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This presentation focuses on the efforts Coordinating Research Council is sponsoring relating fuel properties and composition to performance in emerging advanced high efficiency, clean combustion engines. Presenter William J. Cannella, Chevron USA Inc.

The growing availability of different biofuels and synthetic fuels is leading to increased diversity of automotive fuels. Understanding how fuel properties affect combustion and how engine calibration strategies can compensate for variations in fuel composition is crucial for ensuring proper engine operation in this world of increased fuel diversity. This study looks at the ability to compensate for wide changes in cetane quality. Four different fuels with variations in cetane number, volatility and composition have been tested in a single cylinder engine and compared to diesel fuel. The selected operating conditions represent the entire engine map of a passenger car diesel engine. In part load the effects were investigated for conventional and premixed Diesel combustion. The results show that part load operation is especially relevant for the detection and compensation of varying fuel properties and that, depending on engine load, different control strategies have to be applied.

This study explores the use of two conventional ignition improvers, 2-ethylhexyl nitrate (EHN) and di-tert-butyl peroxide (DTBP), to enhance the autoignition of the regular gasoline in an homogeneous charge compression ignition (HCCI) engine at naturally aspirated and moderately boosted conditions (up to 180 kPa absolute) with a constant engine speed of 1200 rpm. The results showed that both EHN and DTBP are very effective for reducing the intake temperature (Tin) required for autoignition and for enhancing stability to allow a higher charge-mass fuel/air equivalence ratio (ϕm). On the other hand, the addition of these additives can also make the gasoline too reactive at some conditions, so significant exhaust gas recirculation (EGR) is required at these conditions to maintain the desired combustion phasing. Thus, there is a trade-off between improving stability and reducing the oxygen available for combustion when using ignition improvers to extend the high-load limit.

Homogeneous charge compression ignition (HCCI) combustion with fully premixed charge is severely limited at high-load operation due to the rapid pressure-rise rates (PRR) which can lead to engine knock and potential engine damage. Recent studies have shown that two-stage ignition fuels possess a significant potential to reduce the combustion heat release rate, thus enabling higher load without knock. This study focuses on three factors, engine speed, intake temperature, and fuel composition, that can affect the pre-ignition processes of two-stage fuels and consequently affect their performance with partial fuel stratification. A model fuel consisting of 73 vol.% isooctane and 27 vol.% of n-heptane (PRF73), which was previously compared against neat isooctane to demonstrate the superior performance of two-stage fuels over single-stage fuels with partial fuel stratification, was first used to study the effects of engine speed and intake temperature.

Previous work has shown that it may be advantageous to use gasoline type fuels with long ignition delays compared to today's diesel fuels in compression ignition engines. In the present work we investigate if high volatility is also needed along with low cetane (high octane) to get more premixed combustion leading to low NO and smoke. A single-cylinder light-duty compression ignition engine is run on four fuels in the diesel boiling range and three fuels in the gasoline boiling range. The lowest cetane diesel boiling range fuel (DCN = 22) also has very high aromatic content (75%vol) but the engine can be run on this to give very low NO (≺ 0.4 g/kWh) and smoke (FSN ≺ 0.1), e.g,. at 4 bar and 10 bar IMEP at 2000 RPM like the gasoline fuels but unlike the diesel fuels with DCNs of 40 and 56. If the combustion phasing and delay are matched for any two fuels at a given operating condition, their emissions behavior is also matched regardless of the differences in volatility and composition.

A broad range of diesel, kerosene, and gasoline-like fuels has been tested in a single-cylinder diesel engine optimized for advanced combustion performance. These fuels were selected in order to better understand the effects of ignition quality, volatility, and molecular composition on engine-out emissions, performance, and noise levels. Low-level biofuel blends, both biodiesel (FAME) and ethanol, were included in the fuel set in order to test for short-term advantages or disadvantages. The diesel engine optimized in Part 1 of this study included cumulative engine hardware enhancements that are likely to be used to meet Euro 6 emissions limits and beyond, in part by operating under conditions of Homogeneous Charge Compression Ignition (HCCI), at least over some portions of the speed and load map.

Two single-cylinder diesel engines were optimised for advanced combustion performance by means of practical and cumulative hardware enhancements that are likely to be used to meet Euro 5 and 6 emissions limits and beyond. These enhancements included high fuel injection pressures, high EGR levels and charge cooling, increased swirl, and a fixed combustion phasing, providing low engine-out emissions of NOx and PM with engine efficiencies equivalent to today's diesel engines. These combustion conditions approach those of Homogeneous Charge Compression Ignition (HCCI), especially at the lower part-load operating points. Four fuels exhibiting a range of ignition quality, volatility, and aromatics contents were used to evaluate the performance of these hardware enhancements on engine-out emissions, performance, and noise levels.

The behavior of Ethanol and seven fuels in the boiling point range of gasoline but with an Octane Number spanning from 69 to 99 was investigated in Partially Premixed Combustion. A load sweep was performed from 5 to 18 bar gross IMEP at 1300 rpm. The engine used in the experiments was a single cylinder Scania D12. To allow high load operations and achieve sufficient mixing, the compression ratio was decreased from the standard 18:1 to 14.3:1. It was shown that by using only 50% of EGR it is possible to achieve NOx below 0.30 g/kWh even at high loads. At 18 bar IMEP soot was in the range of 1-2 FSN for the gasoline fuels while it was below 0.06 FSN with Ethanol. The use of high boost combined with relatively short combustion duration allowed reaching gross indicated efficiencies in the range of 54 - 56%. At high load the partial stratified mixture allowed to keep the maximum pressure rise rate below 15 bar/CAD with most of the fuels.

Effects of six different fuels on low temperature premixed compression ignition (PCI) combustion were experimentally investigated in this paper with a light-duty HSDI engine. The PCI combustion concept reduces NOx and smoke emissions simultaneously by low temperature and premixed combustion, respectively. To achieve low temperature and premixed combustion, the ignition delay is prolonged and the injection duration is shortened. Six fuels were chosen to examine the influence of cetane number (CN) and other fuel properties on low temperature PCI combustion. The fuel selection also included a pure Gas- to-Liquid (GTL) fuel and a blend of base diesel and 20% soy based biodiesel (B20). Fuel effects were studied over a matrix of seven part load points in the low temperature combustion mode. The seven part load points were specified by engine speed (RPM) and brake mean effective pressure (BMEP).

Six diesel, kerosene, gasoline-like, and naphtha fuels have been tested in a single cylinder diesel engine and a demonstrator vehicle, both equipped with similar engine technology and optimized for advanced combustion performance. This study was completed in order to investigate the potential to reduce engine-out emissions while maintaining engine efficiency and noise levels through changes in both engine hardware and fuel properties. The fuels investigated in this study were selected in order to better understand the effects of ignition quality, volatility, and molecular composition on engine-out emissions and performance. The optimized bench engine used in this study included engine hardware enhancements that are likely to be used to meet Euro 6 emissions limits and beyond, in part by operating under advanced combustion conditions, at least under some speed and load conditions.

The current research focuses in understanding how inlet pressure, EGR, combustion phasing, engine speed and pilot main ratio are affecting the main parameters of the combustion (e.g. efficiency, NOx, soot, maximum pressure rise rate) in the novel concept of injecting high octane number fuels in partially premixed combustion. The influence of the above mentioned parameters was studied by performing detailed sweeps at 32 bar fuel MEP (c.a. 16-18 bar gross IMEP); three different kinds of gasoline were tested (RON: 99, 89 and 69). The experiments were ran in a single cylinder heavy duty engine; Scania D12. At the end of these sweeps the optimized settings were computed in order to understand how to achieve high efficiency, low emissions and acceptable maximum pressure rise rate.

This research describes the potential to adopt detailed chemical kinetics for practical and potential future fuels using tri-component surrogate mixtures capable of simulating fuel octane “sensitivity” . Since the combustion characteristics of modern fuels are routinely measured using the RON and MON of the fuel, a methodology to generate detailed chemical kinetic mechanisms for these fuels based on these data is presented. Firstly, a novel correlation between various tri-component blends (comprised of i-octane, n-heptane and toluene) and fuel RON and MON was obtained by carrying out standard octane tests. Secondly, a chemical kinetic mechanism for tri-component fuels was validated using a Stochastic Reactor Model (SRM) suite, an in-cylinder engine combustion simulator, and a series of engine experiments conducted in HCCI operating mode.

Port fuel injected (PFI) technology remains the most common fuel delivery type present in the marketplace for gasoline spark ignition engines and a legacy vehicle fleet featuring PFI technology will remain in the market for decades to come. This is especially the case in parts of Asia where PFI technology is still prominent, although direct injection (DI) technology adoption is starting to catch up. PFI engines can, when operated with lower quality fuels and lubricants, build up performance impairing deposits on a range of critical engine parts including in the fuel injectors, combustion chamber and on inlet valves. Inlet valve deposits (IVDs) in more severe cases have been associated with drivability issues such as engine stumble and engine hesitation on sudden acceleration. Deposit control additives in gasoline formulations are a well-established route to managing and even reversing fuel system fouling.

If fuels that are more resistant to auto-ignition are injected near TDC in compression ignition engines, they ignite much later than diesel fuel and combustion occurs when the fuel and air have had more chance to mix. This helps to reduce NOX and smoke emissions at much lower injection pressures compared to a diesel fuel. However, PPCI (Partially Premixed Compression Ignition) operation also leads to higher CO and HC at low loads and higher heat release rates at high loads. These problems can be significantly alleviated by managing the mixing through injector design (e.g. nozzle size and centreline spray angle) and changing CR (Compression Ratio). This work describes results of running a single-cylinder diesel engine on fuel blends by using three different nozzle design (nozzle size: 0.13 mm and 0.17 mm, centreline spray angle: 153° and 120°) and two different CRs (15.9:1 and 18:1).

Cyclic fluctuations of the in-cylinder processes in a Direct Injection Spark Ignition (DISI) engine may strongly affect the engine operation causing misfires or variations in the indicated mean effective pressure (imep). Particularly misfires prevent compliance with current or future exhaust emission legislations. Nevertheless, the origin of cyclic fluctuations is not well understood since fluctuations of in-cylinder air flow, fuel injection and wall interaction have to be considered. This paper focusses on a detailed experimental analysis of the origin of cyclic fluctuations in a DISI engine with an air guided combustion process by means of advanced Laser Induced Exciplex Fluorescence (LIEF) measurements. It reveals that cycle-to-cycle variations primarily originate from the air/fuel ratio at the spark plug.

The main assignment of Controlled Auto Ignition (CAI) operation range expansion is to reduce the burn rate or combustion noise at high load and to minimize misfire at low load. The potential of two principal EGR strategies is well known to initiate CAI in a wide range of operation map by using a variable train system: the Exhaust Port Recirculation (EPR) for higher part load and the Combustion Chamber Recirculation (CCR - also called Negative Valve Overlap) for lower part load. However the detailed comparison of the ignition phenomena with each EGR strategy has not been fully studied yet. In this paper, EPR and CCR were compared with same operational condition (engine speed and load). For the analysis, flame luminescence and Raman scattering method for optical measurement and STAR-CD (CD-adapco) for numerical simulation are used.

The current discussion about possible limitation of CO2 emissions makes improvement of fuel consumption a central topic for gasoline engine development. Various technological solutions are available to realize this improvement. Concepts featuring direct fuel injection, engine downsizing and unthrottled control of engine load with variable valvetrains are currently considered the most promising ways to achieve this goal. Further concepts that are under development include Controlled Auto Ignition (CAI) and homogenous lean burn combustion as well as certain combinations of these technologies. Within the European market, direct injection is currently the most popular solution. The drawback is that a very expensive exhaust gas aftertreatment system is necessary to keep exhaust emissions within legal limits.

Controlled Auto Ignition (CAI) as a promising future combustion process is a concept to strongly reduce fuel consumption as well as NOx emissions. The acceptance and the potential of this combustion process depends on the possible CAI operation range in the engine map and the fuel consumption benefit, as well as the complexity of the variable valve train which is necessary to realize the CAI combustion process. The thermodynamic investigations presented in this paper were done on an engine equipped with an electromechanical valve train (EMVT), featuring Port Fuel Injection (PFI) and direct Injection. They show that the electromechanical valve train is an excellent platform for developing the CAI process. Controlled Auto Ignition has been realized with port fuel injection in a speed range between 1000 and 4500 rpm and in a load range between approximately 1 and 6 bar BMEP (about 5 bar BMEP for pressure gradients lower than 3 bar/°CA) depending on engine speed.

The performance aspect of gasoline combustion has traditionally been measured using Research Octane Number (RON) and Motor Octane Number (MON) which describe antiknock performance under different conditions. Recent literature suggests that MON is less important than RON in modern cars and a relaxation in the MON specification could improve vehicle performance, while also helping refiners in the production of gasoline. At the same time, for the same octane number change, increasing RON appears to provide more benefit to engine power and acceleration than reducing MON. It has also been suggested that there could be fuel efficiency benefits (on a tank to wheels basis) for specially adapted engines, for example, operating at higher compression ratio, on very high RON (100+). Other workers have advocated the use of an octane index (OI) which incorporates both RON and MON to give an indication of octane quality.

Factors affecting the pressure rise rate, and consequently the high-load limit, in the sequential ignition of a homogeneous charge in a temperature gradient have been identified. The pressure rise rate decreases with an increase in the magnitude of the temperature gradient and an increase in the sensitivity of the constant volume ignition delay time to temperature. It increases with an increase in the intrinsic reaction rate (i.e., the reaction rate for a charge of uniform composition and temperature). Since the ignition delay time and the intrinsic reaction rate are directly related to fuel properties, the high-load limit is sensitive to fuel selection. The above three factors are used to explain the high-load limit obtained from a knock limited Controlled Auto-Ignition (CAI) engine with a homogeneous charge operating with three different fuels. The fuel comparisons are made with the engine operating at the same combustion phasing.