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As a research of low temperature regeneration of DPF, combustion mechanism of diesel particulate matter (PM) trapped in DPF was investigated. For the assumption of PM combustion mechanism, the relationship between PM combustion characteristics and the physical properties of PM particles was investigated by using thermal and spectroscopic analysis methods. Experimental PM samples were produced under typical engine operating conditions using three representative fuels, two commercial diesel fuels containing aromatics (JIS-2 and Class 1) and a paraffin fuel that was prepared in a gas-to-liquid (GTL) process and did not contain any aromatics. Based upon these characteristics and combustion test results of the PM samples, a mechanism of the PM combustion was assumed. And the crystallinity of PM particles and existence of some surface functional groups containing oxygen are thought to be the important factors to lower the temperature of PM combustion., independent of the fuel type.

The blending of dimethyl carbonate (DMC), which contains 53% of oxygen, in diesel fuel is very effective to suppress the formation of exhaust particulates, however, the mechanism of the suppression has not been made clear. In this study, the comparison on the performance of gas oil and DMC mixture was achieved. The effect of the oxygen in DMC molecule has to suppress the formation of particulates was monitored by way of using thermal cracking analyzer under various conditions.