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Monitoring NO2 Production of a Diesel Oxidation Catalyst

2012-01-24
A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.
Journal Article

Ethanol Blend Effects On Direct Injection Spark-Ignition Gasoline Vehicle Particulate Matter Emissions

2010-10-25
2010-01-2129
Direct injection spark-ignition (DISI) gasoline engines can offer better fuel economy and higher performance over their port fuel-injected counterparts, and are now appearing increasingly in more U.S. vehicles. Small displacement, turbocharged DISI engines are likely to be used in lieu of large displacement engines, particularly in light-duty trucks and sport utility vehicles, to meet fuel economy standards for 2016. In addition to changes in gasoline engine technology, fuel composition may increase in ethanol content beyond the 10% allowed by current law due to the Renewable Fuels Standard passed as part of the 2007 Energy Independence and Security Act (EISA). In this study, we present the results of an emissions analysis of a U.S.-legal stoichiometric, turbocharged DISI vehicle, operating on ethanol blends, with an emphasis on detailed particulate matter (PM) characterization.
Journal Article

Lean Gasoline Engine Reductant Chemistry During Lean NOx Trap Regeneration

2010-10-25
2010-01-2267
Lean NOx Trap (LNT) catalysts can effectively reduce NOx from lean engine exhaust. Significant research for LNTs in diesel engine applications has been performed and has led to commercialization of the technology. For lean gasoline engine applications, advanced direct injection engines have led to a renewed interest in the potential for lean gasoline vehicles and, thereby, a renewed demand for lean NOx control. To understand the gasoline-based reductant chemistry during regeneration, a BMW lean gasoline vehicle has been studied on a chassis dynamometer. Exhaust samples were collected and analyzed for key reductant species such as H₂, CO, NH₃, and hydrocarbons during transient drive cycles. The relation of the reductant species to LNT performance will be discussed. Furthermore, the challenges of NOx storage in the lean gasoline application are reviewed.
Journal Article

Effects of Biofuel Blends on RCCI Combustion in a Light-Duty, Multi-Cylinder Diesel Engine

2013-04-08
2013-01-1653
Reactivity Controlled Compression Ignition (RCCI) is an engine combustion strategy that utilizes in-cylinder fuel blending to produce low NOx and PM emissions while maintaining high thermal efficiency. Previous RCCI research has been investigated in single-cylinder heavy-duty engines [1, 2, 3, 4, 5, 6]. The current study investigates RCCI operation in a light-duty multi-cylinder engine over a wide number of operating points representing vehicle operation over the US EPA FTP test. Similarly, previous RCCI engine experiments have used petroleum based fuels such as ultra-low sulfur diesel fuel (ULSD) and gasoline, with some work done using high percentages of biofuels, namely E85 [7]. The current study was conducted to examine RCCI performance with moderate biofuel blends, such as E20 and B20, as compared to conventional gasoline and ULSD.
Journal Article

Lignin-Derived Carbon Fiber as a Co-Product of Refining Cellulosic Biomass

2014-01-15
2013-01-9092
Lignin by-products from biorefineries has the potential to provide a low-cost alternative to petroleum-based precursors to manufacture carbon fiber, which can be combined with a binding matrix to produce a structural material with much greater specific strength and specific stiffness than conventional materials such as steel and aluminum. The market for carbon fiber is universally projected to grow exponentially to fill the needs of clean energy technologies such as wind turbines and to improve the fuel economies in vehicles through lightweighting. In addition to cellulosic biofuel production, lignin-based carbon fiber production coupled with biorefineries may provide $2,400 to $3,600 added value dry Mg−1 of biomass for vehicle applications. Compared to producing ethanol alone, the addition of lignin-derived carbon fiber could increase biorefinery gross revenue by 30% to 300%.
Journal Article

Characterization of Reactivity Controlled Compression Ignition (RCCI) Using Premixed Gasoline and Direct-Injected Gasoline with a Cetane Improver on a Multi-Cylinder Engine

2015-04-14
2015-01-0855
The focus of the present study was to characterize Reactivity Controlled Compression Ignition (RCCI) using a single-fuel approach of gasoline and gasoline mixed with a commercially available cetane improver on a multi-cylinder engine. RCCI was achieved by port-injecting a certification grade 96 research octane gasoline and direct-injecting the same gasoline mixed with various levels of a cetane improver, 2-ethylhexyl nitrate (EHN). The EHN volume percentages investigated in the direct-injected fuel were 10, 5, and 2.5%. The combustion phasing controllability and emissions of the different fueling combinations were characterized at 2300 rpm and 4.2 bar brake mean effective pressure over a variety of parametric investigations including direct injection timing, premixed gasoline percentage, and intake temperature. Comparisons were made to gasoline/diesel RCCI operation on the same engine platform at nominally the same operating condition.
Journal Article

Analysis of Thermal and Chemical Effects on Negative Valve Overlap Period Energy Recovery for Low-Temperature Gasoline Combustion

2015-09-06
2015-24-2451
A central challenge for efficient auto-ignition controlled low-temperature gasoline combustion (LTGC) engines has been achieving the combustion phasing needed to reach stable performance over a wide operating regime. The negative valve overlap (NVO) strategy has been explored as a way to improve combustion stability through a combination of charge heating and altered reactivity via a recompression stroke with a pilot fuel injection. The study objective was to analyze the thermal and chemical effects on NVO-period energy recovery. The analysis leveraged experimental gas sampling results obtained from a single-cylinder LTGC engine along with cylinder pressure measurements and custom data reduction methods used to estimate period thermodynamic properties. The engine was fueled by either iso-octane or ethanol, and operated under sweeps of NVO-period oxygen concentration, injection timing, and fueling rate.
Journal Article

Effects of Fuel Composition on EGR Dilution Tolerance in Spark Ignited Engines

2016-04-05
2016-01-0715
Fuel-specific differences in exhaust gas recirculation (EGR) dilution tolerance are studied in a modern, direct-injection single-cylinder research engine. A total of 6 model fuel blends are examined at a constant research octane number (RON) of 95 using n-heptane, isooctane, toluene, and ethanol. Laminar flame speeds for these mixtures, which are calculated using two different methods (an energy fraction mixing rule and a detailed kinetic simulation), span a range of about 6 cm/s. A nominal load of 350 kPa IMEPg at 2000 rpm is maintained with constant fueling and varying CA50 from 8-20 CAD aTDCf. EGR is increased until a COV of IMEP of 5% is reached. The results illustrate that flame speed affects EGR dilution tolerance; fuels with increased flame speeds have increased EGR tolerance. Specifically, flame speed correlates most closely to the initial flame kernel growth, measured as the time of ignition to 5% mass fraction burned.
Journal Article

Exploring the Relationship Between Octane Sensitivity and Heat-of-Vaporization

2016-04-05
2016-01-0836
The latent heat-of-vaporization (HoV) of blends of biofuel and hydrocarbon components into gasolines has recently experienced expanded interest because of the potential for increased HoV to increase fuel knock resistance in direct-injection (DI) engines. Several studies have been conducted, with some studies identifying an additional anti-knock benefit from HoV and others failing to arrive at the same conclusion. Consideration of these studies holistically shows that they can be grouped according to the level of fuel octane sensitivity variation within their fuel matrices. When comparing fuels of different octane sensitivity significant additional anti-knock benefits associated with HoV are sometimes observed. Studies that fix the octane sensitivity find that HoV does not produce additional anti-knock benefit. New studies were performed at ORNL and NREL to further investigate the relationship between HoV and octane sensitivity.
Journal Article

The Reduced Effectiveness of EGR to Mitigate Knock at High Loads in Boosted SI Engines

2017-09-04
2017-24-0061
Numerous studies have demonstrated that exhaust gas recirculation (EGR) can attenuate knock propensity in spark ignition (SI) engines at naturally aspirated or lightly boosted conditions [1]. In this study, we investigate the role of cooled EGR under higher load conditions with multiple fuel compositions, where highly retarded combustion phasing typical of modern SI engines was used. It was found that under these conditions, EGR attenuation of knock is greatly reduced, where EGR doesn’t allow significant combustion phasing advance as it does under lighter load conditions. Detailed combustion analysis shows that when EGR is added, the polytropic coefficient increases causing the compressive pressure and temperature to increase. At sufficiently highly boosted conditions, the increase in polytropic coefficient and additional trapped mass from EGR can sufficiently reduce fuel ignition delay to overcome knock attenuation effects.
Journal Article

Characterization of Hydrocarbon Emissions from Gasoline Direct-Injection Compression Ignition Engine Operating on a Higher Reactivity Gasoline Fuel

2017-03-28
2017-01-0747
Low temperature combustion engine technologies are being investigated for high efficiency and low emissions. However, such engine technologies often produce higher engine-out hydrocarbon (HC) and carbon monoxide (CO) emissions, and their operating range is limited by the fuel properties. In this study, two different fuels, a US market gasoline containing 10% ethanol (RON 92 E10) and a higher reactivity gasoline (RON 80 E0), were compared on Delphi’s second generation Gasoline Direct-Injection Compression Ignition (Gen 2.0 GDCI) multi-cylinder engine. The engine was evaluated at three operating points ranging from a light load condition (800 rpm/2 bar IMEPg) to medium load conditions (1500 rpm/6 bar and 2000 rpm/10 bar IMEPg). The engine was equipped with two oxidation catalysts, between which was located the exhaust gas recirculation (EGR) inlet. Samples were taken at engine-out, between the catalysts, and at tailpipe locations.
Journal Article

Development and Validation of a Reduced Reaction Mechanism for Biodiesel-Fueled Engine Simulations

2008-04-14
2008-01-1378
In the present study a reduced chemical reaction mechanism for biodiesel surrogate fuel was developed and validated for multi-dimensional engine combustion simulations. An existing detailed methyl butanoate mechanism that contained 264 species and 1219 reactions was chosen to represent the oxygenated portion of the fuel. The reduction process included flux analysis, ignition sensitivity analysis, and optimization of reaction rate constants under constant volume conditions. The current reduced mechanism consists of 41 species and 150 reactions and gives predictions in excellent agreement with those of the comprehensive mechanism. In order to validate the mechanism under biodiesel-fueled engine conditions, it was combined with another skeletal mechanism for n-heptane oxidation. This combined reaction mechanism can be used to adjust the energy content of the fuel, and account for diesel/biodiesel blend engine simulations.
Journal Article

Fundamental Approach to Investigate Pre-Ignition in Boosted SI Engines

2011-04-12
2011-01-0340
A comprehensive experimental and theoretical approach was undertaken to understand the phenomenon of pre-ignition and to assess parameters to improve or even eliminate it completely. Oil mixing with fuel was identified as the leading theory of self ignition of the fuel. End of compression temperature has to meet a minimum level for pre-ignition to take place. In this work a comprehensive list of parameters were identified that have a direct and crucial role in the onset of pre-ignition including liner wetting, injection targeting, stratification, mixture motion and oil formulation. Many secondary effects were identified including ring dynamics, ring tension, spark plug electrode temperature and coolant temperature. CFD has been extensively used to understand test results including wall film, A/F ratio distribution and temperature at the end of compression when looked at in the context of fuel evaporation and mixing.
Journal Article

Challenges in Real Time Controls Simulation (Hardware-In-the-Loop) in Active Safety for Subsystem Level Software Verification

2011-04-12
2011-01-0450
As the new features for driver assistance and active safety systems are growing rapidly in vehicles, the simulation within a virtual environment has become a necessity. The current active safety system consists of Electronic Control Units (ECUs) which are coupled to camera and radar sensors. Two methods of implementation exists, integrated sensors with control modules or separation of sensors form control modules. The subsystem integration testing poses new challenges for virtual environment for simulation of active safety features. The comprehensive simulation environment for integration testing consists of chassis controls, powertrain, driver assistance, body and displays controllers. Additional complexity in the system is the serial communication strategy. Multiple communication protocols such as GMLAN, LIN, standard CAN, and Flexray could be present within the same vehicle topology.
Journal Article

Vehicle Safety Communications - Applications: System Design & Objective Testing Results

2011-04-12
2011-01-0575
The USDOT and the Crash Avoidance Metrics Partnership-Vehicle Safety Communications 2 (CAMP-VSC2) Consortium (Ford, GM, Honda, Mercedes, and Toyota) initiated, in December 2006, a three-year collaborative effort in the area of wireless-based safety applications under the Vehicle Safety Communications-Applications (VSC-A) Project. The VSC-A Project developed and tested communications-based vehicle safety systems to determine if Dedicated Short Range Communications (DSRC) at 5.9 GHz, in combination with vehicle positioning, would improve upon autonomous vehicle-based safety systems and/or enable new communications-based safety applications.
Journal Article

Modeling/Analysis of Pedestrian Back-Over Crashes from NHTSA's SCI Database

2011-04-12
2011-01-0588
An analysis of the first 35 back-over crashes reported by NHTSA's Special Crash Investigations unit was undertaken with two objectives: (1) to test a hypothesized classification of backing crashes into types, and (2) to characterize scenario-specific conditions that may drive countermeasure development requirements and/or objective test development requirements. Backing crash cases were sorted by type, and then analyzed in terms of key features. Subsequent modeling of these SCI cases was done using an adaptation of the Driving Reliability and Error Analysis Methodology (DREAM) and Cognitive Reliability and Error Analysis Methodology (CREAM) (similar to previous applications, for instance, by Ljung and Sandin to lane departure crashes [10]), which is felt to provide a useful tool for crash avoidance technology development.
Journal Article

Vehicle Safety Communications - Applications: Multiple On-Board Equipment Testing

2011-04-12
2011-01-0586
The United States Department of Transportation (USDOT) and the Crash Avoidance Metrics Partnership-Vehicle Safety Communications 2 (CAMP-VSC2) Consortium (Ford, General Motors, Honda, Mercedes-Benz, and Toyota) initiated, in December 2006, a three-year collaborative effort in the area of wireless-based safety applications under the Vehicle Safety Communications-Applications (VSC-A) Project. The VSC-A Project developed and tested Vehicle-to-Vehicle (V2V) communications-based safety systems to determine if Dedicated Short Range Communications (DSRC) at 5.9 GHz, in combination with vehicle positioning, would improve upon autonomous vehicle-based safety systems and/or enable new communications-based safety applications.
Journal Article

Development of a Camera-Based Forward Collision Alert System

2011-04-12
2011-01-0579
Forward Collision Alert (or Forward Collision Warning) systems provide alerts intended to assist drivers in avoiding or mitigating the harm caused by rear-end crashes. These systems currently use front-grille mounted, forward-looking radar devices as the primary sensor. In contrast, Lane Departure Warning (LDW) systems employ forward-looking cameras mounted behind the windshield to monitor lane markings ahead and warn drivers of unintended lane violations. The increasing imaging sensor resolution and processing capability of forward-looking cameras, as well recent important advances in machine vision algorithms, have pushed the state-of-the-art for camera-based features. Consequently, camera-based systems are emerging as a key crash avoidance system component in both a primary and supporting sensing role. There are currently no production vehicles with cameras used as the sole FCA sensing device.
Journal Article

Reliability and Safety/Integrity Analysis for Vehicle-to-Vehicle Wireless Communication

2011-04-12
2011-01-1045
Vehicle-to-vehicle (V2V) and vehicle-to-infrastructure (V2I) communications are gaining increasing importance in automotive research and engineering domains. The novel communication scheme is targeted to improve driver safety (e.g., forward collision warnings) and comfort (e.g., routing to avoid congestion, automatic toll collection, etc.). Features exploiting these communication schemes are still in the early stages of research and development. However, growing attention to system wide infrastructure - in terms of OEM collaboration on interface standardization, protocol standardization, and government supported road/wireless infrastructure - will lead to popularity of such features in the future. This paper focuses on evaluating reliability and safety/integrity of data communicated over the wireless channels for early design verification. Analysis of a design can be done based on formal models, simulation, emulation, and testing.
Journal Article

Analysis of Pre-Crash Data Transferred over the Serial Data Bus and Utilized by the SDM-DS Module

2011-04-12
2011-01-0809
The primary function of an airbag control module is to detect crashes, discriminate and predict if a deployment is necessary, then deploy the restraint systems including airbags and where applicable, pretensioners. At General Motors (GM), the internal term for airbag control module is Sensing and Diagnostic Module (SDM). In the 1994 model year, GM introduced its SDM on some of its North American airbag-equipped vehicles. A secondary function of that SDM and all subsequent SDMs is to record crash related data. This data can include data regarding impact severity from internal accelerometers and pre-crash vehicle data from various chassis and powertrain modules. Previous researchers have addressed the accuracy of both the velocity change data, recorded by the SDM, and the pre-crash data, but the assessment of the timing of the pre-crash data has been limited to a single family of modules (Delphi SDM-G).
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