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The most significant operation limit prohibiting the further reduction of the CO2 emissions of gasoline engines is the occurrence of knock. Thus, being able to predict the incidence of this phenomenon is of vital importance for the engine process simulation - a tool widely used in the engine development. Common knock models in the 0D/1D simulation are based on the calculation of a pre-reaction state of the unburnt mixture (also called knock integral), which is a simplified approach for modeling the progress of the chemical reactions in the end gas where knock occurs. Simulations of thousands of knocking single working cycles with a model representing the Entrainment model’s unburnt zone were performed using a detailed chemical reaction mechanism. The investigations showed that, at specific boundary conditions, the auto-ignition of the unburnt mixture resulting in knock happens in two stages.