Journal Article
Long-Term Validation of Rapid Impedance Spectrum Measurements as a Battery State-of-Health Assessment Technique
2013-04-08
2013-01-1524
The objective of this study was to assess the long-term capability and impact of a rapid, in-situ impedance measurement technique known as Harmonic Compensated Synchronous Detection. This technique consists of a sum-of-sines excitation signal that includes a targeted selection of frequencies and only requires one period of the lowest frequency. For a given frequency range of 0.1 Hz to approximately 2 kHz, the measurement duration would only be ten seconds. The battery response is captured and synchronously detected for impedance spectra measurements. This technique was compared to laboratory-based performance degradation measurements using commercially available lithium-ion cells. The cells were aged for 150,000 cycles at accelerated rates using temperatures of 40 and 50°C. Every 30,000 cycles, cycle-life testing was interrupted to gauge degradation at the reference temperature of 30°C.
