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A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.

Dual-monolith catalyst systems containing Pd/Rh three-way catalysts (TWCs) provide effective emission solutions for LEV2/Bin 5 and Bin 4 close-coupled applications at low PGM loadings. These systems combine washcoat technology and PGM distribution for front and rear catalysts resulting in optimal hydrocarbon and NOx light-off and transient NOx control. The dual-catalyst [Pd/Rh + Pd/Rh] systems are characterized as a function of Pd-Rh content, PGM location, and catalyst technology for 4-cyl [close-coupled + underfloor] systems and 6-cyl close-coupled applications. The current Pd/Rh dual-catalyst converters significantly reduce NOx emissions compared to earlier [Pd + Pt/Rh] or [Pd + Pd/Rh] LEV/ULEV systems by utilizing uniform Rh distribution and new OSC materials. These new design strategies particularly impact NOx performance, especially during transient A/F excursions.

Performance of two types of NOx adsorber catalysts, one based on Ba and the other based on Ba with alkali metals, was compared fresh and after thermal aging. Incorporation of sodium(Na), potassium(K) and cesium(Cs) into NOx adsorber washcoat containing barium significantly increases the NOx conversions in the temperature range of 350-600°C over that of the alkali metal free NOx adsorber catalysts. NOx performance benefit and HC performance penalty were observed on both engine dynamometer and vehicle tests for the “Ba+alkali metals” NOx adsorber catalysts. “Ba+alkali metals” NOx adsorber catalysts also demonstrate superior sulfur resistance with better NOx performance after repeated sulfur poisonings and desulfations over the “Ba based” NOx adsorber catalysts.

As vehicle fuel economy requirements continue to increase it is becoming more challenging and expensive to simultaneously improve fuel consumption and meet emissions regulations. The Passive Ammonia SCR System (PASS) is a novel aftertreatment concept which has the potential to address NOx emissions with application to both lean SI and stoichiometric SI engines. PASS relies on an underfloor (U/F) SCR for storage of ammonia which is generated by the close-coupled (CC) TWCs. For lean SI engines, it is required to operate with occasional rich pulses in order to generate the ammonia, while for stoichiometric application ammonia is passively generated through the toggling of air/fuel ratio. PASS serves as an efficient and cost-effective enhancement to standard aftertreatment systems. For this study, the PASS concept was demonstrated first using lab reactor results which highlight the oxygen tolerance and temperature requirements of the SCR.

This paper focuses on measuring particle emissions of a representative light-duty diesel vehicle equipped with different engine exhaust aftertreatment in close-coupled position, including one designed to meet the upcoming Euro 6 emission standards. The latter combines a lean NOx trap (LNT) and a diesel particulate filter (DPF) in series to simultaneously reduce NOx and PM. Particle Matter (PM) and particle number emissions are measured throughout testing procedure and instrumentation which are compliant with the UN-ECE Regulation 83 proposals. Specifically measuring devices for particle number emissions, provided by two different suppliers, are alternatively used. No significant differences are observed due to the different system employed. On the other hand particle size distributions are measured by means of a specific experimental set-up including a two stage dilution system and an electrical low pressure impactor (ELPI).

Diesel engines have the potential to significantly increase vehicle fuel economy and decrease CO₂ emissions; however, efficient removal of NOx and particulate matter from the engine exhaust is required to meet stringent emission standards. A conventional diesel aftertreatment system consists of a Diesel Oxidation Catalyst (DOC), a urea-based Selective Catalyst Reduction (SCR) catalyst and a diesel particulate filter (DPF), and is widely used to meet the most recent NOx (nitrogen oxides comprising NO and NO₂) and particulate matter (PM) emission standards for medium- and heavy-duty sport utility and truck vehicles. The increasingly stringent emission targets have recently pushed this system layout towards an increase in size of the components and consequently higher system cost. An emerging technology developed recently involves placing the SCR catalyst onto the conventional wall-flow filter.

High-speed (12 kHz) imaging of combustion luminosity (enhanced by using a sodium fuel additive) has been analyzed and compared to crank angle resolved heat release rates and mass fraction burn profiles in a spray-guided spark-ignited direct-injection (SG-SIDI) optical single-cylinder engine. The addition of a sodium-containing additive to gasoline greatly increases the combustion luminosity, which allows unintensified high-speed (12 kHz) imaging of early partially premixed flame kernel growth and overall flame propagation with excellent signal-to-noise ratio for hundreds of consecutive engine cycles. Ignition and early flame kernel growth are known to be key to understanding and eliminating poor burn cycles in SG-SIDI engines.

The urea injection is a key function in Urea-SCR NOx reduction system. As the tailpipe NOx emission standard becomes increasingly stringent, it is critical to diagnose the injection faults in order to guarantee the SCR DeNox functionality and performance. Particularly, a blocked injector may cause under-dosing of urea thus reduced DeNox functionality. Monitoring urea injection rate is one of the efficient methods for injection fault diagnosis. However, direct measurement of the urea mass flow is not feasible due to its high cost. This paper presents methods that are promising for detecting and isolating faults in urea injection by processing certain actuator signal and existing sensory measurements, e.g., the injector Pulse Amplitude Modulated (PAM) command and the pressure of the urea delivery line. No additional dedicated sensor is required. Three methods are discussed to detect urea injection system faults.

The light-medium load operating range (4-7 bar net IMEP) presents many challenges for advanced low temperature combustion strategies utilizing low cetane fuels (specifically, 87-octane gasoline) in light-duty, high-speed engines. The overly lean overall air-fuel ratio (Φ≺0.4) sometimes requires unrealistically high inlet temperatures and/or high inlet boost conditions to initiate autoignition at engine speeds in excess of 1500 RPM. The objective of this work is to identify and quantify the effects of variation in input parameters on overall engine operation. Input parameters including inlet temperature, inlet pressure, injection timing/duration, injection pressure, and engine speed were varied in a ~0.5L single-cylinder engine based on a production General Motors 1.9L 4-cylinder high-speed diesel engine.

Cooled exhaust gas recirculation (EGR) is widely used in diesel engines to control engine-out NOx (oxides of nitrogen) emissions. A portion of the exhaust gases is re-circulated into the intake manifold of the engine after cooling it through a heat exchanger. EGR cooler heat exchangers, however, tend to lose efficiency and have increased pressure drop as deposit forms on the heat exchanger surface due to transport of soot particles and condensing species to the cooler walls. In this study, condensation of water vapor and hydrocarbons at the exit of the EGR cooler was visualized using a fiberscope coupled to a camera equipped with a complementary metal oxide semiconductor (CMOS) color sensor. A multi-cylinder diesel engine was used to produce a range of engine-out hydrocarbon concentrations. Both surface and bulk gas condensation were observed with the visualization setup over a range of EGR cooler coolant temperatures.

Diesel engine developers are continually striving to reduce harmful NOx emissions through various calibration and hardware strategies. One strategy being implemented in production Diesel engines involves utilizing cooled exhaust gas recirculation (EGR). Although there is a significant NOx reduction potential by utilizing cooled EGR, there are also several issues associated with it, such as EGR cooler fouling and a reduction in cooler effectiveness that can occur over time. The exact cause of these issues and many others related to cooler fouling are not clearly understood. One such unanswered issue or phenomenon that has been observed in both field tested and lab tested EGR coolers is that of a recovery in EGR cooler effectiveness after a shutdown or after cycling between various conditions.

Dual-brick catalyst systems containing Pd-only catalysts followed by Pt/Rh three-way catalysts (TWCs) are effective emission solutions for both close-coupled and underfloor LEV/ULEV applications due to optimal hydrocarbon light-off, NOx control, and balance of precious metal (PGM) usage. Dual-brick [Pd +Pt/Rh] systems on 3.8L V-6 LEV-calibrated vehicles were characterized as a function of PGM loading, catalyst technology, converter volumes, and substrate cell density. While hydrocarbon emissions improve with increasing Pd loading, decreasing the front catalyst volume at constant Pd content (resulting in higher Pd density) improved light-off emissions. Use of 600cpsi substrates improved underfloor NMHC emissions on a 3.8L vehicle by ∼ 6-10mg/mi compared to 400cpsi catalysts, and thus allowing reduction of catalyst volume while achieving ULEV emission levels without air addition.

Proposed vehicle emissions regulations for the near future have prompted automotive manufactures and component suppliers to focus heavily on developing more efficient exhaust aftertreatment devices to lower emissions from spark and compression ignition engines. One of the primary pollutants from lean-burn engines, especially from diesels, are oxides of nitrogen (NOx). Current three-way catalytic converters will not have adequate performance to meet future emission reduction requirements. Therefore, there is a need for researchers and engineers to develop efficient exhaust aftertreatment devices that will reduce NOx emissions from lean-burn engines. These devices must have very high conversion of NOx gases, be unaffected by exhaust-gas impurity such as sulfur, and have minimal impact on vehicle operations and fuel economy. An effective technology for NOx control that is currently receiving a lot of attention is a non-thermal plasma system.

With new legislation and federal regulation for vehicle emission levels, automotive and truck manufacturers have been prompted to focus on emission control technologies that limit the level of exhaust pollutants. One of the primary pollutants, especially from diesel engines, is oxides of nitrogen (NOx). One possible solution to this pollution challenge is to design a more efficient internal combustion engine, which would require better engine operating parameter controls. However, there are limitations associated with such tight engine management. This need has led researchers and engineers to focus on the development of exhaust aftertreatment devices that will reduce NOx emissions with current diesel engines. An optimum aftertreatment device must be unaffected by exhaust-gas impurity poisoning such as sulfur products, and must have minimal impact on vehicle operations and fuel economy.

With ever more stringent CO2 emissions mandates, many automobile manufacturers are seeking the fuel economy benefits of diesel and lean-burn gasoline engines. At the same time the emissions standards that diesel and gasoline engines will have to meet in the next decade continue to reduce. Proposed solutions for meeting the stringent emissions standards all appear to have limitations, such as propensities to poisoning from sulfur, narrow operating temperature windows, and requirements for controls that give rapid rich excursions. Non-thermal plasma-catalyst systems have shown good performance in bench testing while being largely unaffected by these same issues. A two-stage system with a unique non-thermal plasma reactor combined with a zeolite-based catalyst has been constructed and shown to work over a wide temperature range.

A double dielectric barrier discharge reactor driven by an alternating voltage is a relatively simple approach to promote oxidation of NO to NO2 for subsequent reduction in a catalyst bed. The chemical performance of such a non-thermal plasma reactor is determined by its current and electric field behavior in the gap, and by the fraction of the current carried by electrons, because the key reactants which initiate the NO oxidation and accompanying chemical changes are produced there, mostly by electron impact. We have tried to determine by models and experiments the bounds on performance of double dielectric barrier reactors and guidelines for optimization. Models reported here predict chemical results from time-resolved applied voltage and series sense capacitor data.