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Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

In the next years, the upcoming emission legislations are expected to introduce further restrictions on the admittable level of pollutants from vehicles measured on homologation cycles and real drive tests. In this context, the strict control of pollutant emissions at the cold start will become a crucial point to comply with the new regulation standards. This will necessarily require the implementation of novel strategies to speed-up the light-off of the reactions occurring in the after-treatment system, since the cold start conditions are the most critical one for cumulative emissions. Among the different possible technological solutions, this paper focuses on the evaluation of the potential of a burner system, which is activated before the engine start. The hypothetical burner exploits the lean combustion of an air-gasoline mixture to generate a high temperature gas stream which is directed to the catalyst section promoting a fast heating of the substrate.

Knock occurrence and fuel enrichment, which is required at high engine speed and load to limit the turbine inlet temperature, are the major obstacles to further increase performance and efficiency of down-sized turbocharged spark ignited engines. A technique that has the potential to overcome these restrictions is based on the injection of a precise amount of water within the mixture charge that can allow to achieve important benefits on knock mitigation, engine efficiency, gaseous and noise emissions. One of the main objectives of this investigation is to demonstrate that water injection (WI) could be a reliable solution to advance the spark timing and make the engine run at leaner mixture ratios with strong benefits on knock tendency and important improvement on fuel efficiency.

Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

Due to the increasing pressure to develop small-size and low-cost after-treatment systems meeting the legislative demands it is desirable to integrate multiple functionalities and exploit any possible synergies. Typical examples include DPFs catalyzed with deNOx catalysts, as well as LNT-SCR combinations using layered coating technology. The present paper deals with the modeling challenges involved for the proper simulation of such advanced concepts. Key role in such advanced simulation attempts has the coupling between diffusion-reaction phenomena, which is captured through intra-layer modeling. All investigations in this paper deal with the application of possible combined LNT-SCR system configurations. The simulation results show that a dual bed LNT- passive SCR configuration offers substantial NOx emissions reductions compared to a single LNT catalyst and effectively controls secondary NH3 emissions produced during LNT regeneration phases.

The small engine for two-wheel vehicles has generally high possibility to be optimized at low speeds and high loads. In these conditions fuel consumption and pollutants emission should be reduced maintaining the performance levels. This optimization can be realized only improving the basic knowledge of the thermo-fluid dynamic phenomena occurring during the combustion process. It is known that, during the fuel injection phase in PFI SI engines, thin films of liquid fuel can form on the valves surface and on the cylinder walls. Successively the fuel films interact with the intake manifold and the combustion chamber gas flow. During the normal combustion process, it is possible to achieve gas temperature and mixture strength conditions that lead to fuel film ignition. This phenomenon can create diffusion-controlled flames that can persist well after the normal combustion event. These flames induce the emission of soot and unburned hydrocarbons.

The rare occurrence during city driving of the exhaust temperature levels required for ceramic trap regeneration without catalytic aid, seems to be the main reason of delay in wide application of the trap. The use of catalysts seems to be more or less necessary. Study of the catalytic activity during trap regeneration had not been very effective so far. This holds equally true for the case of catalyzed trap as for the case of catalytic fuel additives. The lack of a satisfactory theory for the explanation and prediction of catalytic activity, directed international research and development towards the quest of the optimum catalyst, which could support a very simple and low-cost regeneration system. The new approach to the explanation of catalytic activity presented in this paper, denies the above assumption.

Internal combustion engines for vehicle propulsion are more and more sophisticated due to increasingly restrictive environmental regulations. In case of heavy-duty engines, Compressed Natural Gas (CNG) fueling coupled with Three-Way Catalyst (TWC) and Exhaust Gas Recirculation (EGR) can help in meeting the imposed emission limits and preventing from thermal stress of engine components. To cope with the new issues associated with the more complex hardware and to improve powertrain performance and reliability and after-treatment efficiency, the engine control strategies must be reformulated. The paper focuses on the steady-state optimization of control parameters for a heavy-duty engine fueled by CNG and equipped with turbocharger and EGR. The optimization analysis is carried out to design EGR, spark timing and wastegate control, aimed at increasing fuel economy while reducing in-cylinder temperature to prevent from thermal stress of engine components.

All the experimental investigations performed in the last years on newly sold motorcycles, equipped with a three-way catalyst and electronic mixture control, clearly indicate that CO and HC cold additional emissions, if compared with those exhausted in hot conditions, represent an important proportion of total emissions. Consequently, calculation programs for estimating emissions from road transports for air quality modeling in dedicated local areas should take into consideration this effect. From this motivation, an experimental activity on motorcycles cold emissive behavior is being jointly conducted by Istituto Motori of the National Research Council (IM-CNR) and the Department of Mechanic and Energetic (DiME) of the University of Naples.

In the last years, as a response to the more and more restrictive emission legislation, new devices (SRC, DOC, NOx-trap, DPF) have been progressively introduced as standard components of modern after-treatment system for Diesel engines. In addition, the adoption of electrical heating is nowadays regarded with interest as an effective solution to promote the light-off of the catalyst at low temperature, especially at the start-up of the engine and during the low load operation of the engine typical of the urban drive. In this work, a state-of-the-art 48 V electrical heated catalyst is considered, in order to investigate its effect in increasing the abatement efficiency of a standard DOC. The electrical heating device considered is based on a metallic support, arranged in a spiral layout, and it is heated by the Joule effect due to the passage of the electrical current.

The aim of this study is to investigate the effect of ethanol-gasoline mixtures on cold emissive behavior of commercial motorcycles. For the newly sold motorcycles, equipped with a three-way catalyst and electronic mixture control, CO and HC cold additional emissions, if compared with those exhausted in hot conditions, represent an important proportion of total emissions. On the other hand, ethanol is known as potential alcohol alternative fuel for spark ignition engines, which can be blended with gasoline to increase oxygen content and then to decrease emissions. From this explanations, a research on cold start emissions of motorcycles using ethanol-gasoline mixtures was conducted.

The successful design and especially the control of the SCR system is a challenging process that can be supported by the application of simulation tools. As a first step, we employ physico-chemically informed ‘off-line’ models that are calibrated with the help of targeted small- and full-scale tests. Despite their high level of sophistication, this SCR model is able to be integrated in a control-oriented simulation software platform and connected to other powertrain simulation blocks. The target is to use this simulation platform as a virtual environment for the development and optimization of SCR control strategies. The above process is demonstrated in the case of a passenger car SCR. The model is calibrated at both fresh and aged catalyst condition and validated using experimental data from the engine bench under a wide variety of operating conditions. Next, the calibrated model was coupled with embedded control models, developed for Euro 6 passenger car powertrains.

In this paper the low temperature reduction process of nitrates stored at high temperatures over model Pt-Ba/Al2O3 LNT catalysts using both H2 and C3H6 is analyzed. The results indicate that over the Pt-Ba/Al2O3 catalyst the reduction of stored NOx with both H2 and C3H6 occurs at temperature below those corresponding to their thermal stability. Accordingly, the reduction process occurs through a Pt-catalyzed surface reaction, which does not involve, as a preliminary step, the thermal decomposition of the adsorbed NOx species. The occurrence of such a pathway also requires the co-presence of the storage element and of the noble metal on the same support.

Multi-wavelength ultraviolet-visible extinction spectroscopy was applied to follow the evolution of fuel vapor injected by post-injection along the exhaust line of a common-rail turbocharged direct-injection diesel engine at moderate speed and load. The exhaust line was specifically designed and customized to allow the insertion of the optical access upstream of the Diesel Oxidation Catalyst. During the experimental campaign, the engine was fuelled with commercial B5 fuel and a B30 v/v blend of RME and ultra low sulfur diesel, monitoring emissions upstream of the catalyst and exhaust gas temperature across the catalyst. Tests were performed at different engine operating conditions with particular attention to moderate speed and load.

Particle emissions have been generally associated to diesel engines. However, spark-ignition direct injection (SI-DI) engines have been observed to produce notable amounts of particulate matter as well. The upcoming Euro 6 legislation for passenger cars (effective in 2014, stricter limit in 2017) will further limit the particulate emissions from SI engines by introducing a particle number emission (PN) limit, and it is not probable that the SI-DI engines are able to meet this limit without resorting to additional aftertreatment systems. In this study, the solid particle emissions of a SI-DI passenger car with and without an installed Particle Oxidation Catalyst (POC®) were studied over the New European Driving Cycle (NEDC) on a chassis dynamometer and over real transient acceleration situations on road. It was observed that a considerable portion of particle number emissions occurred during the transient acceleration phases of the cycle.

A reason of the lack of agreement between measured pollutants concentration in the air of urban areas and vehicle pollutant emissions evaluated by available emission models is the fact that catalyst performance variability is not considered. In this paper, an experimental study on the effect of performance variability of catalyst on emissions is presented. Average emissions have been measured using driving cycles representative of different levels of urban traffic, determined by statistical methods on the basis of data detected on-road by an instrumented car. For each driving cycle, representative of a certain traffic level, different thermal starting conditions of catalyst have been tested. These conditions have been determined by the characterization of catalyst performance at steady state and are representative of real catalyst conditions experienced on the road.

Increasing demands on the capabilities of engine simulation and the ability to accurately predict both performance and acoustics has lead to the development of several numerical tools to help engine manufacturers during the prototyping stage. The aid of CFD tools (3D and 1D) can remarkably reduce the duration and the costs of this stage. The need of achieving good accuracy, along with acceptable computational runtime, has given the spur to the development of a geometry based quasi-3D approach. This is designed to model the acoustics and the fluid dynamics of both intake and exhaust system components used in internal combustion engines. Models of components are built using a network of quasi-3D cells based primarily on the geometry of the system. The solution procedure is based on an explicitly time marching staggered grid approach making use of a flux limiter to prevent numerical instabilities.

Ethanol is the most promising alternative fuel for spark ignition (SI) engines, that is blended with gasoline, typically. Moreover, in the last years great attention is paid to the dual fueling, ethanol and gasoline are injected simultaneously. This paper aims to analyze the better methods, blending or dual fueling in order to best exploit the potential of ethanol in improving engine performance and reducing pollutant emissions. The experimental activity was carried out in a small displacement single cylinder engine, representative of 2-3 wheel vehicle engines or of 3-4 cylinder small displacement automotive engines. It was equipped with a prototype gasoline direct injection (GDI) head. The tests were carried out at 3000, 4000, and 5000 rpm full load. The investigated engine operating conditions are representative of the European homologation urban driving cycle.

The aim of the paper is the comparison of the performance, gaseous and particle emissions from different injection configurations and fuels. The engine was operated in port fuel injection (PFI), direct injection (DI) and dual fuel (DF). For DF, ethanol DI-gasoline PFI and gasoline DI-gasoline PFI strategies were performed to discern the effect of injection strategy from the effect of the fuel. The experimental activity was carried out in a small displacement single cylinder engine, representative of 2-3 wheel vehicle engines or of 3-4 cylinder small displacement automotive engines. It was equipped with a prototype gasoline direct injection (GDI) head. The tests were carried out at 3000 rpm, 4000 rpm and 5000 rpm full load. The investigated engine operating conditions are representative of the homologation urban driving cycle. The gaseous and particle emissions were measured at the exhaust by means of a gas analyzer and a smoke meter.