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For a better understanding of soot formation and oxidation processes in conventional diesel and biodiesel spray flames, the morphology, microstructure and sizes of soot particles directly sampled in spray flames fuelled with US#2 diesel and soy-methyl ester were investigated using transmission electron microscopy (TEM). The soot samples were taken at 50mm from the injector nozzle, which corresponds to the peak soot location in the spray flames. The spray flames were generated in a constant-volume combustion chamber under a diesel-like high pressure and high temperature condition (6.7MPa, 1000K). Direct sampling permits a more direct assessment of soot as it is formed and oxidized in the flame, as opposed to exhaust PM measurements. Density of sampled soot particles, diameter of primary particles, size (gyration radius) and compactness (fractal dimension) of soot aggregates were analyzed and compared. No analysis of the soot micro-structure was made.

This study investigates the role of turbulent-chemistry interaction in simulations of diesel spray combustion phenomena after end-of-injection (EOI), using the commercially-available CFD code CONVERGE. Recent experimental and computational studies have shown that the spray flame dynamics and mixture formation after EOI are governed by turbulent entrainment, coupled with rapid evolution of the thermo-chemical state of the mixture field. A few studies have shown that after EOI, mixtures between the injector nozzle and the lifted diffusion flame can ignite and appear to propagate back towards the injector nozzle via an auto-ignition reaction sequence; referred to as “combustion recession”.