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The impact of gasoline composition on vehicle particulate emissions response has been widely investigated and documented. Correlation equations between fuel composition and particulate emissions have also been documented, e.g. Particulate Matter Index (PMI) and Particulate Evaluation Index (PEI). Vehicle PM/PN emissions correlate very well with these indices. In a previous paper, global assessment with PEI on fuel sooting tendency was presented [1]. This paper will continue the previous theme by the authors, and cover China gasoline in more detail. With air pollution an increasing concern, along with more stringent emission requirements in China, both OEMs and oil industries are facing new challenges. Emissions controls require a systematic approach on both fuels and vehicles. Chinese production vehicle particulate emissions for a range of PEI fuels are also presented.

Fuel chemistry plays a crucial role in the continued reduction of particulate emissions (PE) and cleaner air quality from vehicles and equipment powered by internal combustion engines (ICE). Over the past ten years, there have been great improvements in predictive particulate emissions indices (correlative mathematical models) based on the fuel’s composition. Examples of these particulate indices (PI) are the Honda Particulate Matter Index (PMI) and the General Motors Particulate Evaluation Index (PEI). However, the analytical chemistry lab methods used to generate data for these two PI indices are very time-consuming. Because gasoline can be mixtures of hundreds of hydrocarbon compounds, these lab methods typically include the use of the high resolution chromatographic separation techniques such as detailed hydrocarbon analysis (DHA), with 100m chromatography columns and long (3 - 4 hours) analysis times per sample.

With the implementation of the China VI gasoline standards, the use of ethanol is expanding and is intended to further reduce vehicle criteria gaseous and particulate emissions. However, due to the constraints of biomass ethanol production, petroleum derived Methyl tert-Butyl Ether (MTBE) is being used in addition to ethanol to improve fuel octane and maintain oxygen content. The impact of these mixed oxygenates on vehicle emissions are studied in this paper. The correlation of fuel characteristics to vehicle particulate emissions and their predictive indices has been investigated. The results from this study suggest some alternatives to existing fuel indices due to oxygenate contribution. Additionally, this paper studies, the emissions of three direct-injection turbocharged vehicle models focusing on particulate emissions from the Worldwide Harmonized Light Vehicles Test Cycle (WLTC). The test fuels were China VIb gasoline, blended with different ratios of ethanol and MTBE.

A gasoline’s chemical composition impacts a vehicle’s sooting tendency and therefore has been the subject of numerous emissions studies. From these studies, several mathematical correlation equations have been developed to predict a gasoline’s sooting tendency in modern spark-ignited internal combustion engine vehicles. This paper reviews the recently developed predictive tool methods and summarizes five years of global market fuel survey data to characterize gasoline sooting tendency trends around the world. Additionally, the paper will evaluate and suggest changes to the predictive methods to improve emissions correlations.