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Global demand for alternative fuels to combat rising energy costs has sparked a renewed interest in catalysts that can effectively remediate NOx emissions resulting from combustion of a range of HC based fuels. Because many of these new engine technologies rely on lean operating environments to produce efficient power, the resulting emissions are also present in a lean atmosphere. While HCs are easily controlled in such environments, achieving high NOx conversion to N2 has continued to elude fully satisfactory solution. Until recently, most approaches have relied on catalysts with precious metals to either store NOx and subsequently release it as N2 under rich conditions, or use NH3 SCR catalysts with urea injection to reduce NOx under lean conditions. However, new improvements in Ag based technologies also look very promising for NOx reduction in lean environments.

With increasingly stringent emissions regulations and concurrent requirements for enhanced engine thermal efficiency, a comprehensive characterization of the automotive gasoline fuel spray has become essential. The acquisition of accurate and repeatable spray data is even more critical when a combustion strategy such as gasoline direct injection is to be utilized. Without industry-wide standardization of testing procedures, large variablilities have been experienced in attempts to verify the claimed spray performance values for the Sauter mean diameter, Dv90, tip penetration and cone angle of many types of fuel sprays. A new SAE Recommended Practice document, J2715, has been developed by the SAE Gasoline Fuel Injection Standards Committee (GFISC) and is now available for the measurement and characterization of the fuel sprays from both gasoline direct injection and port fuel injection injectors.

Low-cost lean NOx aftertreatment is one of the main challenges facing high-efficiency gasoline and diesel engines operating with lean mixtures. While there are many candidate technologies, they all offer tradeoffs. We have investigated a multi-component Dual SCR aftertreatment system that is capable of obtaining NOx reduction efficiencies of greater than 90% under lean conditions, without the use of precious metals or urea injection into the exhaust. The Dual SCR approach here uses an Ag HC-SCR catalyst followed by an NH3-SCR catalyst. In bench reactor studies from 150 °C to 500 °C, we have found, for modest C/N ratios, that NOx reacts over the first catalyst to predominantly form nitrogen. In addition, it also forms ammonia in sufficient quantities to react on the second NH3-SCR catalyst to improve system performance. The operational window and the formation of NH3 are improved in the presence of small quantities of hydrogen (0.1–1.0%).

A single-cylinder engine was used to study the potential of a high-efficiency combustion concept called gasoline direct-injection compression-ignition (GDCI). Low temperature combustion was achieved using multiple injections, intake boost, and moderate EGR to reduce engine-out NOx and PM emissions engine for stringent emissions standards. This combustion strategy benefits from the relatively long ignition delay and high volatility of regular unleaded gasoline fuel. Tests were conducted at 6 bar IMEP - 1500 rpm using various injection strategies with low-to-moderate injection pressure. Results showed that triple injection GDCI achieved about 8 percent greater indicated thermal efficiency and about 14 percent lower specific CO2 emissions relative to diesel baseline tests on the same engine. Heat release rates and combustion noise could be controlled with a multiple-late injection strategy for controlled fuel-air stratification. Estimated heat losses were significantly reduced.

With the wider use of biofuels in the marketplace, a program was conducted to study the deposit forming tendencies and performance of E85 (85% denatured ethanol and 15% gasoline) in a modern Flexible Fuel Vehicle (FFV). The test vehicle for this program was a 2006 General Motors Chevrolet Impala FFV equipped with a 3.5 liter V-6 powertrain. A series of 5,000 mile Chassis Dynamometer (CD) Intake Valve Deposits (IVD) and performance tests were conducted while operating the FFV on conventional (E0) regular unleaded gasoline and E85 to determine the deposit forming tendencies of both fuels. E85 test fuels were found to generate significantly higher levels of IVD than would have been predicted from the base gasoline component alone. The effects on the weight and composition of IVD due to a corrosion inhibitor and sulfates that were indigenous to one of the ethanols were also studied.

This paper includes a numerical and experimental study of fluid flow in automotive catalytic converters. The numerical work involves using computational fluid dynamics (CFD) to perform three-dimensional calculations of turbulent flow in an inlet pipe, inlet cone, catalyst substrate (porous medium), outlet cone, and outlet pipe. The experimental work includes using hot-wire anemometry to measure the velocity profile at the outlet of the catalyst substrate, and pressure drop measurements across the system. Very often, the designer may have to resort to offset inlet and outlet cones, or angled inlet pipes due to space limitations. Hence, it is very difficult to achieve a good flow distribution at the inlet cross section of the catalyst substrate. Therefore, it is important to study the effect of the geometry of the catalytic converter on flow uniformity in the substrate.

This paper describes a new tool to capture cylinder pressure information, calculate combustion parameters, and implement control algorithms. There are numerous instrumentation and prototyping systems which can provide some or all of this capability. The Cylinder Pressure Development Controller (CPDC) is unique in that it uses advanced high volume automotive grade circuitry, packaging, and software methodologies. This approach provides insight regarding the implementation of cylinder pressure based controls in a production engine management system. A high performance data acquisition system is described along with a data reduction technique to minimize data processing requirements. The CPDC software architecture is discussed along with model-based algorithm development and autocoding. Finally, CPDC calculated combustion parameters are compared with those from a well established combustion analysis system and thermodynamic simulations.

Implementation of real-time combustion feedback for use in closed-loop combustion control is a technology that has potential to assist in the successful production implementation of advanced diesel combustion modes. Low-temperature, pre-mixed diesel combustion is presently of interest because it offers the ability to lower the engine-out emissions of oxides of nitrogen (NOx) and particulate matter (PM). The need for lowering these two emissions is driven by tighter regulations enacted worldwide, especially the NOx limits in the United States. Reducing engine-out emissions eases the need for additional exhaust aftertreatment devices and their associated cost and mass. In this paper we will describe an experimental cylinder pressure-based control system and present both steady-state and transient results from a diesel engine employing a pre-mixed type of combustion.

As OEMs race to build their sales fleets to meet ever more stringent California Air Resources Board (CARB) mobile source evaporative emissions requirements, new technologies are emerging to control pollution. Evaporative emissions emanating from sources up-stream in the induction flow and venting through the ducts of the engine air induction system (EIS) need to be controlled in order classify a salable vehicle as a Partial Zero Emissions Vehicle (PZEV) in the state of California. As other states explore adopting California's pollution control standards, demand for emissions control measures in the induction system is expected to increase. This paper documents some of the considerations of designing an adsorbent evaporative emissions device in to a 2007 production passenger car for the North American and Asian markets. This new evaporative emissions device will be permanently installed in the vehicle's air cleaner cover without requiring service for 150K miles (expected vehicle life).

The traditional method of engine knock detection is to compare the knock intensity with a predetermined threshold. The calibration of this threshold is complex and difficult. A statistical knock detection method is proposed in this paper to reduce the effort of calibration. This method dynamically calculates the knock threshold to determine the knock event. Theoretically, this method will not only adapt to different fuels but also cope with engine aging and engine-to-engine variation without re-calibration. This method is demonstrated by modeling and evaluation using real-time engine dynamometer test data.

The requirement of reduced emissions and improved fuel economy led the introduction of direct-injection (DI) spark-ignited (SI) engines. Dual-fuel injection system (direct-injection and port-fuel-injection (PFI)) was also used to improve engine performance at high load and speed. Ethanol is one of the several alternative transportation fuels considered for replacing fossil fuels such as gasoline and diesel. Ethanol offers high octane quality but with lower energy density than fossil fuels. This paper presents the combustion characteristics of a single cylinder dual-fuel injection SI engine with the following fueling cases: a) gasoline for PFI and DI, b) PFI gasoline and DI ethanol, and c) PFI ethanol and DI gasoline. For this study, the DI fueling portion varied from 0 to 100 percentage of the total fueling over different engine operational conditions while the engine air-to-fuel ratio remained at a constant level.

Recovery of potable water from wastewater is essential for the success of long-term manned missions to the moon and Mars. Honeywell International and the team consisting of Thermodistillation Company (Kyiv, Ukraine) and NASA Johnson Space Center (JSC) Crew and Thermal Systems Division are developing a wastewater processing subsystem that is based on centrifugal vacuum distillation. The Wastewater Processing Cascade Distillation Subsystem (CDS) utilizes an innovative and efficient multi-stage thermodynamic process to produce purified water. The rotary centrifugal design of the system also provides gas/liquid phase separation and liquid transport under microgravity conditions. A five-stage prototype of the subsystem was built, delivered and integrated into the NASA JSC Advanced Water Recovery Systems Development Facility for development testing.

A key quantity for use in engine control is the exhaust manifold pressure. For production applications it is an important component in the calculation of the engine volumetric efficiency, as well as EGR flow and residual fraction. For cost reasons, however, it is preferable to not have to measure the exhaust manifold pressure for production applications. For that reason, it is advantageous to develop a model for estimating the exhaust manifold pressure in production application software that is small, accurate, and simple to calibrate. In this paper, a mean-value model for calculating the exhaust manifold pressure is derived from the compressible flow equation, treating the exhaust system as a fixed-geometry restriction between the exhaust manifold and the outlet of the tailpipe. Validation data from production applications is presented.

As diesel emission regulations continue to increase, the use of exhaust aftertreatment systems containing, for example the diesel oxidation catalyst (DOC) and diesel particulate filter (DPF) will become necessary in order to meet these stringent emission requirements. The addition of a DOC and DPF in conjunction with utilizing biodiesel fuels requires extensive research to study the implications that biodiesel blends have on emissions as well as to examine the effect on aftertreatment devices. The proceeding work discusses results from a 2006 VM Motori four-cylinder 2.8L direct injection diesel engine coupled with a diesel oxidation catalyst and catalyzed diesel particulate filter. Tests were done using ultra low sulfur diesel fuel blended with 20% choice white grease biodiesel fuel to evaluate the effects of biodiesel emission products on the performance and effectiveness of the aftertreatment devices and the effect of low temperature combustion modes.

In recent years, gasoline direct injection (GDi) engines have been popular due to their inherent potential for reduction of exhaust emissions and fuel consumption to meet stringent EPA standards. These engines require high-pressure fuel injection in order to improve the atomization process and accelerate mixture preparation. The high-pressure fuel pump is an essential component in the GDi system. Therefore, understanding the flow characteristics of this device and its associated behavior is critical for improving the performance of this category of engines. In this paper, the fluid flow characteristics in a high-pressure single-piston pump for use in GDi engines are analyzed using 1-D LMS Imagine.Lab AMESim system and 3-D Ansys Fluent computational fluid dynamics (CFD) models. The flow rate of the fuel pump under various cam speeds has been examined along with characteristics of the pump's control valve.

This paper describes a correlation study on fuel spray pattern recognition of multi-hole injectors for gasoline direct injection (GDi) engines. Spray pattern is characterized by patternation length, which represents the distance of maximum droplet concentration from the axis of the injector. Five fuel injectors with different numbers and sizes of nozzle holes were considered in this study. Experimental data and CFD modeling results were used separately to develop regression models for spray patternation. These regressions predicted the influence of a number of injector operating and design parameters, including injection system operating pressure, valve lift, injector hole length-to-diameter ratio (L/d) and the orientation of the injector hole. The regression correlations provided a good fit with both experimental and CFD spray simulation results. Thus CFD offers a good complement to experimental validation during development efforts to meet a desired injector spray pattern.

This paper focuses on the numerical investigation of the mixing and combustion of ethanol and gasoline in a single-cylinder 3-valve direct-injection spark-ignition engine. The numerical simulations are conducted with the KIVA code with global reaction models. However, an ignition delay model mitigates some of the deficiencies of the global one-step reaction model and is implemented via a two-dimensional look-up table, which was created using available detailed kinetics models. Simulations demonstrate the problems faced by ethanol operated engines and indicate that some of the strategies used for emission control and downsizing of gasoline engines can be employed for enhancing the combustion efficiency of ethanol operated engines.

Because combustion engine equipped vehicles must conform to stringent hydrocarbon (HC) emission requirements, many of them on the road today are equipped with an engine air intake system that utilizes a hydrocarbon adsorber. Also known as HC traps, these devices capture environmentally dangerous gasoline vapors before they can enter the atmosphere. A majority of these adsorbers use activated carbon as it is cost effective and has excellent adsorption characteristics. Many of the procedures for evaluating the adsorbtive performance of these emissions devices use mass gain as the measurand. It is well known that activated carbon also has an affinity for water vapor; therefore it is useful to understand how well humidity must be controlled in a laboratory environment. This paper outlines investigations that were conducted to study how relative humidity levels affect an activated carbon hydrocarbon adsorber.

The need for improved emissions control in lean exhaust to meet tightening, world-wide NOx emissions standards has led to the development of selective catalytic reduction of NOx with ammonia as a major technology for emissions control. Current systems are being designed to use a solution of urea (32.5 wt %) dissolved in water or Diesel Exhaust Fluid (DEF) as the ammonia source. While DEF or AdBlue® is widely used as a source of ammonia, it has a number of issues at low temperatures, including freezing below −12 °C, solid deposit formation in the exhaust, and difficulties in dosing at exhaust temperatures below 200 °C. Additionally creating a uniform ammonia concentration can be problematic, complicating exhaust packaging and usually requiring a discrete mixer.

Recovery of potable water from wastewater is essential to the success of long-duration human missions to the moon and Mars. Honeywell International and a team from the NASA Johnson Space Center (JSC) are developing a wastewater processing subsystem that is based on centrifugal vacuum distillation. The wastewater processor, which is referred to as the cascade distillation subsystem (CDS), uses an efficient multistage thermodynamic process to produce purified water. A CDS unit employing a five-stage distiller engine was designed, built, and delivered to the NASA JSC Advanced Water Recovery Systems Development Facility for performance testing; an initial round of testing was completed in fiscal year 2008 (FY08). Based, in part, on FY08 testing, the system is now in development to support an Exploration Life Support Project distillation comparison test that is expected to begin in 2009.