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Due to the stringent requirements to reduce the tail pipe emissions of NOx, Selective Catalytic Reduction (SCR) systems are used to remove NOx using ammonia. When a urea solution is injected into the exhaust system, urea will undergo hydrolysis and decomposition reaction that produces ammonia. At the catalyst surface, ammonia will react with the exhaust gases to convert NOx into nitrogen, N2 and water, H2O. One of the challenging problems is to make sure the urea solution is available for the SCR system at cold start conditions. At extreme cold temperatures, the urea solution will begin to freeze at −12°C. At the start up of a vehicle under such low ambient temperatures, a heating system is used to provide the heat required for melting the frozen urea. Therefore, there will be a time lag between the vehicle start up and the availability of urea solution to the SCR system.

Due to raising interest in diesel powered passenger cars in the U.S. in combination with a desire to reduce dependency on imported petroleum, there has been increased attention to the operation of diesel vehicles on fuels blended with biodiesel. One of several factors to be considered when operating a vehicle on biodiesel blends is understanding the impact and performance of the fuel on the emission control system. This paper documents the impact of the biodiesel blends on engine-out emissions as well as the overall system performance in terms of emission control system calibration and the overall system efficiency. The testing platform is a light-duty HSDI diesel engine with a Euro 4 base calibration in a 1700 kg sedan vehicle. It employs 2nd generation common-rail injection system with peak pressure of 1600 bar as well as cooled high-pressure EGR. The study includes 3 different fuels (U.S.

Tier 4 emissions legislation is emerging as a clear pre-cursor for widespread adoption of exhaust aftertreatment in off-highway applications. Large bore engine manufacturers are faced with the significant challenge of packaging a multitude of catalyst technologies in essentially the same design envelope as their pre-Tier 4 manifestations, while contending with the fuel consumption consequences of the increased back pressure, as well as the incremental cost and weight associated with the aftertreatment equipment. This paper discusses the use of robust metallic catalysts upstream of the exhaust gas turbine, as an effective means to reduce catalyst volume and hence the weight and cost of the entire aftertreatment package. The primarily steady-state operation of many large bore engine applications reduces the complication of overcoming pre-turbine catalyst thermal inertia under transient operation.

When considered along with Phase 2 Greenhouse Gas (GHG) requirements, the proposed Air Resource Board (ARB) nitrogen oxide (NOx) emission limit of 0.02 g/bhp-hr will be very challenging to achieve as the trade-off between fuel consumption and NOx emissions is not favorable. To meet any future ultra-low NOx emission regulation, the NOx conversion efficiency during the cold start of the emission test cycles needs to be improved. In such a scenario, apart from changes in aftertreatment layout and formulation, additional heating measures will be required. In this article, a physics-based model for an advanced aftertreatment system comprising of a diesel oxidation catalyst (DOC), an SCR-catalyzed diesel particulate filter (SDPF), a stand-alone selective catalytic reduction (SCR), and an ammonia slip catalyst (ASC) was calibrated against experimental data.

The European research co-operation Lotus is presented. The main objectives of the project were i) to show the potential for a urea-based SCR system to comply with the EU standard of years 2005 and 2008 for heavy-duty Diesel engines for different driving conditions with optimal fuel consumption, ii) to reach 95 % conversion of NOx at steady state at full load on a Euro III engine, iii) to reach 75 % NOx reduction for exhaust temperatures between 200-300°C, and 85 % average NOx reduction between 200-500°C. The energy content of the consumed urea should not exceed 1.0 %, calculated as specific fuel consumption. These targets were met in May 2003 and the Lotus SCR system fulfilled the Euro V NOx legislative objectives for year 2008.