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In this paper, a three-dimensional (3D) microstructure-based finite element modeling method (i.e., extrinsic modeling method) is developed, which can be used in examining the effects of porosity on the ductility/fracture of Mg castings. For this purpose, AM60 Mg tensile samples were generated under high-pressure die-casting in a specially-designed mold. Before the tensile test, the samples were CT-scanned to obtain the pore distributions within the samples. 3D microstructure-based finite element models were then developed based on the obtained actual pore distributions of the gauge area. The input properties for the matrix material were determined by fitting the simulation result to the experimental result of a selected sample, and then used for all the other samples’ simulation. The results show that the ductility and fracture locations predicted from simulations agree well with the experimental results.

Although the urea-SCR technology exhibits high NO reduction efficiency over a wide range of temperatures among the lean NO reduction technologies, further improvement in low-temperature performance is required to meet the future emission standards and to lower the system cost. In order to improve the catalyst technologies and optimize the system performance, it is critical to understand the reaction mechanisms and catalyst behaviors with respect to operating conditions. Urea-SCR catalysts exhibit poor NO reduction performance at low-temperature operating conditions (T ≺ 150°C). We postulate that the poor performance is either due to NH₃ storage inhibition by species like hydrocarbons or due to competitive adsorption between NH₃ and other adsorbates such as H₂O and hydrocarbons in the exhaust stream. In this paper we attempt to develop one-dimensional models to characterize inhibition and competitive adsorption in Fe-zeolite-based urea-SCR catalysts based on bench reactor experiments.

More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number-based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample-handling methods have been implemented in an engine test cell with a spark-ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion.

Thermally-sprayed, composite coatings have been developed and sprayed on aluminum engine heads to replace powdered metal valve seat inserts. The process uses a conventional two-wire arc (TWA) gun with nickel and iron-based wire feedstocks. A unique surface preparation technique was developed to assure excellent coating adhesion. A composite Fe/Fe3O4/Ni/NiO/CrO coating was dynamometer tested using a single-cylinder Rotax engine, and showed improved wear performance over a conventional powdered-metal insert. Details of surface preparation, coating development, tribological properties and engine testing are described in this work.

The effect of hydroforming on the mechanical properties and dynamic crush behaviors of tapered aluminum 6063-T4 tubes with octagonal cross section are investigated by experiments. First, the thickness profile of the hydroformed tube is measured by non-destructive examination technique using ultrasonic thickness gauge. The effect of hydroforming on the mechanical properties of the tube is investigated by quasi-static tensile tests of specimens prepared from different regions of the tube based on the thickness profile. The effect of hydroforming on the dynamic crush behaviors of the tube is investigated by axial crush tests under dynamic loads. Specimens and tubes are tested in two different heat treatment conditions: hydroformed-T4 (as-received) and T6. The results of the quasi-static tensile tests for the specimens in hydroformed-T4 condition show different amounts of work hardening depending on the regions, which the specimens are prepared from.

New techniques have been developed to visualize soot deposition in both traditional and new diesel particulate filter (DPF) substrate materials using a modified cyanoacrylate fuming technique. Loading experiments have been conducted on a variety of single channel DPF substrates to develop a deeper understanding of soot penetration, soot deposition characteristics, and to confirm modeling results. Early results indicate that stabilizing the soot layer using a vaporized adhesive (Cynoacrylate) may allow analysis of the layer with new methods.

This paper describes the application of pore-scale filtration simulations to the advanced ceramic material (ACM) developed for use in advanced diesel particulate filters. The application required the generation of a three-dimensional substrate geometry to provide the boundary conditions for the flow model. An innovative stochastic modeling technique was applied matching chord length distribution and the porosity profile of the material. Additional experimental validation was provided by the single-channel experimental apparatus. Results show that the stochastic reconstruction techniques provide flexibility and appropriate accuracy for the modeling efforts. Early investigation efforts imply that needle length may provide a mechanism for adjusting performance of the ACM for diesel particulate filter (DPF) applications. New techniques have been developed to visualize soot deposition in both traditional and new DPF substrate materials.

This paper describes the reduction of cyclic combustion variations in spark-ignited engines, especially under idle conditions in which the air-fuel mixture is lean of stoichiometry. Under such conditions, the combination of residual cylinder gas and parametric variations (such as variations in fuel preparation) gives rise to significant combustion instabilities that may lead to customer-perceived engine roughness and transient emissions spikes. Such combustion instabilities may preclude operation at air-fuel ratios that would otherwise be advantageous for fuel economy and emissions. This approach exploits the recognition that a component of the observed combustion instability results from a noise-driven, nonlinear deterministic mechanism that can be actively stabilized by small feedback control actions which result in little if any additional use of fuel.

In this paper, the formability of AA5754 aluminum laser-welded blanks produced by Nd:YAG laser welding is investigated under biaxial straining conditions. The mechanical behavior of the laser-welded blanks is first examined by uniaxial tensile tests conducted with the weld line perpendicular to the tensile axis. Shear failure in the weld metal is observed in the experiments. Finite element simulations under generalized plane strain conditions are then conducted in order to further understand the effects of weld geometry and strength on the shear failure and formability of these welded blanks. The strain histories of the material elements in the weld metal obtained from finite element computations are finally used in a theoretical failure analysis based on the material imperfection approach to predict the failure strains for the laser-welded blanks under biaxial straining conditions.

Environmental concerns have prompted increasingly stringent government legislation regulating automotive fuel economy and emissions. Recent rules not only mandate lower total emissions, but also require on-board diagnostics which monitor the vehicle exhaust systems. In order to satisfy these requirements, new and improved exhaust gas sensors are continually being developed to serve as part of the engine feedback control and emissions monitoring systems. Before we can properly design these new sensors, we must attempt to better understand the harsh environment in which they will operate. In this paper, we examine the high frequency nature of pressure fluctuations found in the exhaust system for both steady state and transient engine operating conditions. We also investigate temperature fluctuations, but restrict these measurements to the sampling environment found in the packaging of a Ford Si-based microcalorimeter.

Brønsted acidity of solution ion-exchanged and solid-state exchanged zeolites was compared for NaY, BaY, CaY, NaX, and CaX zeolites. These materials were chosen because they all exhibit catalytic activity in SCR of NOx in combination with a non-thermal plasma. Brønsted acidity was characterized qualitatively with retinol as an indicator dye. Our results show that the solid-state exchange using a chloride salt creates zeolites with lower acidity than zeolites obtained by conventional solution ion-exchange. NO2 adsorption was also found to create a significant quantity of acid sites at room temperature and a slight increase in acidity at 200°C. We speculate that the acid sites created by NO2 adsorption, because of their vicinity to metal cation sites in the zeolite, may lead to preferential reactions that lead to NOx reduction. BaY made by solution ion-exchange and BaY made by solid-state exchange using a chloride salt were tested for NOx reduction in a plasma-catalyst reactor system.

Ford Motor Company is participating in the Department of Energy's (DOE) Ultra-Clean Transportation Fuels Program with the goal to explore the development of innovative emission control systems for advanced compression-ignition direct-injection (CIDI) transportation engines. CIDI (or diesel) engines have the advantages of a potential 40% fuel economy improvement and 20% less CO2 emissions than current gasoline counterparts. To support this goal, Ford plans to demonstrate an exhaust emission control system that provides high efficiency particulate matter (PM) and NOx reduction. Very low sulfur diesel fuel will be used to enable low PM emissions, reduce the fuel economy penalty associated with the emission control system, and increase the long-term durability of the system. The end result will allow vehicles with CIDI engines to be Tier II emissions certified at a minimum cost to the consumer.

This paper presents two methods of characterizing and describing the formability of tailor welded blanks (TWB). The first method involves using miniature tensile specimens, extracted from TWB weld material, to quantify mechanical properties and material imperfection within TWB welds. This technique combines statistical methods of describing material imperfection together with conventional M-K method modeling techniques to determine safe forming limit diagrams for weld material. The second method involves the use of an extended M-K method modeling technique, which places multiple material thickness and material imperfections inside one overall model of TWB performance. These methods of describing TWB formability and their application to specific aluminum TWB populations are described.

Diesel vehicles have significant advantages over their gasoline counterparts including a more efficient engine, higher fuel economy, and lower emissions of HC, CO, and CO2. However, NOx control is more difficult on a diesel because of the high O2 concentration in the exhaust, making conventional three-way catalysts ineffective. The most promising technology for continuous NOx reduction onboard diesel vehicles is Selective Catalytic Reduction (SCR) using aqueous urea. Recent work with urea SCR has involved aftertreatment for the 1.2L DIATA common-rail diesel engine. This engine was used in Ford's hybrid-electric vehicle, the Prodigy, which was developed under the PNGV (Partnership for a New Generation of Vehicles) program. An emission control system consisting of a diesel particulate filter followed by an underbody SCR system was used successfully to meet ULEV emission standards (0.2 g/mi NOx, 0.04 g/mi particulate matter (PM)).

Aftertreatment modeling capabilities are an important part of the diesel engine manufacturer's efforts to meet the quickly approaching EPA 2007 heavy-duty emissions regulations. A critical, yet poorly understood, component of particulate filter modeling is the representation of the soot oxidation rate. This term directly influences most of the macroscopic phenomenon of interest, including filtration efficiency, heat transfer, back pressure, and filter regeneration. Intrinsic soot cake properties such as packing density, permeability and heat transfer coefficients remain inadequately characterized (1). The work reported in this paper involves subgrid modeling techniques which may prove useful in resolving these inadequacies. The technique involves the use of a lattice Boltzmann modeling approach. This approach resolves length scales which are orders of magnitude below those typical of a standard computational fluid dynamics (CFD) representation of an aftertreatment device.

In this paper, we develop a method for optimizing urea dosing to minimize the downstream readings from a production NOx sensor that has cross-sensitivity to ammonia. This approach favors high NOx conversion and reduced ammonia slip. The motivation for this work is to define a process to identify the maximum selective catalytic reduction SCR performance bounds for a given drive cycle. The approach uses a model structure that has a closed-form optimal solution for the urea injection. Every aftertreatment system has its own, unique model, which must be identified and validated. To demonstrate the approach, a model is identified and validated using experimental SCR input/output NOx sensor data from a 2010 Cummins 6.7L ISB production engine. The optimal control law is then simulated and its performance compared against the simulated performance of the SCR using experimental data for its inlet conditions.

Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

Almost one-third of the fuel energy is wasted through the exhaust of a vehicle. An efficient waste heat recovery (WHR) process will undoubtedly lead to improved fuel efficiency and reduced greenhouse gases (GHG) emission. Currently, there are multiple WHR technologies that are being investigated by various entities in the auto industry. One relatively simple device to extract heat energy from the exhaust is a heat exchanger. Heat exchangers are used in some automotive applications to transfer heat from the hot exhaust gas to the colder coolant fluid to raise the coolant temperature. The warmer coolant fluid can be used for several purposes such as; faster heating of the engine’s lubrication oil and transmission fluids during cold starts, and faster cabin heating, which in turn, can potentially improve the overall engine efficiency and reduce exhaust emissions.

Sustained NOx reduction at low temperatures, especially in the 150-200 °C range, shares some similarities with the more commonly discussed cold-start challenge, however, poses a number of additional and distinct technical problems. In this project, we set a bold target of achieving and maintaining 90% NOx conversion at the SCR catalyst inlet temperature of 150 °C. This project is intended to push the boundaries of the existing technologies, while staying within the realm of realistic future practical implementation. In order to meet the resulting challenges at the levels of catalyst fundamentals, system components, and system integration, Cummins has partnered with the DOE, Johnson Matthey, and Pacific Northwest National Lab and initiated the Sustained Low-Temperature NOx Reduction program at the beginning of 2015 and completed in 2017.

This paper presents the coupon performance data of friction stir welded tailor welded blanks (TWBs) joined to a monolithic aluminum sheet by self-piercing rivets (SPRs). Uniaxial tensile tests were performed to characterize the joint strength and the total energy absorption capability of the TWB/monolithic sheet joint assemblies. Cyclic fatigue tests were also conducted to characterize the fatigue behavior and failure mechanisms of the jointed assemblies. This study provides data for the automotive designer to determine whether friction stir welded aluminum TWB/monolithic sheet joints are within the target joint strengths for a particular application if it should be pierced during the assembly process.