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This paper presents the experimental investigation of combustion stability and nano-particle emissions from the CNG-diesel RCCI engine. A modified automotive diesel engine is used to operate in RCCI combustion mode. An open ECU is used to control the low and high reactivity fuel injection events. The engine is tested for fixed engine speed and two different engine load conditions. The tests performed for various port-injected CNG masses and diesel injection timings, including single and double diesel injection strategy. Several consecutive engine cycles are recorded using in-cylinder combustion pressure measurement system. Statistical and return map techniques are used to investigate the combustion stability in the CNG-diesel RCCI engine. Differential mobility spectrometer is used for the measurement of particle number concentration and particle-size and number distribution. It is found that advanced diesel injection timing leading to higher cyclic combustion variations.