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Catalysts that have been extensively investigated for direct soot oxidation in Catalyzed Diesel Particulate Filters (CDPFs) are very often based on mixed oxides of ceria with zirconia, materials known to assist soot oxidation by providing oxygen to the soot through an oxidation-reduction catalytic cycle. Besides the catalyst composition that significantly affects soot oxidation, other parameters such as morphological characteristics of the catalyst largely determined by the synthesis technique followed, as well as the reagents used in the synthesis may also contribute to the activity of the catalysts. In the present work, two ceria-zirconia catalyst samples with different zirconia content were subjected to different milling protocols with the aim to shift the catalyst particle size distribution to lower values. The produced catalysts were then evaluated with respect to their soot oxidation activity following established protocols from previous works.

Evolving marine diesel emission regulations drive significant reductions of nitrogen oxide (NOx) emissions. There is, therefore, considerable interest to develop and validate Selective Catalytic Reduction (SCR) converters for marine diesel NOx emission control. Substrates in marine applications need to be robust to survive the high sulfur content of marine fuels and must offer cost and pressure drop benefits. In principle, extruded honeycomb substrates of higher cell density offer benefits on system volume and provide increased catalyst area (in direct trade-off with increased pressure drop). However higher cell densities may become more easily plugged by deposition of soot and/or sulfate particulates, on the inlet face of the monolithic converter, as well as on the channel walls and catalyst coating, eventually leading to unacceptable flow restriction or suppression of catalytic function.

Catalyzed Diesel Particulate Filters (CDPFs) continue to be an important emission control solution and are now also expanding to include additional functionalities such as gas species oxidation (such as CO, hydrocarbons and NO) and even storage phenomena (such as NOx and NH3 storage). Therefore an in depth understanding of the coupled transport - reaction phenomena occurring inside a CDPF wall can provide useful guidance for catalyst placement and improved accuracy over idealized effective medium 1-D and 0-D models for CDPF operation. In the present work a previously developed 3-D simulation framework for porous materials is applied to the case of NO-NO2 turnover in a granular silicon carbide CDPF. The detailed geometry of the CDPF wall is digitally reconstructed and micro-simulation methods are used to obtain detailed descriptions of the concentration and transport of the NO and NO2 species in the reacting environment of the soot cake and the catalyst coated pores of the CDPF wall.

The increasing need for controlled diesel engine emissions and the strict regulations in the abatement of diesel exhaust products lead to an ever increasing use of Diesel Particulate Filters (DPFs) in OEM applications. The periodic regeneration of DPFs (oxidation of soot particles) demands temperatures that rarely appear during engine operation. It is therefore necessary to employ direct or indirect catalytic measures. In the present work, the development and synthesis via aerosol-based routes, of nanostructured base metal oxides for direct soot oxidation, along with their characterization and their evaluation in engine exhaust is described. The synthesized powders were characterized with respect to their phase composition and morphology. XRD, SEM and TEM analysis have shown the nanostructured character of the powders, while Raman spectroscopy was employed for the preliminary characterization of the materials surface chemistry.

Current progress in the development of diesel engines substantially contributes to the reduction of NOx and Particulate Matter (PM) emissions but will not succeed to eliminate the application of Diesel Particulate Filters (DPFs) in the future. In the past we have introduced a Multi-Functional Reactor (MFR) prototype, suitable for the abatement of the gaseous and PM emissions of the Low Temperature Combustion (LTC) engine operation. In this work the performance of MFR prototypes under both conventional and advanced combustion engine operating conditions is presented. The effect of the MFR on the fuel penalty associated to the filter regeneration is assessed via simulation. Special focus is placed on presenting the performance assessment in combination with the existing differences in the morphology and reactivity of the soot particles between the different modes of diesel engine operation (conventional and advanced). The effect of aging on the MFR performance is also presented.

In this paper, a methodology is presented to study the influence of thermal aging on catalytic DPF performance using small scale coated filter samples and side-stream reactor technology. Different mixed oxide catalytic coating families are examined under realistic engine exhaust conditions and under fresh and thermally aged state. This methodology involves the determination of filter physical (flow resistance under clean and soot loaded conditions and filtration efficiency) and chemical properties (reactivity of catalytic coating towards direct soot oxidation). Thermal aging led to sintering of catalytic nanoparticles and to changes in the structure of the catalytic layer affecting negatively the filter wall permeability, the clean filtration efficiency and the pressure drop behavior during soot loading. It also affected negatively the catalytic soot oxidation activity of the catalyzed samples.

Trends towards lower vehicle fuel consumption and smaller environmental impact will increase the share of Diesel hybrids and Diesel Range Extended Vehicles (REV). Because of the Diesel engine presence and the ever tightening soot particle emissions, these vehicles will still require soot particle emissions control systems. Ceramic wall-flow monoliths are currently the key players in the Diesel Particulate Filter (DPF) market, offering certain advantages compared to other DPF technologies such as the metal based DPFs. The latter had, in the past, issues with respect to filtration efficiency, available filtration area and, sometimes, their manufacturing cost, the latter factor making them less attractive for most of the conventional Diesel engine powered vehicles. Nevertheless, metal substrate DPFs may find a better position in vehicles like Diesel hybrids and REVs in which high instant power consumption is readily offered enabling electrical filter regeneration.

The understanding of deactivation mechanisms is critical to the development of NOx adsorber catalysts with improved durability. The thermal deactivation of a state-of-the-art Pt/Rh based NOx adsorber catalyst is evaluated following oven agings at 800 and 900°C. Sulfur poisoning during lean/rich cycling is studied as a function of catalyst inlet temperature and SO2 concentration. Complementing these studies utilizing synthetic exhaust gas compositions, deactivation resulting from three different engine aging schedules is examined. The performance of engine-aged catalysts is evaluated as received, and following desulfurization procedures differing in inlet temperature and air/fuel ratio. The impact of aging schedules on NOx adsorption and three-way catalyst function is discussed with respect to precious metal dispersion, washcoat sintering, as well as sulfur build-up and oil-derived poisonings.

The transition from Euro2 to Euro3 emission standards for passenger diesel vehicles requires very good hydrocarbon control coupled with moderate, passive NOx reduction. In some cases, CO and PM conversion is also required. Passive NOx reduction, that is, selective catalytic reduction of NOx by hydrocarbons without delivery of hydrocarbon specifically for this purpose, requires good management of a scarce hydrocarbon resource. At the same time, increased requirements for HC control demand that unconverted HC be further minimized. Appropriately designed lean NOx catalysts with hydrocarbon adsorber capabilities offer very good HC control with moderate NOx reduction performance when fresh. However, certain zeolite structures appear quite unstable under high temperature aging, yielding significant declines in aged NOx performance. Instabilities can be avoided through proper choice of molecular sieve structure and composition, together with suitable washcoat structure.

Increasing interest in lean NOx catalysis at temperatures between about 300-550°C has led to development of catalytic materials with thermal durability considerably improved over academic benchmark catalysts such as Cu-ZSM-5. The breaching of thermal durability barriers brings new obstacles into focus. Practical implementation of high temperature HC-based lean NOx catalysis entails delivery of hydrocarbons to the catalyst inlet at high temperatures. We have found initially unexpected, but scientifically precedented, phenomena regarding gas-phase kinetic instability of hydrocarbons in diesel exhaust atmospheres above 300°C. Around 300°C, homogeneous hydrocarbon oxidation can begin to occur. Rates of oxidation decrease between about 350-450°C and then increase again at higher temperatures. Some apparent NOx disappearance that does not correspond to chemical reduction of NOx can also occur homogeneously throughout this temperature range.

Since the CO2 emissions of passenger car traffic and their greenhouse potential are in the public interest, natural gas (CNG) is discussed as an attractive alternative fuel. The engine concepts that have been applied to date are mainly based upon common gasoline engine technology. In addition, in mono-fuel applications, it is made use of an increased compression ratio -thanks to the RON (Research Octane Number) potential of CNG-, which allows for thermodynamic benefits. This paper presents advanced engine concepts that make further use of the potentials linked to CNG. Above all, the improved knock tolerance, which can be particularly utilized in turbocharged engine concepts. For bi-fuel (CNG/gasoline) power trains, the realization of variable compression ratio is of special interest. Moreover, lean burn technology is a perfect match for CNG engines. Fuel economy and emission level are evaluated basing on test bench and vehicle investigations.

The aggressive reduction of future diesel engine NOx emission limits forces the heavy- and light-duty diesel engine manufacturers to develop means to comply with stringent legislation. As a result, different exhaust emission control technologies applicable to NOx have been the subject of many investigations. One of these systems is the NOx adsorber catalyst, which has shown high NOx conversion rates during previous investigations with acceptable fuel consumption penalties. In addition, the NOx adsorber catalyst does not require a secondary on-board reductant. However, the NOx adsorber catalyst also represents the most sulfur sensitive emissions control device currently under investigation for advanced NOx control. To remove the sulfur introduced into the system through the diesel fuel and stored on the catalyst sites during operation, specific regeneration strategies and boundary conditions were investigated and developed.

The modern engine design process is characterized by shorter development cycles and a reduced number of prototypes. However, simultaneously exhaust after-treatment and emission testing is becoming increasingly more sophisticated. The introduction of predictive real-time simulation tools that represent the entire powertrain can likely contribute to improving the efficiency of the calibration process. Engine models, which are purely based on physical first principles, are usually not capable of real-time applications, especially if the simulation is focused on cold start and warm-up behavior. However, the initial data definition for the ECU using a Hardware-in-the-Loop (HiL)-Simulator requires a model with both real-time capability and sufficient accuracy. The use of artificial intelligence systems becomes necessary, e.g. neural networks. Methods, structures and the realization of a hybrid real-time model are presented in this paper, which combines physical and neural network models.

Diesel particulate trap regeneration is a complex process involving the interaction of phenomena at several scales. A hierarchy of models for the relevant physicochemical processes at the different scales of the problem (porous wall, filter channel, entire trap) is employed to obtain a rigorous description of the process in a multidimensional context. The final model structure is validated against experiments, resulting in a powerful tool for the computer-aided study of the regeneration behavior. In the present work we employ this tool to address the effect of various spatial non-uniformities on the regeneration characteristics of diesel particulate traps. Non-uniformities may include radial variations of flow, temperature and particulate concentration at the filter inlet, as well as variations of particulate loading. In addition, we study the influence of the distribution of catalytic activity along the filter wall.

With regard to increasingly stringent emission legislation natural gas is gaining interest as an alternate fuel. Concerning mobile application natural gas is often considered to produce potentially lower exhaust emissions compared to diesel and gasoline fuel. Nevertheless, also the exhaust gas of diesel and gasoline fuelled vehicles will be improved by applying advanced technical solutions. The paper reveals the state-of-the-art in exhaust emission behaviour of diesel, gasoline, liquified petroleum gas and natural gas fuelled vehicles. Passenger cars and light-duty trucks will be considered as well as HD-trucks. Emissions include NOx, THC, NMHC, CO, Aldehydes and PAH. In addition CH4 and CO2 emissions are discussed with respect to increasing concern about the greenhouse effect. From the viewpoint of the HD-engines the alternate fuels Dimethylether (DME) and Diesel/water-Emulsion are also considered.

Despite the great effort devoted to the modeling of the operation of catalytic DPFs, even today very simple expressions are used for the soot oxidation rate. In the relevant to DPF operation case of a gas phase rich in oxygen, the structure of the soot-catalyst geometry and its evolution during oxidation determines the reaction rate. An extensive set of controlled experiments (isothermal or with linear temperature increase) using fuel borne catalysts and catalytic coatings has been performed in order to obtain corresponding soot oxidation rate-conversion curves. The shape of the resulting curves cannot be described by the typical theories for solid phase reactions posing the need for microstructural models for the micromechanics of soot catalyst interactions.

Nowadays diesel particulate filters (DPFs) with catalyst coatings have assumed one of the most significant roles for road vehicle emission control. DPFs made of re-crystallized SiC (SiC-DPFs) have guaranteed the soot filtration efficiency for the current regulation. In order to further enhance their filtration efficiency, even though a higher porosity and larger pore size must be adopted for sufficient catalyst coating capacity, we developed the concept of a filtration layer on the DPF inlet channel walls and researched its performance both theoretically and experimentally. First of all, models of the new filtration layer, closely resembling the real one made in the laboratory, were digitally reconstructed and soot deposition simulations were conducted.

The EU emission standards for new rail Diesel engines are becoming even more stringent. EGR and SCR technologies can both be used to reduce NOx emissions; however, the use of EGR is usually accompanied by an increase in PM emissions and may require a DPF. On the other hand, the use of SCR requires on-board storage of urea. Thus, it is necessary to study these trade-offs in order to understand how these technologies can best be used in rail applications to meet new emission standards. The present study assesses the application of these technologies in Diesel railcars on a quantitative basis using one and three dimensional numerical simulation tools. In particular, the study considers a 560 kW railcar engine with the use of either EGR or SCR based solutions for NOx reduction. The NOx and PM emissions performances are evaluated over the C1 homologation cycle.

This paper describes the durability of the filtration layer integrated into Diesel Particulate Filters (DPFs) that we have developed to ensure low pressure loss and high filtration efficiency performances which also meet emission regulations. DPF samples were evaluated in regards to their performance deterioration which is brought about by ash loading and uncontrolled regeneration cycles, respectively. Ash was synthesized by using a diesel fuel/lubrication oil mixture and was trapped up to a level which corresponded to a 240,000km run, into the DPFs both with and without the filtration layer. Afterwards, aged-DPFs were measured with respect to their permeability, pressure loss, filtration efficiency, as well as soot oxidation speed using suitable analytical methods. Consequently, it has been confirmed that there was no noteworthy deterioration of the performances in the DPF with the filtration layer.

The paper presents the results of the STYFF-DEXA project which has delivered an attractive computational approach based on detailed treatment of the filtration and regeneration processes inside diesel particulate foam filter materials. The new approach can provide accurate macroscopic material parameters by utilizing tomographic data and novel algorithms to reconstruct three-dimensional digital representations of the foam material microstructure. The Lattice-Boltzmann (LB) Method is used as a basis for computing the flow within the foam pores. The latter is coupled to sub-models of particle transport/deposition and size distribution based on the very efficient Method of Moments which employs a probability density function representation of the suspended soot. Additionally, acoustics modelling functionality has been developed which permits the evaluation of the engine noise attenuation capabilities of the foams and similar microstructures.