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A highly anti-corrosive organic-inorganic hybrid paint for automotive steel parts has been developed. The inorganic component included in the paint is silicon dioxide (SiO2), which has the capability to passivate zinc. By application of the paint on a trivalent chromatetreated zinc-plated steel sheet or a trivalent chromate-treated zinc-nickel-plated steel sheet, high anti-corrosion protection can be provided to steel materials. Particularly in the case of application over a zinc-nickel-plated steel sheet, 0 mm corrosion depth after a cyclic corrosion test (CCT) of 450 cycles was demonstrated.

This paper describes the development of a fracture finite element (FE) model for laser screw welding (LSW) and validation of the model with experimental results. LSW was developed and introduced to production vehicles by Toyota Motor Corporation in 2013. LSW offers superb advantages such as increased productivity and short pitch welding. Although the authors had previously developed fracture FE models for conventional resistance spot welding (RSW), a fracture model for LSW has not been developed. To develop this fracture model, many comprehensive experiments were conducted. The results revealed that LSW had twice as many variations in fracture modes compared to RSW. Moreover, fracture mode bifurcations were also found to result from differences in clearance between welded plates. In order to analyze LSW fracture phenomena, detailed FE models using fine hexahedral elements were developed.

The development of an alternative oxygen reduction electrocatalyst to platinum based electrocatalysts is critical for practical use of the polymer electrolyte membrane fuel cell (PEMFC). Transition metal sulfide chalcogenides have recently been reported as a possible candidate for Pt replacement. Our work focused on chalcogenides composed of ruthenium, molybdenum, and sulfur (RuMoS). We elucidate the factors affecting electrocatalytic activity of carbon supported RuXMoY SZ catalyst. This was demonstrated through a correlation of oxygen reduction reaction (ORR) activity of the catalysts with structural changes resulting from designed changes in sulfur composition in the catalysts.

This paper describes the development of a simplified fracture finite element (FE) model for resistance spot welds (RSW) of ultra-high-strength steel (UHSS) that can be incorporated into large-scale vehicle FE model. It is known that the RSW of UHSS generates two types of fracture modes: heat-affected zone (HAZ) and nugget zone fractures. Lap shear and peeling coupon tests using UHSS sheets found that the different RSW fracture modes occurred at different nugget diameters. To analyze this phenomenon, detailed simulated coupon tests were carried out using solid hexahedral elements. The analytical results revealed that RSW fractures are defined by both the application of plastic strain on the elements and the stress triaxiality state of the elements. A detailed model incorporating a new fracture criteria model recreated the different UHSS RSW fracture modes and achieved a close correlation with the coupon test results.

This article proposes a rubber suspension bushing model considering amplitude dependence as a useful tool at the initial design phase. The purpose of this study is not to express physical phenomena accurately and in detail and to explore the truth academically, but to provide a useful design method for initial design phase. Experiments were carried out to verify several dynamic characteristics of rubber bushings under vibration up to a frequency of 100 Hz, which is an important frequency range when designing ride comfort performance. When dynamic characteristic theory and the geometrical properties of the force-displacement characteristic curve were considered using these dynamic characteristics as assumptions, an equation was derived that is capable of calculating the dynamic stiffness under an arbitrary amplitude by identifying only two general design parameters (dynamic stiffness and loss factor) under a reference amplitude.

Silver metallic colors with thin and smooth aluminum flake pigments have been introduced for luxury brand OEMs. Regarding the paint formulation for these types of colors, low non-volatile(NV) and high aluminum flake pigment contents are known as technology for high metallic appearance designs. However, there are two technical concerns. First is mottling which is caused by uneven distribution of the aluminum flake pigments in paint film and second is poor film property due to high aluminum pigment concentration in paint film. Therefore, current paint systems have limitation of paint design. As a countermeasure for those two concerns, we had investigated cellulose nanofiber (CNF) dispersion liquid as both the coating binder and rheology control agent in a new type of waterborne paint system. CNF is an effective rheology control agent because it has strong hydrogen bonds with other fiber surfaces in waterborne paint.

A technique for induction-hardening local portions of vehicle body reinforcements press-formed of thin sheet steel has been developed, with the aim of ensuring occupant safety in a side collision. This technique for increasing the tensile strength of sheet steel was practically applied to the front floor cross member and center pillar reinforcement. Owing to this method, the weight of body reinforcements can be decreased. New induction-hardening systems have also been developed for the present technique. One is an apparatus which allows induction-hardening a part with a three-dimensionally curved surface. Another is a straightening quench technique used to retain the same dimensional accuracy as the original press-formed part.

1 The principal characteristics required of sealing materials used in the body shop have focused on their adhesion to oily steel sheets and quick curing performance. Means for attaining these characteristics have been narrowed down to a basic resin system and a curing system. Various techniques have been studied to ensure proper anti-corrosion performance at the sealer application boundaries and thin application areas. They include the addition of anti-corrosion fillers, the provision of conductivity (through electro-deposition), and the application of a micro foam film over the application boundaries. Thus, prospects for attaining the same level of anti-corrosion performance as existing materials have been achieved.

This paper describes development of a numerical simulation method for the FMVSS 201 testing. This method considers not only deformation but also fracture of plastic materials. a simplified calculation method for predicting the load during impact of absorbing plastic materials was introduced from the numerical simulation results. By applying this simplified calculator method trial and error in development would be reduced.

Through a polymer design and precise morphology control, The Super Olefin Polymer, TSOP-1 and TSOP-5 were developed for the material consolidation of interior and exterior parts, respectively. Due to a good balance of TSOP performance, several conventional materials were consolidated into one material for each application. Accordingly, considerable amounts of weight reduction and cost savings have been obtained. In addition to the excellent recyclability of TSOP, the coated bumpers collected from the market were re-utilized through paint decomposition technology. The first dashboard construction, molded partially with foam-padded skin, was also realized. The current amount of TSOP used in a vehicle is about 30% of the total amount of plastic materials. Through the usage of TSOP, 70% of the material consolidation has been achieved.

We studied the use of Bio-plastics (plastics made from plants) such as poly(lactic acid) (PLA) to automotive parts. To apply this material to automotive plastic parts, improvement in heat and impact performance is required. From the viewpoint of suppressing the increase in CO2 emissions, we attempted to improve the performance of PLA by combining with natural fiber. As the result, we could improve both heat and impact performance. In addition, we could achieve higher modulus and lower bulk density, which leads to the weight reduction of automotive parts.

We studied the application of Bio-plastics (plastics made from plants) such as poly(lactic acid) (PLA) to automotive parts. To apply this material to automotive plastic parts, major improvement is required for thermal and impact performance. From the viewpoint of suppressing the increase CO2 emissions, we attempt to improve the performance of PLA by combining with natural fiber. As the result, we could improve both thermal and impact performance. In addition, we could achieve higher modulus and lower bulk density, which lead to the weight reduction of automotive parts.

A new material recycling technology for crosslinked rubber was developed using the continuous reactive processing method. In this process of producing reclaimed rubber, breakage of crosslinking points in the crosslinked rubber occurs selectively under the controls of shear stress, reaction temperature, and internal pressure in a modular screw type reactor. Deodorization during the process has also become possible by a newly developed method. The reclaimed rubber obtained from rubber waste generated from both automobile manufacturing products and post-consumer products shows excellent mechanical properties applicable to new rubber compounds. Furthermore, an enhanced rubber recycling process for producing thermoplastic elastomer (TPE) based on rubber waste has been established. The obtained TPE exhibits highly recoverable rubber elasticity and mechanical properties comparable to commercial TPE.

Toyota is implementing various technical developments in various fields for protection of environment. Reducing the fuel consumption is a matter of great urgency for the reduction of CO2 emissions. In the technology of vehicle body development, mass reduction and the improvement of aerodynamics are mainly important for fuel economy. As the one of way for this, we adopted resin glass as the back door glass of ES3, small-sized low-fuel consumption vehicle. (Figure 1,2,3) The first advantage of resin glass is the low density that weights about a half of inorganic glass. However resin glass is needed higher thickness for equivalent rigidity, as the result approximately 41% mass reduction was achieved. However resin glass is relatively expensive. Therefore it seems to be difficult to expand the usage of resin for this application. Then, we focused on additional advantage of resin glass, in order to make good use of resin glass. The second advantage of resin glass is design flexibility.

Galvannealed steel sheet (GA) is very extensively used for vehicle panels. However ζ-phase (FeZn13) in GA coat causes poor stamping formability. Previously, there were no easy methods to evaluate the influence of ζ-phase on the frictional characteristics other than the X-ray diffraction method. This study will discuss the development of a new testing method: Dr. STAMP Method that is both efficient and convenient with pin-on-disc tester.

From the viewpoint of measures for environmental issues, the amount of solvents in paint for aluminum wheels needs to be minimized. Environmentally friendly powder coatings have been used widely for primer coating and clear coating, but there is no precedent for its use for base coating. This time, we optimized the condition of surface treatment of pigment and hardening behavior of constituent resin in the melting process and succeeded in developing a metallic powder coating for aluminum wheels that fulfills the appearance and the quality requirements of aluminum wheels.

Underbody coating is used to prevent chipping damage of the automobile underbody and wheel well. Multi-functional material that gives sound insulating properties is called sound insulating underbody coating. This paper describes the development of underbody coating material with powdered acrylic composition as an alternative to polyvinyl chloride resin. The new material also has better foaming properties. It is possible to ensure excellent sound insulating performance with thin film. This multi-functional underbody coating is the first application in the world with weight reduction and cost saving, and in a more environmentally acceptable manner.

Thermoplastic polyurethane (TPU) Powder Slush material for automotive interior parts, like instrument panels and door trim was developed as an alternative material for polyvinyl chloride (PVC) Powder Slush. Generally, TPU has poor anti-alcohol performance. However this performance has to be improved for automotive interior parts because the common cleaner solvent for interior parts usually contains some type of alcohol. Through our study of various TPU formulas, sufficient anti-alcohol performance was achieved by introducing aromatic polyol. Due to negative effects of aromatic polyol for low temperature and melting properties, additional study for plasticizer was essential. These properties are important for air bag deployment performance and moldability of powder slush. In order to solve these problems, various types and amounts of plasticizer were studied. Benzoic ester produced the best balance between compatibility with urethane polymer and anti-fogging performance.

Plastic materials are used for fuel tanks for automobiles because they are lightweight and highly durable and help these tanks ensure a capacity. However, plastic fuel tanks have the disadvantage of easily allowing the fuel to permeate through. To solve this problem, HDPE is used nowadays as the main material, and fuel tanks using EVOH for a barrier material and formed by multi-layer blowing are installed in the majority of automobiles conforming to the Tier 1 regulations set by EPA and the LEV I regulations set by CARB. In view of EPA's Tier 2 regulations and CARB's LEV II regulations, both of which will be launched in the near future, plastic fuel tanks with a lower level of fuel vapor permeability (hereinafter referred to as “permeability”) are desired. We thus developed a plastic fuel tank that is much lower than conventional plastic fuel tanks in permeability. This low-permeation plastic fuel tank may easily conform to the Tier 2 and LEV II regulations.

We studied the adoption of plastics derived from plants (bioplastics) such as poly(lactic acid) (PLA) for automotive parts in order to contribute to suppressing the increase in CO, emissions. For this application. major improvements of heat and impact resistance are needed. As a method to improve heat resistance, we developed PLA combined with clay of high heat resistance. As a result. we succeeded in synthesizing a PLA-clay nanocomposite using 18(OH)2-Mont. In-mold crystallization of PLA-clay nanocomposite lead to the great suppression of storage modulus decrease at high temperature. which in turn improved the heat resistance of PLA.