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In this study the fuel influence of several bio-fuel candidates on homogeneous engine combustion systems with direct injection is investigated. The results reveal Ethanol and 2-Butanol as the two most knock-resistant fuels. Hence these two fuels enable the highest efficiency improvements versus RON95 fuel ranging from 3.6% - 12.7% for Ethanol as a result of a compression ratio increase of 5 units. Tetrahydro-2-methylfuran has a worse knock resistance and a decreased thermal efficiency due to the required reduction in compression ratio by 1.5 units. The enleanment capability is similar among all fuels thus they pose no improvements for homogeneous lean burn combustion systems despite a significant reduction in NOX emissions for the alcohol fuels as a consequence of lower combustion temperatures.

For gasoline engines controlled autoignition provides the vision of enabling the fuel consumption benefit of stratified lean combustion systems without the drawback of additional NOx aftertreatment. In this study the potential of certain biofuels on this combustion system was assessed by single-cylinder engine investigations using the exhaust strategy "combustion chamber recirculation" (CCR). For the engine testing sweeps in the internal EGR rate with different injection strategies as well as load sweeps were performed. Of particular interest was to reveal fuel differences in the achievable maximal load as well as in the NOx emission behavior. Additionally, experiments with a shock tube and a rapid compression machine were conducted in order to determine the ignition delay times of the tested biofuels concerning controlled autoignition-relevant conditions.