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Green zones are challenging problems for the thermal management systems of hybrid vehicles. This is because within the green zone the engine is turned off, and the only way to keep the aftertreatment system warm is lost. This means that there is a risk of leaving the green zone with a cold and ineffective aftertreatment system, resulting in high emissions. A thermal management strategy that heats the aftertreatment system prior to turning off the engine, in an optimal way, to reduce the NOx emissions when the engine is restarted, is developed. The strategy is also used to evaluate under what conditions pre-heating is a suitable strategy, by evaluating the performance in simulations using a model of a heavy-duty diesel powertrain and scenario designed for this purpose.

Today's diesel PM reduction systems are mainly based on catalyzed particulate filter(CPF) systems. However, most of their reaction kinetics remain unresolved. Among others, the soot oxidation rate over catalyst is particularly important in the evaluation of the performance of the catalysts and the efficient control of CPF regeneration. This study, therefore, investigated the oxidation rate of carbon black (Printex-U) over various Pt supported catalysts using a flow reactor setup simulating diesel exhaust conditions. Compared to non-catalyzed soot oxidation, the oxidation rate of carbon black over Pt catalysts was to an extent shifted towards low temperatures. This activity enhancement of soot oxidation over a catalyst can be attributed principally to NO to NO2 conversion because NO2 oxidizes soot with much lower activation energy (Ea=60kJ/mol) than O2 (Ea=177kJ/mol).

The combustion characteristics of a HSDI diesel engine were analyzed numerically using a reduced chemical kinetics. The reaction mechanism consisting of 26 steps and 17 species including the Zel'dovich NOx mechanism for the higher hydrocarbon fuel was implemented in the KIVA-3V. The characteristic time scale model was adopted to account for the effects of turbulent mixing on the reaction rates. The soot formation and oxidation processes are represented by Hiroyasu's model and NSC's model. The validation cases include the homogenous fuel/air mixture and the spray combustion in a constant volume chamber. After the validation, the present approach was applied to the analysis of the spray combustion processes in a HSDI diesel engine. The present approach reasonably well predicts the ignition delay, combustion processes, and emission characteristics in the high-pressure turbulent spray flame-field encountered in the practical HSDI diesel engines.

The Representative Interactive Flamelet(RIF) concept has been applied to numerically simulate the combustion processes and pollutant formation in the direct injection diesel engine. Due to the ability for interactively describing the transient behaviors of local flame structures with CFD solver, the RIF concept has the capabilities to predict the auto-ignition and subsequent flame propagation in the diesel engine combustion chamber as well as to effectively account for the detailed mechanisms of soot and NOx formation. In order to account for the spatial inhomogeneity of the scalar dissipation rate, the Eulerian Particle Flamelet Model using the multiple flamelets has been employed. Special emphasis is given to the turbulent combustion model which properly accounts for vaporization effects on turbulence-chemistry interaction.

The residual gas in SI engines is one of important factors on emission and performance such as combustion stability. With high residual gas fractions, flame speed and maximum combustion temperature are decreased and there are deeply related with combustion stability, especially at Idle and NOx emission at relatively high engine load. Therefore, there is a need to characterize the residual gas fraction as a function of the engine operating parameters. A model for predicting the residual gas fraction has been formulated in this paper. The model accounts for the contribution due to the back flow of exhaust gas to the cylinder during valve overlap and it includes in-cylinder pressure prediction model during valve overlap. The model is derived from the one dimension flow process during overlap period and a simple ideal cycle model.

NO2 is an effective soot oxidizer operating at lower temperatures than O2. The effect of pure NO2 on soot oxidation was evaluated and compared with the gas treated by plasma, which initially consisted of NO, O2, and hydrocarbons. The cutout of a commercial DPF was used and the pressure difference across the DPF was monitored for an hour. The concentration of NO/NO2, CO, CO2 at the outlet of the DPF was measured as a function of time. CO and CO2 concentration was measured periodically by gas chromatography. The experiment was performed at 230, 250, 300, 350°C. When NO2 only was used as an oxidizing agent, there was a close relationship between the decrease of the pressure difference across the DPF, the CO and CO2 concentration at the outlet of the DPF, and the back conversion of NO2 to NO.

Plasma-catalyst (Ag, Au/Al2O3) systems were applied to NOx reduction in a model lean-burn engine exhaust gas. Also, DeNOx test of real diesel exhaust gas was performed by plasma-Ag/Al2O3 system. In the case of model exhaust gas, the catalytic activity for NOx reduction was enhanced by the assistance of plasma in the wide temperature range. The NOx conversion efficiency of plasma-Ag/Al2O3 was 40∼90% under the condition of C3 H6 3200ppm (C1/NOx = 5.96) and 10% O2 over the temperature range of 250∼400°C. The plasma-Au/Al2 O3 system showed remarkable low temperature NOx reduction activity at 100∼250°C. The real engine full flow test was performed for 70% of the full load and at engine speed of 1500rpm. NOx removal of 46% from the diesel exhaust gas was achieved by the plasma-Ag/Al2O3 catalyst system at 364°C(C1/NOx = 6). In the case of higher C1/NOx = 10, the NOx conversion increased up to 73% at 381°C. Also, DeNOx engine tests were performed for full load of 1500, 2000 and 2500rpm.

To improve the cold startability of methanol, methanol-butane mixed fuel was experimented. Engine performance and exhaust emissions are obtained with methanol-butane mixed fuel. These characteristics are compared with those of methanol and gasoline. The mixing ratios of methanol and butane are 50:50 (M50), 80:20 (M80), and 90:10 (M90) based on the calorific value. As a result, M90 produces more power than gasoline and more or less than methanol depending on the engine speed and the excess air ratio. Brake horse power of M90 is higher than that of gasoline by 5 - 10 %, and brake specific fuel consumption is smaller than that of gasoline by 17 % to the maximum based on the calorific value. NOx emission concentrations for M90 are lower than those for gasoline and higher than those for methanol because of the effect of butane, CO emission concentrations are somewhat lower than those for methanol and gasoline.

Diesel engines are the most commonly used power train of the freight and public transportations in the world. From the viewpoint of global warming restraint, however, reduction of exhaust emissions from the diesel engine is urgent demand. Stringent emission regulations are being proposed with growing concern on NOx, PM and CO2 emissions. Future emission regulations require advanced emission control technologies, such as SCR(Selective Catalytic Reduction), LNT(Lean NOx Trap) and EGR(Exhaust Gas Recirculation). The EGR is a commonly used technique to reduce emission. In this study, a LP-EGR(Low Pressure Exhaust Gas Recirculation) system was investigated to evaluate its potential on emission reduction and fuel economy improvement, especially for a passenger diesel engine. A 3.0ℓ diesel engine equipped with the LP-EGR system was tested using an in-house control algorithm.

As environmental problems such as global warming are emerging, regulations on automobile exhaust gas are strengthened and various exhaust gas reduction technologies are being developed in various countries in order to satisfy exhaust emission regulations. Exhaust gas recirculation (EGR) technology is a very effective way to reduce nitrogen oxides (NOx) at high combustion temperatures by using EGR coolers to lower the combustion temperature. This EGR cooler has been mass-produced in stainless steel, but it is expensive and heavy. Recently, high efficiency and compactness are required for the EGR cooler to meet the new emission regulation. If aluminum material is applied to the EGR cooler, heat transfer efficiency and light weight can be improved due to high heat transfer coefficient of aluminum compared to conventional stainless steel, but durability is insufficient. Therefore, the aluminum EGR cooler has been developed to enhance performance and durability.

The author's new approach, diesel and gasoline dual fuel powered combustion system based on diesel CI triggered ignition control, provides not only how key ideas extracted from LTC concept could be established in a small bore HSDI turbocharged diesel engine but also which mechanism works to bring almost same benefits as we have experienced in both conventional diesel combustion and LTC based advanced combustion systems like HCCI, PCCI and PPCI combustions. The combustion system presented in the paper physically combines both mixing controlled diesel compression ignition combustion and gasoline premixed charge combustion in one power generation cycle. Gasoline fuel in the system is provided by the conventional gasoline PFI system firstly into the cylinder in which premixed charge spreads out. In compression stroke, the exact amount of diesel fuel is injected into the highly diluted EGR ambient with premixed gasoline charge.

The More precise control of the multiple-injection is required in common-rail injection system of direct injection diesel engine to meet the low NOx emission and optimal PM filter system. The main parameter for obtaining the multiple-injections is the mechanism controlling the injector needle energizing and movement. In this study, a piezo-driven diesel injector, as a new method driven by piezoelectric energy, has been applied with a purpose to develop the analysis model of the piezo actuator to predict the dynamics characteristics of the hydraulic component (injector) by using the AMESim code and to evaluate the effect of this control capability on spray formation processes. Aimed at simulating the hydraulic behavior of the piezo-driven injector, the circuit model has been developed and verified by comparison with the experimental results.

A physics-based model for SCR (Selective Catalytic Reduction) was developed based on five independent SGB (Synthetic Gas Bench) tests. There are NH3 adsorption & desorption test, NO oxidation test, NH3 oxidation test, SCR reaction (NOx & NH3) test and SV (Space Velocity) test. To validate the accuracy of SCR model’s prediction, transient reactor tests were conducted at four different input conditions. A newly developed SCR model showed more than 90% prediction accuracy in transient test conditions in view of cumulative NOx. Validation of SCR model was conducted on 1.6L light duty diesel vehicle in the WLTC (Worldwide Harmonized Light vehicles Test Cycle). Based upon this SCR model, vehicle level SCR calibrations used for urea dosing control were made and validated in the emission test cycles like WLTC.

Selective Non-Catalytic Reduction (SNCR), used to reduce the emissions of nitrogen oxides (NOx), has been a well-established technology in the power plant industry for several decades. The SNCR technique is an aftertreatment strategy based on thermal reduction of NOx at high temperatures. In the compression ignition engine application, the technology has not been applicable due to low exhaust temperatures, which makes the SCR (Selective Catalytic Reduction) system essential for efficient nitrogen oxide reduction to fulfill the environment legislation. For a general Double Compression Expansion Engine (DCEE) the complete expansion cycle is split in two separate cycles, i.e. the engine is a split cycle engine. In the first cylinder the combustion occurs and in the second stage the combustion gas is introduced and further expanded in a low-pressure expansion cylinder. The combustion cylinder is connected with the expansion cylinder through a large insulated high-pressure tank.

Improved Lean NOx Trap (LNT) catalysts with enhanced NH3 generation feature were developed for the small diesel engine. The next generation LNT system needs to perform good NOx conversions over the wide temperature range including below 200°C for urban driving and above 400°C for motorway of real road driving. However, the extended use of BaO, a component of LNT known to be very effective for high temperature NOx storage, results in the decrease of low temperature NOx conversion due to the degradation of NO oxidation associating with sulfur over time. The improvement of the low-temperature LNT performance is a key requirement for the real driving emission control as the best operation temperature for urea-SCR is above ~250°C. In this study, our next generation LNT with new washcoat architecture has demonstrated improved NOx removal efficiencies under the wider operation temperature window than the current production technology.

The double compression expansion engine (DCEE) is a promising concept for high engine efficiency while fulfilling the most stringent European and US emission legislation. The complete thermodynamic cycle of the engine is split among several cylinders. Combustion of fuel occurs in the combustion cylinder and in the expansion cylinder the exhaust gases are over expanded to obtain high efficiency. A high-pressure tank is installed between these two cylinders for after-treatment purposes. One proposal is to utilize thermal reduction of nitrogen oxides (NOx) in the high-pressure tank as exhaust temperatures can be sufficiently high (above 700 °C) for the selective non-catalytic reduction (SNCR) reactions to occur. The exhaust gas residence time at these elevated exhaust temperatures is also long enough for the chemical reactions, as the volume of the high-pressure tank is substantially larger than the volume of the combustion cylinders.

In diesel engine development, the new technology is coming out to meet the stringent exhaust emission regulation. The regulation demands more eco-friendly vehicles. Euro6c demands to meet not only WLTP mode, but also RDE(Real Driving Emission). In order to satisfy RDE mode, the new technology to reduce emissions should cover all operating areas including High Load & High Speed. It is a big challenge to reduce NOx on the RDE mode and a lot of DeNOx technologies are being developed. So the new DeNOx technology is needed to cover widened operating area and strict acceleration / deacceleration. The existing LNT(Lean NOx Trap) and Urea SCR(Selective Catalytic Reduction) is necessary to meet the typical NEDC or WLTP, but the RDE mode demands the powerful DeNOx technology. Therefore, the LNT & Urea SCR on DPF was developed through this study.

The integration of SCR catalyst into diesel-particulate filter (SDPF) may be one of most viable ways to meet upcoming stringent emission regulations with new test protocols such as Worldwide harmonized Light vehicles Test Cycles (WLTC) and Real Driving Emissions (RDE) requirements. The chabazite-structured SSZ-13-based catalysts enabled the wide implementation of urea-SCR technology for mobile applications due to their robust thermal stability up to 750°C compared to the thermally unstable ZSM-5-based technologies. However, the thermally stable Cu-SSZ-13 catalyst starts losing its initial activity with the increase of aging time at 850°C, where the SCR catalyst on SDPF can possibly be exposed during filter regeneration under a drop-to-idle (DTI) condition. Therefore, more durable SCR catalysts that survive under higher temperatures have been strongly desired in automotive industry. Recently, we found Cu-exchanged high silica LTA revealed an excellent hydrothermal stability.

The worldwide fuel economy compliance level has been tightening, at the same time, LEV-III/Euro-6d/China-6/BS-6 regulations for NMOG and NOx emissions are being introduced or already effective. Therefore, intensive research effort has been conducted in order to improve the fuel efficiency of passenger cars and reduce exhaust emission. In response to these demands, turbocharged gasoline direct injection (TGDI) engine is being introduced for gasoline vehicles in consideration of fuel efficiency improvement, high output and driving performance compared to naturally aspirated (NA) engine. However, due to its larger thermal mass from the turbo hardware in the exhaust, it suffers from the cold-start emission. The main hazardous gases emitted from gasoline vehicles are CO, HC and NOx, and a three-way catalyst (TWC) is installed for the purification of these harmful emissions.

Generally, vehicles do not need power during deceleration. Therefore, the fuel efficiency can be improved by stopping the fuel injection in this period. However, when the fuel cut is activated, NOx is emitted immediately after fuel cut. During the fuel cut period, a large amount of fresh air flows into the catalytic converter installed on a vehicle since there is no combustion. Thus, the catalytic materials are converted into an oxidizing atmosphere. As a result, NOx purification performance of the catalyst deteriorates, and eventually NOx is emitted when combustion restarts. The quantity of NOx in this period is relatively small. However, in case of increasing fuel cuts, emission problem could arise. Therefore, in order to meet the stringent regulation such as LEV III-SULEV20 or 30, the number of fuel cuts need to be limited. The problem is that this strategy leads to a disadvantage of fuel efficiency.