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A miniaturized electronic nose has been constructed at JPL in collaboration with Caltech. This array of conductometric sensors has been trained to detect and quantify the presence of vapors in the air; the compounds detected have been found as contaminants in shuttle air. This device has potential application as a miniature, distributed device for monitoring and controlling the constituents in air.

A flight experiment to test the operation of an Electronic Nose developed and built at JPL and Caltech was done aboard STS-95 in October-November, 1998. This ENose uses conductometric sensors made of insulating polymer-carbon composite films; it has a volume of 1.7 liters, weighs 1.4 kg including the operating computer and operates on 1.5 W average power. In the flight experiment, the ENose was operated continuously for 6 days and recorded the sensors' response to changes in air in the mid-deck of the orbiter. The ENose had been trained to identify and quantify ten common contaminants at the 24-hour Spacecraft Maximum Allowable Concentration (SMAC) level. Most SMACs are on the order of 10-100 ppm. The experiment was controlled by collecting air samples daily and analyzing them using standard analytical techniques after the flight. The device is microgravity insensitive.

This paper reports several slow reversible and quasi-reversible processes which occur in the porous electrode/solid electrolyte combination at AMTEC operating temperatures. These processes help to elucidate the evolution of the electrode and electrolyte characteristics with time. They also demonstrate that the atomic constituents of the electrode/electrolyte engage in significant dynamic motion. We report the stability of the sodium beta“-alumina phase in low pressure sodium vapor at 1173K up to 3000 hours, and the decomposition of the sodium meta-aluminate (NaAlO2) phase present at about 1% in the BASE ceramic, which gives rise to transient local increases in the solid electrolyte resistivity due to local micro-cracking. We also report slow apparent morphological changes, possibly surface or grain boundary reconstruction, in TiN and RhW electrodes driven by changes in the local sodium activity.