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The effect of ammoniac deoxidizing agent (Urea) on the reduction of NOx produced in the Diesel engine was investigated numerically. Urea desolved in water was directly injected into the engine cylinder during the expansion stroke. The NOx deoxidizing process was described using a simplified chemical kinetic model coupled with the comprehensive kinetics of Diesel oil surrogate combustion. If the technology of DWI (Direct Water Injection) with the later injection timing is supposed to be used, the deoxidizing reactants could be delivered in a controlled amount directly into the flame plume zones, where NOx are forming. Numerical simulations for the Isotta Fraschini DI Diesel engine are carried out using the KIVA-3V code, modified to account for the “co-fuel” injection and reaction with combustion products. The results showed that the amount of NOx could be substantially reduced up to 80% with the injection timing and the fraction of Urea in the solution optimized.

The main objective of the present paper is the application of a detailed kinetic model to study diesel combustion in an optical accessible engine equipped with a common rail injection system. Three different injection schedules made of one to three consecutive injections are considered from both the numerical and the experimental point of view. The numerical model is assessed in such a way to assure its portability with respect to changing injection strategies. The employed detailed kinetic mechanism consists of 305 reactions involving 70 species and is included in the KIVA-3V code. The considered fuel has the liquid phase properties of the diesel oil, the vapor phase properties of C14H28. It is subsequently decomposed into n-heptane and toluene. The chemical solver is based on the use of the reference species technique and on the Partially Stirred Reactor (PaSR) hypothesis. These allow maintaining the computational cost within acceptable limits.

The present paper reports the results of the numerical simulations carried out by means of a modified version of the KIVA-3V code and of the comparison with experimental results obtained by using different optical techniques in a single-cylinder optically accessible diesel engine. The engine is equipped with a commercial four valves cylinder head and a second-generation, Common-Rail injection system. A detailed kinetic model consisting of 283 reactions involving 69 species is applied to simulate the combustion process and the soot and NOx formation. The fuel surrogate model consisting of two constituent components, n-heptane and toluene, approximating the physical and ignition properties of the diesel oil, is considered. The Partially Stirred Reactor (PaSR) assumption is adopted to maintain the computational cost within acceptable limits.