce the Soot emissions. One way to achieve this homogeneous condition is to start injection very early together with the use of higher EGR rates. The direct effect of these conditions cause a longer ignition delay (this is the time between start of the injection and auto-ignition during physical and chemical sub processes such as fuel atomization, evaporation, fuel air mixing and chemical pre-reactions take place) so that the mixture formation has more time to achieve a homogeneous state.

Increased demand for highly fuel efficient propulsion systems drives the engine development community to develop advanced technologies allowing improving the overall thermal efficiency while maintaining low emission levels. In addition to improving the thermal efficiencies of the internal combustion engine itself the developments of fuels that allow improved combustion as well as lower the emissions footprint has intensified recently. This paper will describe the effects of five different fuel types with significantly differing fuel properties on a state-of-the-art light-duty HSDI diesel engine. The fuels cetane number ranges between 26 and 76. These fuels feature significantly differing boiling characteristics as well as heating values. The fuel selection also contains one pure biodiesel (SME - Soy Methyl Ester). This study was conducted in part load and full load operating points using a state of the art HSDI diesel engine.

Recently, fuels containing ethanol have become more and more important for spark ignition engines. Fuels with up to 10 vol.-% ethanol can be used in most spark ignition engines without technical modification. These fuels have been introduced in many countries already. Alternatively, for fuels with higher amounts of ethanol so called flex fuel vehicles (FFV) exist. One of the most important quantities characterizing a fuel is the laminar burning velocity. To account for the new fuels with respect to engine design, reliable data need to be existent. Especially for engine simulations, various combustion models have been introduced which rely on the laminar burning velocity as the physical quantity describing the progress of chemical reactions, diffusion, and heat conduction. However, there is very few data available in the literature for fuels containing ethanol, especially at high pressures.

A broad range of diesel, kerosene, and gasoline-like fuels has been tested in a single-cylinder diesel engine optimized for advanced combustion performance. These fuels were selected in order to better understand the effects of ignition quality, volatility, and molecular composition on engine-out emissions, performance, and noise levels. Low-level biofuel blends, both biodiesel (FAME) and ethanol, were included in the fuel set in order to test for short-term advantages or disadvantages. The diesel engine optimized in Part 1 of this study included cumulative engine hardware enhancements that are likely to be used to meet Euro 6 emissions limits and beyond, in part by operating under conditions of Homogeneous Charge Compression Ignition (HCCI), at least over some portions of the speed and load map.

Fuels containing oxygenates have become more and more important for spark ignition engines in recent years. Oxygenates are either used as an octane booster or as a biofuel component for fulfilling legislative regulations. Ethanol has been well established for blend rates up to 10%volliq. On the other hand butanol has been introduced as an alternative biofuel component. The effect of the laminar burning velocity of different fuel components on modern engine development is investigated by conducting experiments under high initial pressure and temperature. Initial conditions in this work are a pressure of p = 10 bar and a temperature of T = 373 K. Experiments were done at different fuel - air ratios between 0.8 and 1.3. Test fuels were the pure fuel components iso-octane, ethanol and n-butanol. Different chemical kinetic mechanisms for iso-octane, ethanol and n-butanol from literature are used to calculate laminar burning velocities.

Fuels derived from biomass will most likely contain oxygen due to the high amount of hydrogen needed to remove oxygen in the production process. Today, alcohol fuels (e. g. ethanol) are well understood for spark ignition engines. The Institute for Combustion Engines at RWTH Aachen University carried out a fuel investigation program to explore the potential of alcohol fuels as candidates for future compression ignition engines to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. The soot formation and oxidation process when using alcohol fuels in diesel engines is not yet sufficiently understood. Depending on the chain length, alcohol fuels vary in cetane number and boiling temperature. Decanol possesses a diesel-like cetane number and a boiling point in the range of the diesel boiling curve. Thus, decanol was selected as an alcohol representative to investigate the influence of the oxygen content of an alcohol on the combustion performance.

Oxygenates, such as methanol or ethanol, are frequently used as blending components in standard gasoline. One oxygenate, dimethyl ether (DME), is also used as a fuel component in some regions of the world, for example in Asia. In addition, patent reviews show the potential of DME as a blending component in liquefied petroleum gas (LPG) or mixed with propane. The laminar burning velocity is one key parameter for the numerical simulation of gasoline engine combustion processes. Therefore, it is of great interest for modern engine development to understand the effect of oxygenates on the laminar burning velocity. The experimental results have been conducted under engine-like conditions with elevated initial pressures of up to 20 bar and initial temperatures of 373 K. Experiments were done at equivalence ratios between 0.8 and 1.3. The experimental setup consists of a spherical closed pressurized combustion vessel with optical access.

One fundamental subprocess for the utilization of alternative fuels for automotive applications is the in-cylinder mixture formation and therefore the fuel injection, which largely affects the combustion efficiency of internal combustion engines. This study analyzes the influence of the physical properties of various model-fuels on atomization and spray propagation at temperatures and pressures matching the operating conditions of today's gasoline engines. The experiments were carried out using an outwardly opening, piezo-driven gasoline injector. In order to cover a wide range of potential fuels the following liquids were investigated: Alcohols (Ethanol, Butanol and Decanol), alkanes (Iso-Octane, Dodecane and Heptane) and one furane (Tetrahydrofurfuryl Alcohol). The macroscopic spray propagation of the fuels was investigated using shadowgraphy. For complementary spray characterization droplet sizes and velocities were measured using Phase-Doppler Anemometry.

Within the Cluster of Excellence “Tailor-Made Fuels from Biomass” at RWTH Aachen University, the Institute for Combustion Engines carried out an investigation program to explore the potential of future biofuel components in Diesel blends. In this paper, thermodynamic single cylinder engine results of today's and future biofuel components are presented with respect to their engine-out emissions and engine efficiency. The investigations were divided into two phases: In the first phase, investigations were performed with rapeseed oil methyl ester (B100) and an Ethanol-Gasoline blend (E85). In order to analyze the impact of different fuel blends, mixtures with 10 vol-% of B100 or E85 and 90 vol-% of standardized EN590 Diesel were investigated. Due to the low cetane number of E85, it cannot be used purely in a Diesel engine.

A reduced kinetic reaction mechanism for the autoignition of dimethyl ether is presented in this paper. Dimethyl ether has proven to be one of the most attractive alternatives to traditional fossil fuels for compression ignition engines. It can either be produced from biomass or from fossil oil. For dimethyl ether, Fischer et al. (Int. J.Chem. Kinet. 32 ( 12 ) (2000) 713-740) proposed a detailed reaction mechanism consisting of 79 species and 351 elementary reactions. In the present work, this detailed mechanism is systematically reduced to 31 species and 49 reactions. The reduced mechanism is discussed in detail with special emphasis on the high temperature thermal decomposition of dimethyl ether and on the fuel specific depleting reactions, which produce the methoxymethyl radical. In addition, a reaction pathway analysis for low temperature combustion is applied, where hydroperoxy-methylformate is found to be the dominating parameter for the low temperature regime.

The European research co-operation Lotus is presented. The main objectives of the project were i) to show the potential for a urea-based SCR system to comply with the EU standard of years 2005 and 2008 for heavy-duty Diesel engines for different driving conditions with optimal fuel consumption, ii) to reach 95 % conversion of NOx at steady state at full load on a Euro III engine, iii) to reach 75 % NOx reduction for exhaust temperatures between 200-300°C, and 85 % average NOx reduction between 200-500°C. The energy content of the consumed urea should not exceed 1.0 %, calculated as specific fuel consumption. These targets were met in May 2003 and the Lotus SCR system fulfilled the Euro V NOx legislative objectives for year 2008.