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The small engine for two-wheel vehicles has generally high possibility to be optimized at low speeds and high loads. In these conditions fuel consumption and pollutants emission should be reduced maintaining the performance levels. This optimization can be realized only improving the basic knowledge of the thermo-fluid dynamic phenomena occurring during the combustion process. It is known that, during the fuel injection phase in PFI SI engines, thin films of liquid fuel can form on the valves surface and on the cylinder walls. Successively the fuel films interact with the intake manifold and the combustion chamber gas flow. During the normal combustion process, it is possible to achieve gas temperature and mixture strength conditions that lead to fuel film ignition. This phenomenon can create diffusion-controlled flames that can persist well after the normal combustion event. These flames induce the emission of soot and unburned hydrocarbons.