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Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

In the next years, the upcoming emission legislations are expected to introduce further restrictions on the admittable level of pollutants from vehicles measured on homologation cycles and real drive tests. In this context, the strict control of pollutant emissions at the cold start will become a crucial point to comply with the new regulation standards. This will necessarily require the implementation of novel strategies to speed-up the light-off of the reactions occurring in the after-treatment system, since the cold start conditions are the most critical one for cumulative emissions. Among the different possible technological solutions, this paper focuses on the evaluation of the potential of a burner system, which is activated before the engine start. The hypothetical burner exploits the lean combustion of an air-gasoline mixture to generate a high temperature gas stream which is directed to the catalyst section promoting a fast heating of the substrate.

Methane abatement in the exhaust gas of natural gas engines is much more challenging in respect to the oxidation of other higher order hydrocarbons. Under steady state λ sweep, the methane conversion efficiency is high at exact stoichiometric, and decreases steeply under both slightly rich and slightly lean conditions. Transient lean to rich transitions can improve methane conversion at the rich side. Previous experimental work has attributed the enhanced methane conversion to activation of methane steam reforming. The steam reforming rate, however, attenuates over time and the methane conversion rate gradually converges to the low steady state values. In this work, a reactor model is established to predict steady state and transient transition characteristics of a three-way catalyst (TWC) mounted in the exhaust of a natural gas heavy-duty engine.

The friction estimation at the tire-ground contact is crucial for the active safety of vehicles. Friction estimation is a key problem of vehicle dynamics and the ultimate solution is still unknown. However the proposed approach, based on a simple idea and on a simple hardware, provides an actual solution. The idea is to compare the tire characteristic at a given friction (nominal characteristic) with the actual characteristic that the tire has while running. The comparison among these two characteristics (the nominal one and the actual one) gives the desired friction coefficient. The friction coefficient is expressed in vector form and a number of running parameters are identified. The mentioned comparison is an efficient but complex algorithm based on a mathematical formulation of the tire characteristic. The actual tire characteristic is somehow measured in real time by a relatively simple smart wheel which is able to detect the three forces and the three moments acting at the hub.

Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.

The influence of the inertia properties (mass, centre of gravity location, and inertia tensor) on the dynamic behaviour of the engine-gearbox system of a car is studied in this paper, devoting particular attention to drivability and comfort. The vibration amplitudes and the natural frequencies of the engine-gearbox system have been considered. Additionally, the loads transmitted to the car body have been taken into account. Both the experimental and the theoretical simulations confirmed that the engine-gearbox vibrations in the range 10 - 15 Hz are particularly sensitive to slight variation of the inertia properties. The effects on engine-gearbox vibrations due to half-axles, exhaust system, pipes and inner engine-gearbox fluids have been highlighted.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

In recent years, concerns for environmental pollution and oil price stimulated the demand for vehicles based on technologies alternative to traditional IC engines. Nowadays several carmakers include hybrid vehicles among their offer and first full electric vehicles appear on the market. Among the different layout of the electric power-train, four in-wheel motors appear to be one of the most attractive. Besides increasing the inner room, this architecture offers the interesting opportunity of easily and efficiently distribute the driving/braking torque on the four wheels. This characteristic can be exploited to generate a yaw moment (torque vectoring) able to increase lateral stability and to improve the handling of a vehicle. The present paper presents and compares two different torque vectoring control strategies for an electric vehicle with four in-wheel motors. Performances of the control strategies are evaluated by means of numerical simulations of open and closed loop maneuvers.

The most common automotive drivelines transmit the engine torque to the driven axle through a differential. Semi-active versions of this device ([4], [5], [6]) have been recently conceived to improve vehicle handling at limit and under particular conditions; these differentials are based on the structural scheme of the passive one but they try to manipulate the vehicle dynamics by controlling the distribution of the driving torque on the wheels of the same axle thus generating a yaw moment. Unfortunately a semi-active differential is not able to perform a complete yaw control since the torque can only be transferred from the faster wheel to the slower one; on the other hand, active differentials ([11], [12], [13]) allow to generate the most appropriate yaw moment controlling both the amount of transferred torque and its direction.

In the last years automotive industry has shown a growing interest in exploring the field of vehicle dynamic control, improving handling performances and safety of the vehicle, and actuating devices able to optimize the driving torque distribution to the wheels. These techniques are defined as torque vectoring. The potentiality of these systems relies on the strong coupling between longitudinal and lateral vehicle dynamics established by tires and powertrain. Due to this fact the detailed (and correct) simulation of the dynamic behaviour of the driveline has a strong importance in the development of these control systems, which aim is to optimize the contact forces distribution. The aim of this work is to build an integrated vehicle and powertrain model in order to provide a proper instrument to be used in the development of such systems, able to reproduce the dynamic interaction between vehicle and driveline and its effects on the handling performances.

Tire-road interaction is one of the main concerns in the design of control strategies for active/semi-active differentials oriented to improve handling performances of a vehicle. In particular, the knowledge of the friction coefficient at the tire-road interface is crucial for achieving the best performance in any working condition. State observers and estimators have been developed at the purpose, based on the measurements traditionally carried out on board vehicle (steer angle, lateral acceleration, yaw rate, wheels speed). However, until today, the problem of tire-road friction coefficient estimation (and especially of its maximum value) has not completely been solved. Thus, active control systems developed so far rely on a driver manual selection of the road adherence condition (anyway characterized by a rough and imprecise quality) or on a conservative tuning of the control logic in order to ensure vehicle safety among different tire-road friction coefficients.

The paper presents a new test rig (named RuotaVia) composed basically by a drum (2,6 m diameter), providing a running contact surface for vehicle wheels. A number of measurements on either full vehicles or vehicle sub-systems (single suspension system or single tyre) can be performed. Tire characteristics influencing rollover can be assessed. The steady-state maximum loads are as follows: Radial: 100kN, tangential: 100kN, lateral (axial with respect to the drum): 100kN. The superstructure carrying a measuring hub can excite the wheel under test up to 20 Hz in lateral and vertical directions. The steer angle range is ± 25 deg, the camber range is ± 80 deg. The minimum eigenfrequency of the drum is higher than 90 Hz and its maximum tangential speed is 440 km/h.

Electronic Stability Program (ESP) and Antilock Braking System (ABS) are nowadays a standard equipment for passenger cars. ESP increases vehicle safety by applying differential braking torque to the wheels while cornering, thus it extends the area of intervention of ABS which prevents the wheels from being locked up in emergency braking, especially on low friction road surfaces, allowing the driver to maintain steering control of the vehicle, to avoid obstacles and to reduce vehicle stopping distance on most road surfaces. This paper describes a flexible mechatronic test bench for ESP/ABS Electronic Control Unit (ECU) based on Hardware-In-the-Loop (HIL) simulation technique. It consists of a passenger car hydraulic braking system (from master cylinder to brake calipers), with the ESP/ABS ECU integrated and a flexible real-time platform, which simulates vehicle dynamics.

The paper investigates the interaction between soil and tractor tires through a 2D numerical model. The tire is schematized as a rigid ring presenting a series of rigid tread bars on the external circumference. The outer profile of the tire is divided into a series of elements, each one able to exchange a normal and a tangential contact force with the ground. A 2D soil model was developed to compute the forces at the ground-tire interface: the normal force is determined on the basis of the compression of the soil generated by the sinking of the tire. The soil is modeled through a layer of springs characterized by two different stiffness for the loading (lower stiffness) and unloading (higher stiffness) condition. This scheme allows to introduce a memory effect on the soil which results stiffer and keeps a residual sinking after the passage of the tire. The normal contact force determines the maximum value of tangential force provided before the soil fails.

Active and semi-active suspension systems are widely diffused into the automotive industry. Most of the proposed devices try to achieve a better compromise between handling and comfort requirements by replacing traditional springs, shock absorbers and antiroll bars with active or semi-active actuators allowing to change suspension stiffness and damping according to a suitable control strategy. An alternative way for controlling passenger car suspensions is proposed in this paper. Traditional passive springs and dampers are maintained, while the geometry of the suspension and thus its kinematics is actively varied. By changing the suspension geometry, spring and damper rates are in fact varied, this modifying the vertical load on the tire and/or the vehicle height from the ground.

In the last years, as a response to the more and more restrictive emission legislation, new devices (SRC, DOC, NOx-trap, DPF) have been progressively introduced as standard components of modern after-treatment system for Diesel engines. In addition, the adoption of electrical heating is nowadays regarded with interest as an effective solution to promote the light-off of the catalyst at low temperature, especially at the start-up of the engine and during the low load operation of the engine typical of the urban drive. In this work, a state-of-the-art 48 V electrical heated catalyst is considered, in order to investigate its effect in increasing the abatement efficiency of a standard DOC. The electrical heating device considered is based on a metallic support, arranged in a spiral layout, and it is heated by the Joule effect due to the passage of the electrical current.

In this paper the low temperature reduction process of nitrates stored at high temperatures over model Pt-Ba/Al2O3 LNT catalysts using both H2 and C3H6 is analyzed. The results indicate that over the Pt-Ba/Al2O3 catalyst the reduction of stored NOx with both H2 and C3H6 occurs at temperature below those corresponding to their thermal stability. Accordingly, the reduction process occurs through a Pt-catalyzed surface reaction, which does not involve, as a preliminary step, the thermal decomposition of the adsorbed NOx species. The occurrence of such a pathway also requires the co-presence of the storage element and of the noble metal on the same support.

In the last years the number of electronic controllers of vehicle dynamics applied to chassis components has increased dramatically. They use lookup table of the primary order vehicle global parameters as yaw rate, lateral acceleration, steering angle, car velocity, that define the ideal behavior of the vehicle. They are usually based on PID controllers which compare the actual behavior of every measured real vehicle data to the desired behavior, from look up table. The controller attempts to keep the measured quantities the same as the tabled quantities by using ESP, TC (brakes and throttle), CDC (control shocks absorbers), EDIFF(active differential) and 4WS (rear wheels active toe). The performances of these controls are good but not perfect. The improvement can be achieved by replacement of the lookup tables with a fast vehicle model running in parallel to the real vehicle.

The paper presents some new and unreferenced analytical formulae describing the dynamic behaviour of the suspension system of road or off-road vehicles. The quarter car model (2 degrees of freedom) is considered, the suspension can be either passive or active. Passive suspensions can be simplified as the spring-damper combination or the spring-damper combination with an additional in series spring (representing, e.g., the rubber bushing at the top of a McPherson strut or the rubber bushing at the end joints of the damper). The mathematical system is linear and the excitation is given by a random stationary and ergodic process. The standard deviations in analytical form are given referring to, respectively, the vehicle body acceleration, the relative displacement between sprung and unsprung mass, and the force at the ground. The so called invariant points of the frequency response functions are derived for both active and passive suspension.

This study examines the impact of slip in aero-thermal conditions of supercooled large droplets (SLD) produced in an Icing Wind Tunnel (IWT) on the ice accretion characteristics. The study identifies potential biases in the SLD model development based on IWT data and numerical predictions that assume the SLD to be in aerothermal equilibrium with the IWT airflow. To obtain realistic temperature and velocity data for each droplet size class in the test section of the Braunschweig Icing Wind Tunnel (BIWT), a Lagrangian droplet tracking solver was used within a Monte Carlo framework. Results showed that SLDs experience considerable slips in velocity and temperature due to their higher inertia and short residence time in the Braunschweig IWT. Large droplets were found to be warmer and slower than the flow in the test section, with larger droplets experiencing larger aerothermal slips.