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Exhaust gas recirculation (EGR) is widely used in diesel engines to reduce nitrogen oxide (NOx) emissions. However, a lacquer is formed on the EGR valve or EGR cooler due to particulate matter and other components present in diesel exhaust, causing serious problems. In this study, the mechanism of lacquer deposition is investigated using attenuated total reflection Fourier transform infrared spectrometry (ATR-FTIR) and scanning electron microscopy (SEM). Deposition of temperature-dependent lacquers was evaluated by varying the temperature of a diamond prism between 80 and 120 °C in an ATR-FTIR spectrometer integrated into a custom-built sample line, which branched off from the exhaust pipe of a diesel engine. Lacquers were deposited on the diamond prism at 100 °C or less, while no lacquer was deposited at 120 °C. Time-dependent ATR-FTIR spectra were obtained for approximately 2 h from the beginning of the experiment.

Dimethyl Ether (DME) is a promising new alternative fuel for compression ignition DI engines. However, some problems arise from the poor lubricity of DME. Breakdown of the film bearing between needle and sleeve of the injector can lead to mechanical wear and leakage, a problem that is not mitigated easily. For example, the application of returning the leakage to fuel tank could raise a back pressure on the injection needle. This pressure can affect injection rate and consequently engine performance. In this study, fuels based on various DME to gas oil (diesel fuel) ratios were investigated, in part. Physical and chemical properties of DME and gas oil are shown to lead to mutual solubility at any ratio. Blended fuels have a higher lubricity compared with pure’ DME and a better injection spray compared with pure gas oil.

In this study, advantages of GTL fueled DI diesel engine were observed, then, some cautionary areas, notably the aptitude for sealing materials, were investigated. Some advantages of using GTL as a diesel engine fuel include reduction of soot emission levels, power output and fuel consumption with GTL to conventional diesel fuel operation is equivalent, super-low sulfur content of GTL and its liquid state at normal temperature and pressure. However, there are some problems with putting GTL fuel on the market, such as lubricity, aptitude for sealing materials, high cetane index and high pour point. It is necessary to use additives to improve GTL's lubricity, and selecting the most appropriate type of lubricity improver is also important. The influence of GTL on the swelling properties of standard rubber materials seem basically the same, but it is necessary to notice on used rubbers.

For better understanding of the combustion characteristics in a direct injection dimethyl ether (DME) engine, the chemiluminescences of a burner flame and in-cylinder flame were analyzed using the spectroscopic method. The emission intensities of chemiluminescences were measured by a photomultiplier after passing through a monochrome-spectrometer. For the burner flame, line spectra were found nearby the wave length of 310 nm, 430 nm and 515 nm, arising from OH, CH and C2 radicals, respectively. For the in-cylinder flame, a strong continuous spectrum was found from 340 nm wave length to 550 nm. Line spectra were also detected nearby 310 nm, 395 nm and 430 nm, arising from OH, HCHO, and C2 radicals, respectively, partially overlapping with the continuous spectrum. Of these line spectra, 310 nm of OH radical did not overlapped with the continuous spectrum.

Since dimethyl ether (DME) is a synthetic fuel, it is possible to make it from natural gas, coal and biomass. It is a low-emission, oxygenated fuel, which does not generate soot in the exhaust. Therefore, it has recently been identified as a possible replacement for diesel fuel. In Japan, the new short-term emissions regulations will be enforced beginning in 2003, and the long-term emissions regulations are scheduled to be enforced in 2005. In order to meet these more stringent emissions regulations, existing diesel engines would not be as widely used in the near future as they currently are. This will thus bring about a more widespread use of DME engines due to their low emissions potential. Moreover, when the modification of existing diesel engines into DME engines is available at a moderate cost, the wider use of DME engines can be expected. This study targeted development and application of DME engine technology for diesel engine retrofit, in a used diesel vehicle.

To date, the DME combustion mechanism has been investigated by in-cylinder gas sampling, numerical calculations and observation of combustion radicals. It has been possible to quantify the emission intensities of in-cylinder combustion using a monochromator, and to observe the emitting species as images by using band-pass filters. However, the complete band images were not observed since the broadband (thermal) intensity may be stronger than band spectra intensities. Emission intensities of DME combustion radicals from a pre-mixed burner flame have been measured using a spectroscope and photomultiplier. Results were compared to other fuels, such as n-butane and methane, then, in this study, to better understand the combustion characteristics of DME, emission intensities near CH bands of an actual DI diesel engine fueled with DME were measured, and band spectra emitted from the engine were defined. Near TDC, emission intensities did not vary with wavelength.

In this study, engine performances and exhaust emissions characteristics of compression ignition engine fueled with GTL were investigated by comparison with diesel fuel. Diesel engine could be operated fueled with GTL without any special modify for the test engine. With the high cetane number of GTL, the ignition lag was shorter, and the combustion started earlier than that of diesel fuel. Brake thermal efficiency operated with GTL increased at middle load conditions due to incomplete combustion emission such as CO and THC were lower than that of diesel fuel operation. NOx emission with GTL was comparable to diesel fuel, and there was a little decrease at high load. With GTL, soot emission was lower than with diesel fuel at above middle load condition. It seemed to be a reason of soot reduction that there was little sulphur contained in GTL.

Recently, dimethyl ether (DME) has been attracting much attention as a clean alternative fuel, since the thermal efficiency of DME powered diesel engine is comparable to diesel fuel operation and soot free combustion can be achieved. In this experiment, the effect of ambient pressure on DME spray was investigated with observation of droplet size such as Sauter mean diameter (SMD) by the shadowgraph and image processing method. The higher ambient pressure obstructs the growth of DME spray, therefore faster breakup was occurred, and liquid column was thicker with increasing the ambient pressure. Then engine performances and exhaust emissions characteristics of DME diesel engine were investigated with various compression ratios. The minimum compression ratio for the easy start and stable operation was obtained at compression ratio of about 12.

In order to reduce environmental disruption due to exhaust PM and NOx emissions from diesel engines of dimethyl ether (DME) has been proposed the use for the next generation vehicles, because the discharge of the atmospheric pollutants is less. In this study, DME is used to fuel a retrofit type diesel engine, and operational tests were carried out using a rotary distributor fuel injection pump. In this experiment, comparison and examination of the effects of fuel injection pressure, nozzle hole diameter, and injection timing. When using DME as an alternative fuel, the fuel temperature affects engine operation. And diameter of the injector nozzle hole and larger injection quantity is regarded as factors affecting the improvement in engine performance. In addition, for understanding the DME spray in the cylinder, DME was sprayed in a constant volume chamber where atmospheric temperature and pressure increased simultaneously, and the result is compared and examined with diesel fuel.

To better understand the combustion characteristics of DME, emission intensities of DME combustion radicals from a pre-mixed burner flame were measured by a spectroscope and photomultiplier, Results were compared to other fuels, such as methane and butane. Large peaks in the band spectra from pre-mixed and diffusion DME flames were found near 310 nm, 430 nm, and 515 nm, arising from OH, CH and C2, respectively. The DME emission intensities decreased with increasing the equivalence ratio in this study. Notably, the relative decrease in the C2 band spectra peak was greater than that of the OH band. Comparing the pre-mixed DME and butane flames, the butane band spectra peaks were similar in shape, but much stronger than those for DME. However, it was remarkable that CH and C2 band spectra peaks decreased only slightly with increase in equivalence ratio compared to the DME case.

In this study, the NO emission characteristics of a dimethyl ether fueled compression ignition (CI) engine were studied, and a suitable combustion control concept was developed. A three-zone thermo-chemical model was used to understand the basic NO formation characteristics with dimethyl ether. The experimental study was carried out using a small direct-injection diesel engine. Comparison of the experimental and calculated results showed that the dimethyl ether / air mixing process was relatively slow compared with diesel fuel, which is the main reason for the relatively high NO emissions with dimethyl ether operation, in spite of its lower adiabatic flame temperature. To reduce the high temperature period, turbulence was introduced into the combustion chamber by a high-turbulence combustion system, which reduced NO emissions. It became clear that acceleration of the mixing process is an important factor for NO reduction with dimethyl ether spray combustion.

Serious problems occur in an exhaust gas recirculation system due to an adhesive hard deposit. It is important to clarify the mechanism of the hard deposit formation to suppress it. In this study, the effect of exhaust gas composition on hard deposit formation was investigated. The amount of the hard deposit formed under various operating conditions while keeping the total hydrocarbon concentration constant was different. The component analyses of the exhaust gas and the hard deposit clarified that polycyclic aromatic hydrocarbon in the exhaust gas strongly affected the hard deposit formation.

Exhaust gas recirculation (EGR) is widely used in diesel engines to reduce nitrogen oxide emissions. To meet the strict emission regulations, e.g., Real Driving Emissions, the EGR system is required to be used at temperatures lower than the present ones. However, under cool conditions, an adhesive deposit forms on the EGR valve or cooler because of the particulate matter and other components present in the diesel exhaust. This causes sticking of the EGR valve or degradation of the heat-exchange performance, which are serious problems. In this study, the EGR deposit formation mechanism was investigated based on spatially- and time-resolved scanning electron microscopy (SEM) observation. The deposit was formed in a custom-made sample line using real exhaust emitted from a diesel engine. The exhaust including soot was introduced into the sample line for 24 h (maximum duration), and the formed deposit was observed using SEM.