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In order to reduce engine out CO2 emissions it is a main subject to find new alternative fuels out of renewable sources. For this paper, several fuels were selected which can be produced out of biomass or with hydrogen which is generated directly via electrolysis with electricity from renewable sources. All fuels are compared to conventional diesel fuel and two diesel surrogates. It is well known that there can be a large effect of fuel properties on mixture formation and combustion, which may result in a completely different engine performance compared to the operation with conventional diesel fuels. Mixture formation and ignition behavior can also largely affect the pollutant formation. The knowledge of the combustion behavior is also important to design new engine geometries or implement new calibrations for an existing engine. The fuel properties of the investigated fuels comprise a large range, for example in case of the derived cetane number, from below 30 up to 100.

In order to reduce engine out CO2 emissions, it is a main subject to find new alternative fuels from renewable sources. For identifying the specification of an optimized fuel for engine combustion, it is essential to understand the details of combustion and pollutant formation. For obtaining a better understanding of the flame behavior, dynamic structure large eddy simulations are a method of choice. In the investigation presented in this paper, an n-heptane spray flame is simulated under engine relevant conditions starting at a pressure of 50 bar and a temperature of 800 K. Measurements are conducted at a high-pressure vessel with the same conditions. Liquid penetration length is measured with Mie-Scatterlight, gaseous penetration length with Shadowgraphy and lift-off length as well as ignition delay with OH*-Radiation. In addition to these global high-speed measurement techniques, detailed spectroscopic laser measurements are conducted at the n-heptane flame.