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Recent trends to downsize engines have resulted in lighter weight and greater compactness. At the same time, however, power density has increased due to the addition of turbocharger and other such means to supplement engine power and torque, and this has increased the thermal and mechanical load. In this kind of environment, corrosion of the copper alloy bushing (piston pin bushing) that is press-fitted in the small end of the connecting rod becomes an issue. The material used in automobile bearings, of which the bushing is a typical example, is known to undergo sulfidation corrosion through reaction with an extreme-pressure additive Zinc Dialkyldithiophosphate (ZnDTP) in the lubricating oil. However, that reaction path has not been clarified. The purpose of the present research, therefore, is to clarify the reaction path of ZnDTP and copper in an actual engine environment.

The purpose of this research was to predict the amount of wear on exhaust valve seats in durability testing of gasoline engines. Through the rig wear test, a prediction formula was constructed with multiple factors as variables. In the rig test, the wear rate was measured in some cases where a number of factors of valve seat wear were within a certain range. Through these tests, sensitivity for each factor was determined from the measured wear data, and then a prediction formula for calculating the amount of wear was constructed with high sensitivity factors. Combining the wear amount calculation formula with the operation mode of the actual engine, the wear amount in that mode can be calculated. The calculated wear amount showed a high correlation with the wear amount measured in bench tests and the wear amount measured in vehicle tests.