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Catalyzed Particulate Filter Passive Oxidation Study with ULSD and Biodiesel Blended Fuel

2012-06-18
The development of PM and NOx reduction system with the combination of DOC included DPF and SCR catalyst in addition to the AOC sub-assembly for NH3 slip protection is described. DPF regeneration strategy and manual regeneration functionality are introduced with using ITH, HCI device on the EUI based EGR, VGT 12.3L diesel engine at the CVS full dilution tunnel test bench. With this system, PM and NOx emission regulation for JPNL was satisfied and DPF regeneration process under steady state condition and transient condition (JE05 mode) were successfully fulfilled. Manual regeneration process was also confirmed and HCI control strategy was validated against the heat loss during transient regeneration mode. Presenter Seung-il Moon
Technical Paper

An Analytical Energy-budget Model for Diesel Droplet Impingement on an Inclined Solid Wall

2020-04-14
2020-01-1158
The study of spray-wall interaction is of great importance to understand the dynamics that occur during fuel impingement onto the chamber wall or piston surfaces in internal combustion engines. It is found that the maximum spreading length of an impinged droplet can provide a quantitative estimation of heat transfer and energy transformation for spray-wall interaction. Furthermore, it influences the air-fuel mixing and hydrocarbon and particle emissions at combusting conditions. In this paper, an analytical model of a single diesel droplet impinging on the wall with different inclined angles (α) is developed in terms of βm (dimensionless maximum spreading length, the ratio of maximum spreading length to initial droplet diameter) to understand the detailed impinging dynamic process.
Journal Article

Impact of Carbonaceous Compounds Present in Real-World Diesel Exhaust on NOx Conversion over Vanadia-SCR Catalyst

2016-04-05
2016-01-0921
Exposure of hydrocarbons (HCs) and particulate matter (PM) under certain real-world operating conditions leads to carbonaceous deposit formation on V-SCR catalysts and causes reversible degradation of its NOx conversion. In addition, uncontrolled oxidation of such carbonaceous deposits can also cause the exotherm that can irreversibly degrade V-SCR catalyst performance. Therefore carbonaceous deposit mitigation strategies, based on their characterization, are needed to minimize their impact on performance. The nature and the amount of the deposits, formed upon exposure to real-world conditions, were primarily carried out by the controlled oxidation of the deposits to classify these carbonaceous deposits into three major classes of species: i) HCs, ii) coke, and iii) soot. The reversible NOx conversion degradation can be largely correlated to coke, a major constituent of the deposit, and to soot which causes face-plugging that leads to decreased catalyst accessibility.
Technical Paper

Optimization of Diesel Engine and After-treatment Systems for a Series Hybrid Forklift Application

2020-04-14
2020-01-0658
This paper investigates an optimal design of a diesel engine and after-treatment systems for a series hybrid electric forklift application. A holistic modeling approach is developed in GT-Suite® to establish a model-based hardware definition for a diesel engine and an after-treatment system to accurately predict engine performance and emissions. The used engine model is validated with the experimental data. The engine design parameters including compression ratio, boost level, air-fuel ratio (AFR), injection timing, and injection pressure are optimized at a single operating point for the series hybrid electric vehicle, together with the performance of the after-treatment components. The engine and after-treatment models are then coupled with a series hybrid electric powertrain to evaluate the performance of the forklift in the standard VDI 2198 drive cycle.
Journal Article

Investigation of the Impact of Real-World Aging on Diesel Oxidation Catalysts

2012-04-16
2012-01-1094
Real-world operation of diesel oxidation catalysts (DOCs), used in a variety of aftertreatment systems, subjects these catalysts to a large number of permanent and temporary deactivation mechanisms. These include thermal damage, induced by generating exotherm on the catalyst; exposure to various inorganic species contained in engine fluids; and the effects of soot and hydrocarbons, which can mask the catalyst in certain operating modes. While some of these deactivation mechanisms can be accurately simulated in the lab, others are specific to particular engine operation regimes. In this work, a set of DOCs, removed from prolonged service in the field, has been subjected to a detailed laboratory study. Samples obtained from various locations in these catalysts were used to characterize the extent and distribution of deactivation.
Technical Paper

The Effect of a Ceramic Particulate Trap on the Particulate and Vapor Phase Emissions of a Heavy-Duty Diesel Engine

1991-02-01
910609
Exhaust emissions were characterized from a Cummins LTA10 heavy-duty diesel engine operated at two EPA steady-state modes with and without an uncatalyzed Corning ceramic particulate trap. The regulated emissions of nitrogen oxides (NOx), hydrocarbons (HC), and total particulate matter (TPM) and its components as well as the unregulated emissions of PAH, nitro-PAH, mutagenic activity and particle size distributions were measured. The consistently significant effects of the trap on regulated emissions included reductions of TPM and TPM-associated components. There were no changes in NOx and HC were reduced only at one operating condition. Particle size distribution measurements showed that nuclei-mode particles were formed downstream of the trap, which effectively removed accumulation-mode particles. All of the mutagenicity was direct-acting and the mutagenic activity of the XOC was approximately equivalent to that of the SOF without the trap.
Journal Article

Fuel Quality and Diesel Injector Deposits

2012-09-10
2012-01-1693
Internal deposits formed within the fuel injection system have been widely reported in the literature. Several root causes exist, with many deposits consisting of more than one material. The final chemistry depends on the availability of trace fuel contaminants and additives and to a lesser extent hydrocarbon/FAME stability and operating conditions. The present paper identifies the primary deposit morphologies, along with the typical root cause. Metal carboxylate salts, also known as metal soaps are most widely reported and are easily recreated under controlled conditions using compounds present at trace concentrations in some market fuels. The salting reaction may occur at low temperatures in the fuel supply system. It is proposed that the resulting fuel insoluble salt molecules are transported as reverse micelles, occasionally plugging filters but more commonly passing to the high pressure injection system.
Journal Article

Internal Fuel Injector Deposits

2011-08-30
2011-01-1925
The need for improved emissions and fuel economy are placing increasingly severe performance requirements on compression ignition engines. These are satisfied in part by advanced fuel injection equipment that provide multiple injections and increased injection pressures along with higher operating temperature. Fuel composition is also changing, with increased use of non-traditional feedstocks combined with a range of additive chemistries to restore or enhance fuel quality. Within this environment, a number of worldwide automotive companies have noted a trend towards increased Internal Injector Deposits (IID). Little quantitative information to understand the root cause is available, largely due to difficulty in reproducing the issue under controlled conditions. The present study details the results of an accelerated test methodology, which is used to evaluate the interrelated effects of fuel composition and operating environment.
Technical Paper

Calibrating and Protecting Microphones to Allow Acoustic Measurements in Hazardous Environments

2009-05-19
2009-01-2163
Performing acoustic measurements on or near engines, transmissions, as well as in other circumstances where the environment is hazardous and harsh for microphones requires special precautions. Fluids inevitably leak, and the possibility of transducer damage can be very high without proper protection. Properly protecting microphones during testing allows for consistent data quality in these hazardous and difficult environments. While this paper will present the use of a 5 mil Nitrile cover which protects against many fluids within the scope of automotive testing, including water, hydrocarbons, and alcohols, as well as having good heat resistance and high strength, the concepts developed are applicable to other types of microphone protective mechanisms. Acoustic sensitivity was measured and used to calculate the change of the microphone's response after the treatment is applied, as well as after being exposed to various contaminants.
Technical Paper

Evaluation of Fischer-Tropsch Fuel Performance in Advanced Diesel Common Rail FIE

2010-10-25
2010-01-2191
An increasing range of conventional and unconventional feed stocks will be used to produce fuel of varying chemical and physical properties for use in compression ignition engines. Fischer-Tropsh (F-T) technology can be used to produce fuels of consistent quality from a wide range of feed stocks. The present study evaluates the performance of F-T fuel in advanced common rail fuel injection systems. Laboratory scale tests are combined with proprietary engine and electrically driven common rail pump hydraulic rig tests to predict long-term performance. The results obtained indicate that the performance of F-T fuel is at least comparable to conventional hydrocarbon fuels and superior in a number of areas. In particular, the lubricity of F-T fuel was improved by addition of lubricity additives or FAME, with minimal wear under a wide range of operating conditions and temperatures.
Technical Paper

Oxidation Catalytic Converter and Emulsified Fuel Effects on Heavy-Duty Diesel Engine Emissions

2002-03-04
2002-01-1277
A study was conducted to assess the effects of a water-diesel fuel emulsion with and without an oxidation catalytic converter (OCC) on steady-state heavy-duty diesel engine emissions. Two OCCs with different metal loading levels were used in this study. A 1988 Cummins L10-300 heavy-duty diesel engine was operated at the rated speed of 1900 rpm and at 75% and 25% load conditions (EPA modes 9 and 11 respectively) of the 13 mode steady-state test as well as at idle. Raw exhaust emissions' measurements included total hydrocarbons (HC), oxides of nitrogen (NOx) and nitric oxide (NO). Diluted exhaust measurements included total particulate matter (TPM) and its primary constituents, the soluble organic (SOF), sulfate (SO42-) and the carbonaceous solids (SOL) fractions. Vapor phase organic compounds (XOC) were also analyzed. The SOF and XOC samples were analyzed for selected polynuclear aromatic hydrocarbons (PAHs).
Technical Paper

A Fundamental Consideration on NOx Adsorber Technology for DI Diesel Application

2002-10-21
2002-01-2889
Diesel engines are far more efficient than gasoline engines of comparable size, and emit less greenhouse gases that have been implicated in global warming. In 2000, the US EPA proposed very stringent emissions standards to be introduced in 2007 along with low sulfur (< 15 ppm) diesel fuel. The California Air Resource Board (CARB) has also established the principle that future diesel fueled vehicles should meet the same low emissions standards as gasoline fueled vehicles and the EPA followed suit with its Tier II emissions regulation. Achieving such low emissions cannot be done through engine development and fuel reformulation alone, and requires application of NOx and particulate matter (PM) aftertreatment control devices. There is a widespread consensus that NOx adsorbers and particulate filter are required in order for diesel engines to meet the 2007 emissions regulations for NOx and PM. In this paper, the key exhaust characteristics from an advanced diesel engine are reviewed.
Technical Paper

Reactor System with Diesel Injection Capability for DOC Evaluations

2018-04-03
2018-01-0647
Plug flow reactors, simulating engine exhaust gas, are widely used in emissions control research to gain insight into the reaction mechanisms and engineering aspects that controls activity, selectivity, and durability of catalyst components. The choice of relevant hydrocarbon (HC) species is one of the most challenging factor in such laboratory studies, given the variety of compositions that can be encountered in different application scenarios. Furthermore, this challenge is amplified by the experimental difficulties related to introducing heavier and multi-component HCs and analyzing the reaction products.
Technical Paper

Experimental and Kinetic Modeling of Degreened and Aged Three-way Catalysts: Aging Impact on Oxygen Storage Capacity and Catalyst Performance

2018-04-03
2018-01-0950
The aging impact on oxygen storage capacity (OSC) and catalyst performance was investigated on one degreened and one aged (hydrothermally aged at 955 °C for 50 h) commercial three-way catalyst (TWC) by experiments and modeling. The difference of OSC between the degreened and aged TWCs was dependent on catalyst temperature. The largest difference was found at 600 °C, at which the amount of OSC decreased by 45.5%. Catalyst performance was evaluated through lightoff tests at two simulated engine exhaust conditions (lean and rich) on a micro-reactor. The aging impact on the catalyst performance was different under lean and rich environments and investigated separately. At the lean condition, oxidation of CO and C3H6 was significantly suppressed while oxidation of C3H8 was relatively less degraded. At the rich condition, the inhibition effect was more pronounced on the aged TWC and inhibiting hydrocarbon species from C3H6 partial oxidation can survive at temperatures up to 450 °C.
Technical Paper

A Combustion Model for Multi-Component Fuels Based on Reactivity Concept and Single-Surrogate Chemistry Representation

2018-04-03
2018-01-0260
High fidelity engine simulation requires realistic fuel models. Although typical automotive fuels consist of more than few hundreds of hydrocarbon species, researches show that the physical and chemical properties of the real fuels could be represented by appropriate surrogate fuel models. It is desirable to represent the fuel using the same set of physical and chemical surrogate components. However, when the reaction mechanisms for a certain physical surrogate component is not available, the chemistry of the unmatched physical component is described using that of a similar chemical surrogate component at the expense of accuracy. In order to reduce the prediction error while maintaining the computational efficiency, a method of on-the-fly reactivity adjustment (ReAd) of chemical reaction mechanism along with fuel re-distribution based on reactivity is presented and tested in this study.
Technical Paper

Catalyzed Particulate Filter Passive Oxidation Study with ULSD and Biodiesel Blended Fuel

2012-04-16
2012-01-0837
A 2007 Cummins ISL 8.9L direct-injection common rail diesel engine rated at 272 kW (365 hp) was used to load the filter to 2.2 g/L and passively oxidize particulate matter (PM) within a 2007 OEM aftertreatment system consisting of a diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF). Having a better understanding of the passive NO₂ oxidation kinetics of PM within the CPF allows for reducing the frequency of active regenerations (hydrocarbon injection) and the associated fuel penalties. Being able to model the passive oxidation of accumulated PM in the CPF is critical to creating accurate state estimation strategies. The MTU 1-D CPF model will be used to simulate data collected from this study to examine differences in the PM oxidation kinetics when soy methyl ester (SME) biodiesel is used as the source of fuel for the engine.
Technical Paper

Experimental and Modeling Study of a Diesel Oxidation Catalyst (DOC) under Transient and CPF Active Regeneration Conditions

2013-04-08
2013-01-1046
In this study, a DOC catalyst was experimentally studied in an engine test cell with a2010 Cummins 6.7L ISB diesel and a production aftertreatment system. The test matrix consisted of steady state, active regeneration with in-cylinder fuel dosing and transient conditions. Conversion efficiencies of total hydrocarbon (THC), CO, and NO were quantified under each condition. A previously developed high-fidelity DOC model capable of predicting both steady state and transient active regeneration gaseous emissions was calibrated to the experimental data. The model consists of a single 1D channel where mass and energy balance equations were solved for both surface and bulk gas regions. The steady-state data were used to identify the activation energies and pre-exponential factors for CO, NO and HC oxidation, while the steady-state active regeneration data were used to identify the inhibition factors. The transient data were used to simulate the thermal response of the DOC.
Technical Paper

A Computational Procedure for Predicting Nitrogen Oxide Emissions from Diesel Engines

2006-04-03
2006-01-0240
The calculation of the Nitrogen Oxide (NO) formation emitted from diesel engines usually involve direct integration of a set of nitrogen chemistry elementary reactions that involve formation and destruction of NO. The primary hydrocarbon chemistry is usually simplified as long as the main species and heat release are predicted correctly. The result of the integration is the net NO formation rate evaluated using the local concentrations and thermodynamic parameters. In the present work a method for calculating NO emissions from diesel engines is proposed that takes into consideration the effect of residence time as a measure of turbulence effects on chemistry. This is based on the assumption that for mixing-limited conditions the turbulent eddy turn-over time can be taken as a characteristic reaction residence time. The proposed procedure depends on a detailed investigation of the primary hydrocarbon combustion chemistry decoupled from the flow-field prediction.
Technical Paper

Evaluation of Diesel Spray-Wall Interaction and Morphology around Impingement Location

2018-04-03
2018-01-0276
The necessity to study spray-wall interaction in internal combustion engines is driven by the evidence that fuel sprays impinge on chamber and piston surfaces resulting in the formation of wall films. This, in turn, may influence the air-fuel mixing and increase the hydrocarbon and particulate matter emissions. This work reports an experimental and numerical study on spray-wall impingement and liquid film formation in a constant volume combustion vessel. Diesel and n-heptane were selected as test fuels and injected from a side-mounted single-hole diesel injector at injection pressures of 120, 150, and 180 MPa on a flat transparent window. Ambient and plate temperatures were set at 423 K, the fuel temperature at 363 K, and the ambient densities at 14.8, 22.8, and 30 kg/m3. Simultaneous Mie scattering and schlieren imaging were carried out in the experiment to perform a visual tracking of the spray-wall interaction process from different perspectives.
Technical Paper

Using a DNS Framework to Test a Splashed Mass Sub-Model for Lagrangian Spray Simulations

2018-04-03
2018-01-0297
Numerical modeling of fuel injection in internal combustion engines in a Lagrangian framework requires the use of a spray-wall interaction sub-model to correctly assess the effects associated with spray impingement. The spray impingement dynamics may influence the air-fuel mixing and result in increased hydrocarbon and particulate matter emissions. One component of a spray-wall interaction model is the splashed mass fraction, i.e. the amount of mass that is ejected upon impingement. Many existing models are based on relatively large droplets (mm size), while diesel and gasoline sprays are expected to be of micron size before splashing under high pressure conditions. It is challenging to experimentally distinguish pre- from post-impinged spray droplets, leading to difficulty in model validation.
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