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Exhaust gas from the diesel engine contains particulate matter (PM) of soot that affects human health and the environment. For the reduction of the emission of the PM, the diesel particulate filter (DPF) is placed in the exhaust system. The pressure drops increases with the PM deposit quantity in the DPF, which results in the burden of the engine. Therefore, the PM should be removed regularly by oxidation process called regeneration. Consumption of fuel is improved by optimizing the timing of regeneration. However, it is difficult to visualize the behavior of PM trapping and oxidation. We have proposed a series of models from PM deposition to the oxidation process in the DPF. In this study, the behavior of deposition and oxidation of PM in the DPF with a catalyst are calculated. The numerical calculations are performed to estimate PM deposition-oxidation process within the DPF. The results are obtained using the simplified model constructed in this study.

Octane appetite of modern engines has changed as engine designs have evolved to meet performance, emissions, fuel economy and other demands. The octane appetite of seven modern vehicles was studied in accordance with the octane index equation OI=RON-KS, where K is an operating condition specific constant and S is the fuel sensitivity (RONMON). Engines with a displacement of 2.0L and below and different combinations of boosting, fuel injection, and compression ratios were tested using a decorrelated RONMON matrix of eight fuels. Power and acceleration performance were used to determine the K values for corresponding operating points. Previous studies have shown that vehicles manufactured up to 20 years ago mostly exhibited negative K values and the fuels with higher RON and higher sensitivity tended to perform better.

Further improvement in fuel consumption is needed for diesel engines to address regulatory requirement particularly for heavy duty diesel in Japan enforced in 2015, in addition to the compliance to the regulatory requirements for exhaust emission, which seems to be more stringent in future. The authors have participated in the project of “Comprehensive Technological Development of Innovative, Next-Generation, Low-Pollution Vehicles” organized by New Energy and Industrial Technology Development Organization (NEDO), and innovative devices such as multi stage boosting system, ultra high-pressure fuel injection system and variable valve actuation (camless) system had been developed in this project from a standpoint of simultaneous improvement of fuel consumption and exhaust emission. In camless system, intake and exhaust valves are driven by hydraulic pressure. So, fully flexible setting of opening and closure timings and lift of the intake and exhaust valves is possible.

Fuel efficiency is one of the most important parameters in advanced vehicles. Therefore, the measurement of fuel consumption in-situ and in real-time is obviously demanded in development and evaluation processes of new engines and vehicles. This paper describes a new concept for measuring fuel consumption in real-time, which utilizing raw exhaust gas flow rate and exhaust air-to-fuel ratio (AFR). The AFR is defined as the mass ratio of air and fuel supplied to the engine, and the mass flow rate of exhaust gas can be regarded as the summation of the mass flow rate of air and fuel. This means the fuel consumption can be calculated from exhaust flow rate and AFR. To realize in-situ, real-time measurement, we used an ultrasonic exhaust flow meter which can measure a wide flow range accurately with no pressure loss, and a fast response zirconia sensor which can be installed onto the exhaust pipe directly without any sampling system.

Hydrogen can be produced by electrolyzation with renewable electricity and the combustion products of hydrogen mixture include no CO, CO2 and hydrocarbons. In this study, engine performance with hydrogen / diesel dual fuel (hydrogen DDF) operation in a multi-cylinder diesel engine is investigated due to clarify advantages and disadvantages of hydrogen DDF operation. Hydrogen DDF operation under several brake power conditions are evaluated by changing a rate of hydrogen to total input energy (H2 rate). As H2 rate is increased, an amount of diesel fuel is decreased to keep a given torque constant. When the hydrogen DDF engine is operated with EGR, Exhaust gas components including carbon are improved or suppressed to same level as conventional diesel combustion. In addition, brake thermal efficiency is improved to 40% by increase in H2 rate that advances combustion phasing under higher power condition. On the other hand, NOx emission is much higher than one of conventional diesel engine.

Worldwide concern about air quality has led to ever-tougher emissions legislation for vehicles and a concomitant tightening of fuel specifications. However, not all countries or regions will move at the same rate. For example, parts of Europe and the US have already seen the introduction of the so-called “sulphur-free” fuels (i.e. <10 and <15ppm S). However, in many developing countries there are fuel specifications with sulphur limits in higher range of 1500 - 2500ppm, and other properties are also more relaxed, such as distillation or density. For a future world where larger volumes of GTL Fuel are available (2010 and beyond), it is essential to know the environmental impact of using both neat GTL and GTL blends, when compared to conventional market diesel. Moreover it is important to take into account the significant variation still anticipated for specifications of diesel between different countries.

Study of DME diesel engines was conducted to improve fuel consumption and emissions of its. Additionally, DME trucks were built for the promotion and the road tests of these trucks were executed on EFV21 project. In this paper, results of diesel engine tests and DME truck driving tests are presented. As for DME diesel engines, the performance of a DME turbocharged diesel engine with LPL-EGR was evaluated and the influence of the compression ratio was also explored. As for DME trucks, a 100,000km road test was conducted on a DME light duty truck. After the road test, the engine was disassembled for investigation. Furthermore, two DME medium duty trucks have been developed and are now the undergoing practical road testing in each area of two transportation companies in Japan.

There is an increasing recognition of injector deposit (ID) formation in fuel injection equipment as direct injection spark ignition (DISI) engine technologies advance to meet increasingly stringent emission legislation and fuel economy requirements. While it is known that the phenomena of ID in DISI engines can be influenced by changes in fuel composition, including increasing usage of aliphatic alcohols and additive chemistries to enhance fuel performance, there is however still a great deal of uncertainty regarding the physical and chemical structure of these deposits, and the mechanisms of deposit formation. In this study, a mechanical cracking sample preparation technique was developed to assess the deposits across DISI injectors fuelled with gasoline and blends of 85% ethanol (E85).

Increasingly strict government emissions regulations in combination with consumer demand for high performance vehicles is driving gasoline engine development towards highly downsized, boosted direct injection technologies. In these engines, fuel consumption is improved by reducing pumping, friction and heat losses, yet performance is maintained by operating at higher brake mean effective pressure. However, the in-cylinder conditions of these engines continue to diverge from traditional naturally aspirated technologies, and especially from the Cooperative Fuels Research engine used to define the octane rating scales. Engine concepts are thus key platforms with which to screen the influence of fundamental fuel properties on future engine performance.

In Gasoline Direct Injection engines, direct exposure of the injector to the flame can cause combustion products to accumulate on the nozzle, which can result in increased particulate emissions. This research observes the impact of injector fouling on particulate emissions and the associated injector spray pattern and shows how both can be reversed by utilising fuel detergency. For this purpose multi-hole injectors were deliberately fouled in a four-cylinder test engine with two different base fuels. During a four hour injector fouling cycle particulate numbers (PN) increased by up to two orders of magnitude. The drift could be reversed by switching to a fuel blend that contained a detergent additive. In addition, it was possible to completely avoid any PN increase, when the detergent containing fuel was used from the beginning of the test. Microscopy showed that increased injector fouling coincided with increased particulate emissions.

Newly designed laboratory measurement system, which reproduces particle number size distributions of both nuclei and accumulation mode particles in exhaust emissions, was developed. It enables continuous measurement of nano particle emissions in the size range between 5 and 1000 nm. Evaluations of particle number size distributions were conducted for diesel vehicles with a variety of emission aftertreatment devices and for gasoline vehicles with different combustion systems. For diesel vehicles, Diesel Oxidation Catalyst (DOC), urea-Selective Catalytic Reduction (urea-SCR) system and catalyzed Diesel Particulate Filter (DPF) were evaluated. For gasoline vehicles, Lean-burn Direct Injection Spark Ignition (DISI), Stoichiometric DISI and Multi Point Injection (MPI) were evaluated. Japanese latest transient test cycles were used for the evaluation: JE05 mode driving cycle for heavy duty vehicles and JC08 mode driving cycle for light duty vehicles.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

JCAPII gasoline workgroup reported vehicle emission study to comprehend the impact of ETBE blending. In previous study, we focused on the compatibility of ETBE blended gasoline with Japanese current gasoline vehicles in-use. Based on recent discussion with ETBE 8% blended gasoline into the market, more information becomes necessary. In this second report, we studied to comprehend the actual emission impact using realistic model fuels using several base stocks. Fuel properties of T50, T90 and aromatic compound content were selected through discussions. Specifications were changed within the range of the market. Both ETBE 0% and 8% were combined for these fuel matrixes. In total, eight fuels and two reference fuels were tested. Two J-ULEV vehicles (one MPI, and a stoichiometric-SIDI) were procured as representatives. We discussed quantitative and qualitative impact toward emissions. Data regarding CO2 and fuel economy change were also reported.

Control of NOx and Particulate Matter (PM) emissions from diesel engines remains a significant challenge. One approach to reduce both emissions simultaneously without fuel economy penalty is the reformed exhaust gas recirculation (REGR) technique, where part of the fuel is catalytically reacted with hot engine exhaust gas to produce a hydrogen-rich combustible gas that is then fed to the engine. On the contrary to fuel cell technology where the reforming requirements are to produce a reformate with maximized H2 concentration and minimized (virtually zero) CO concentration, the key requirement of the application of the exhaust gas fuel reforming technique in engines is the efficient on-demand generation of a reformate with only a relatively low concentration of hydrogen (typically up to 20%).

Various premixed diesel combustion concepts are suggested as the way of simultaneous reduction of NOx and PM emission from diesel engines. However, every combustion concept has common problems, such as difficulty of ignition timing control, a great deal of HC and CO emissions and limiting the operation region to low load operation. The purpose of this study is to expand the operation region of Premixed Compression Ignition (PCI) combustion, which is a premixed diesel combustion concept that realizes the fuel injection around the top dead center. As a result of examining it with EGR, supercharging operation and low compression ratio piston, PCI combustion region was expanded to cover higher load operation. And the high load region was limited by not only stoichiometric air fuel ratio but also permissible maximum in-cylinder pressure.

The objective of the work was to develop a fast response infrared analyzer that makes possible the cyclic measurement of exhaust gas concentrations from internal combustion engines. The new analyzer achieves T90 response time of less than 30 milliseconds and is capable of measuring CO, CO2 and HC (Hydrocarbons) simultaneously. Another feature of the analyzer is its' capability to measure simultaneously from multiple sample points, i.e., one optical bench with a maximum of four sample cells can measure CO, CO2 and HC simultaneously from four different sources. Results from a multiple cylinder engine show that this analyzer can be an effective tool for analysis and diagnosis of internal combustion engine exhaust products.

The blending of oxygenated compounds with gasoline is projected to increase because oxygenate fuels can be produced renewably, and because their high octane rating allows them to be used in substitution of the aromatic fraction in gasoline. Blending oxygenates with gasoline changes the fuels' properties and can have a profound affect on the distillation curve, both of which are known to affect engine-out emissions. In this work, the effect of blending methanol and ethanol with gasoline on unburned hydrocarbon and particulate emissions is experimentally determined in a spray guided direct injection engine. Particulate number concentration and size distribution were measured using a Cambustion DMS500. These data are presented for different air fuel ratios, loads, ignition timings and injection timings. In addition, the ASTM D86 distillation curve was modeled using the binary activity coefficients method for the fuel blends used in the experiments.

A new on-board portable emission measurement system (PEMS) for gaseous emissions has been designed and developed to meet CFR Part 1065 requirements. The new system consists of a heated flame ionization detector (HFID) for the measurement of total hydrocarbon, a heated chemiluminescence detector (HCLD) for the measurement of NOx, and a heated non-dispersive infra-red detector (HNDIR) for the measurement of CO and CO2. The oxygen interference and relative sensitivity of several hydrocarbon components have been optimized for the HFID. The CO2 and H2O quenching effect on the HCLD have been compensated using measured CO2 and H2O concentration. The spectral overlap and molecular interaction of H2O on the HNDIR measurement has also been compensated using an independent H2O concentration measurement. The basic performance of the new on-board emission measurement system has been verified accordingly with CFR part 1065 and all of the performances have met with CFR part 1065 requirement.

Transmission electron microscope (TEM) is a powerful tool for studying catalyst materials at nano-size and/or atomic level. Conventional TEM usually needs to be observed at room temperature in high vacuum conditions. A gaseous atmosphere and high temperature condition may change the properties of catalyst materials. Recently we developed an in situ observation system in TEM for observing the oxidation and reduction under a gas atmosphere at high temperature. Using the new in situ observation system in TEM, the morphological changes of the nano particle and support were observed in the heated gaseous atmosphere at atomic level in real time.

The regeneration of a Diesel Particulate Filter (DPF) is dependent on both the amount and type of soot present on the filter. The objective of this work is to understand how the fuel can affect this ease with which soot can be oxidized. This soot was produced in a two-cylinder four-stroke direct-injection diesel engine, operated with a matrix of fuels with varying aromatic and sulphur level. Their oxidation behaviour in different environments was determined by Temperature Programmed Oxidation in TGA and a six-flow reactor. Transmission electron microscopy was used to examine the soot morphology. Oxidation with only O2 shows oxidation temperatures strongly dependent on the fuel type. Soot oxidation in the presence of NO and a Pt-catalyst results in a lower oxidation temperature. SO2 has an inhibiting effect leading to higher soot oxidation temperature.