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Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

In the next years, the upcoming emission legislations are expected to introduce further restrictions on the admittable level of pollutants from vehicles measured on homologation cycles and real drive tests. In this context, the strict control of pollutant emissions at the cold start will become a crucial point to comply with the new regulation standards. This will necessarily require the implementation of novel strategies to speed-up the light-off of the reactions occurring in the after-treatment system, since the cold start conditions are the most critical one for cumulative emissions. Among the different possible technological solutions, this paper focuses on the evaluation of the potential of a burner system, which is activated before the engine start. The hypothetical burner exploits the lean combustion of an air-gasoline mixture to generate a high temperature gas stream which is directed to the catalyst section promoting a fast heating of the substrate.

The selective catalytic reduction has seen widespread adoption as the best technology to reduce the NOx emissions from internal combustion engines, particularly for Diesels. This technology uses ammonia as a reducing agent, which is obtained injecting an ammonia carrier into the exhaust gas stream. The dosing of the ammonia carrier, usually AdBlue, is the major concern during the design and engine calibration phases, since the interaction between the injected liquid and the components of the exhaust system can lead to the undesired formation of solid deposits. To avoid this, the thermal and kinematic interaction between the spray and the components of the after treatment system (ATS) must be modeled accurately. In this work, the authors developed a Conjugate Heat Transfer (CHT) framework to model the kinetic and thermal interaction among the spray, the eventual liquid layer and the pipe walls.

Nowadays, proton exchange membrane (PEM) fuel cell is widely seen as a promising energy conversion device especially for transportation application scenario because of its high efficiency, low operation temperature and nearly-zero road emission. Extensive modeling work have been done based on different dimensions during the past decades, including one-dimensional (1D), two-dimensional (2D), three-dimensional (3D) and intermediate combinations in between (e.g. “1+1D”). 1D model benefits from a rationally-chosen set of assumptions to obtain excellent calculation efficiency, yet at the cost of accuracy to some extent. In contrast, 3D model has great advantage over 1D model on acquiring more comprehensive information inside the fuel cell. For macro-scale modeling work, one compromise aiming to realize both acceptable computation speed and reasonable reflection of cell operation state is to simplify the membrane electrode assembly (MEA).

Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.

Following market demands for a niche balance between engine performance and legislation requirement, a new-concept compressor scroll has been designed for small to medium size passenger cars. The design adopts a slight deviation from the conventional method, thus resulting in broader surge margin and better efficiency at off-design region. This paper presents the performance evaluation of the new compressor scroll on the cold-flow gas-stand followed by the on-engine testing. The testing program focused on back-to-back comparison with the standard compressor scroll, as well as identifying on-engine operational regime with better brake specific fuel consumption (BSFC) and transient performance. A specially instrumented 1.6L gasoline engine was used for this study. The engine control unit configuration is kept constant in both the compressor testing.

In the last few years, the effect of diabatic test conditions on compressor performance maps has been widely investigated, leading some Authors to propose different correction models. The accuracy of turbocharger performance map constitute the basis for the tuning and validation of a numerical method, usually adopted for the prediction of engine-turbocharger matching. Actually, it is common practice in automotive applications to use simulation codes, which can either require measured compression ratio and efficiency maps as input values or calculate them “on the fly” throughout specific sub-models integrated in the numerical procedures. Therefore, the ability to correct the measured performance maps taking into account internal heat transfer would allow the implementation of commercial simulation codes used for engine-turbocharger matching calculations.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

Models for the convective heat transfer from the combustion gases to the walls inside a spark ignition engine are an important keystone in the simulation tools which are being developed to aid engine optimization. The existing models have, however, been cited to be inaccurate for hydrogen, one of the alternative fuels currently investigated. One possible explanation for this inaccuracy is that the models do not adequately capture the effect of the gas properties. These have never been varied in a wide range because air and ‘classical’ fossil fuels have similar values, but they are significantly different in the case of hydrogen. As a first step towards a fuel independent heat transfer model, we have investigated the effect of the gas properties on the heat flux in a spark ignition engine.

Due to the increasing pressure to develop small-size and low-cost after-treatment systems meeting the legislative demands it is desirable to integrate multiple functionalities and exploit any possible synergies. Typical examples include DPFs catalyzed with deNOx catalysts, as well as LNT-SCR combinations using layered coating technology. The present paper deals with the modeling challenges involved for the proper simulation of such advanced concepts. Key role in such advanced simulation attempts has the coupling between diffusion-reaction phenomena, which is captured through intra-layer modeling. All investigations in this paper deal with the application of possible combined LNT-SCR system configurations. The simulation results show that a dual bed LNT- passive SCR configuration offers substantial NOx emissions reductions compared to a single LNT catalyst and effectively controls secondary NH3 emissions produced during LNT regeneration phases.

The rare occurrence during city driving of the exhaust temperature levels required for ceramic trap regeneration without catalytic aid, seems to be the main reason of delay in wide application of the trap. The use of catalysts seems to be more or less necessary. Study of the catalytic activity during trap regeneration had not been very effective so far. This holds equally true for the case of catalyzed trap as for the case of catalytic fuel additives. The lack of a satisfactory theory for the explanation and prediction of catalytic activity, directed international research and development towards the quest of the optimum catalyst, which could support a very simple and low-cost regeneration system. The new approach to the explanation of catalytic activity presented in this paper, denies the above assumption.

Engine optimization requires a good understanding of the in-cylinder heat transfer since it affects the power output, engine efficiency and emissions of the engine. However little is known about the convective heat transfer inside the combustion chamber due to its complexity. To aid the understanding of the heat transfer phenomena in a Spark Ignition (SI) engine, accurate measurements of the local instantaneous heat flux are wanted. An improved understanding will lead to better heat transfer modelling, which will improve the accuracy of current simulation software. In this research, prototype thin film gauge (TFG) heat flux sensors are used to capture the transient in-cylinder heat flux within a Cooperative Fuel Research (CFR) engine. A two-zone temperature model is linked with the heat flux data. This allows the distinction between the convection coefficient in the unburned and burned zone.

The present work details a study of the heat flux through the walls of an internal combustion engine. The determination of this heat flux is an important aspect in engine optimization, as it influences the power, efficiency and the emissions of the engine. Therefore, a set of simulation tools in the OpenFOAM® software has been developed, that allows the calculation of the heat transfer through engine walls for ICEs. Normal practice in these types of engine simulations is to apply a wall function model to calculate the heat flux, rather than resolving the complete thermo-viscous boundary layer, and perform simulations of the closed engine cycle. When dealing with a complex engine, this methodology will reduce the overall computational cost. It however increases the need to rely on assumptions on both the initial flow field and the behavior in the near-wall region.

To optimize internal combustion engines (ICEs), a good understanding of engine operation is essential. The heat transfer from the working gases to the combustion chamber walls plays an important role, not only for the performance, but also for the emissions of the engine. Besides, thermal management of ICEs is becoming more and more important as an additional tool for optimizing efficiency and emission aftertreatment. In contrast little is known about the convective heat transfer inside the combustion chamber due to the complexity of the working processes. Heat transfer measurements inside the combustion chamber pose a challenge in instrumentation due to the harsh environment. Additionally, the heat loss in a spark ignition (SI) engine shows a high temporal and spatial variation. This poses certain requirements on the heat flux sensor. In this paper we examine the heat transfer in a production SI ICE through the use of Thin Film Gauge (TFG) heat flux sensors.

Homogeneous Charge Compression Ignition (HCCI) engines can achieve both a high thermal efficiency and near-zero emissions of NOx and soot. However, their maximum attainable load is limited by the occurrence of a ringing combustion. At high loads, the fast combustion rate gives rise to pressure oscillations in the combustion chamber accompanied by a ringing or knocking sound. In this work, it is investigated how these pressure oscillations affect the in-cylinder heat transfer and what the best approach is to model the heat transfer during ringing combustion. The heat transfer is measured with a thermopile heat flux sensor inside a CFR engine converted to HCCI operation. A variation of the mass fuel rate at different compression ratios is performed to measure the heat transfer during three different operating conditions: no, light and severe ringing. The occurrence of ringing increases both the peak heat flux and the total heat loss.

In the last years, as a response to the more and more restrictive emission legislation, new devices (SRC, DOC, NOx-trap, DPF) have been progressively introduced as standard components of modern after-treatment system for Diesel engines. In addition, the adoption of electrical heating is nowadays regarded with interest as an effective solution to promote the light-off of the catalyst at low temperature, especially at the start-up of the engine and during the low load operation of the engine typical of the urban drive. In this work, a state-of-the-art 48 V electrical heated catalyst is considered, in order to investigate its effect in increasing the abatement efficiency of a standard DOC. The electrical heating device considered is based on a metallic support, arranged in a spiral layout, and it is heated by the Joule effect due to the passage of the electrical current.

The successful design and especially the control of the SCR system is a challenging process that can be supported by the application of simulation tools. As a first step, we employ physico-chemically informed ‘off-line’ models that are calibrated with the help of targeted small- and full-scale tests. Despite their high level of sophistication, this SCR model is able to be integrated in a control-oriented simulation software platform and connected to other powertrain simulation blocks. The target is to use this simulation platform as a virtual environment for the development and optimization of SCR control strategies. The above process is demonstrated in the case of a passenger car SCR. The model is calibrated at both fresh and aged catalyst condition and validated using experimental data from the engine bench under a wide variety of operating conditions. Next, the calibrated model was coupled with embedded control models, developed for Euro 6 passenger car powertrains.

Knock is one of the main factors limiting the efficiency of spark-ignition engines. The introduction of alternative fuels with elevated knock resistance could help to mitigate knock concerns. Alcohols are prime candidate fuels and a model that can accurately predict their autoignition behavior under varying engine operating conditions would be of great value to engine designers. The current work aims to develop such a model for neat methanol. First, an autoignition delay time correlation is developed based on chemical kinetics calculations. Subsequently, this correlation is used in a knock integral model that is implemented in a two-zone engine code. The predictive performance of the resulting model is validated through comparison against experimental measurements on a CFR engine for a range of compression ratios, loads, ignition timings and equivalence ratios.

In this paper the low temperature reduction process of nitrates stored at high temperatures over model Pt-Ba/Al2O3 LNT catalysts using both H2 and C3H6 is analyzed. The results indicate that over the Pt-Ba/Al2O3 catalyst the reduction of stored NOx with both H2 and C3H6 occurs at temperature below those corresponding to their thermal stability. Accordingly, the reduction process occurs through a Pt-catalyzed surface reaction, which does not involve, as a preliminary step, the thermal decomposition of the adsorbed NOx species. The occurrence of such a pathway also requires the co-presence of the storage element and of the noble metal on the same support.

Particle emissions have been generally associated to diesel engines. However, spark-ignition direct injection (SI-DI) engines have been observed to produce notable amounts of particulate matter as well. The upcoming Euro 6 legislation for passenger cars (effective in 2014, stricter limit in 2017) will further limit the particulate emissions from SI engines by introducing a particle number emission (PN) limit, and it is not probable that the SI-DI engines are able to meet this limit without resorting to additional aftertreatment systems. In this study, the solid particle emissions of a SI-DI passenger car with and without an installed Particle Oxidation Catalyst (POC®) were studied over the New European Driving Cycle (NEDC) on a chassis dynamometer and over real transient acceleration situations on road. It was observed that a considerable portion of particle number emissions occurred during the transient acceleration phases of the cycle.