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Journal Article

Iso-Stoichiometric Ternary Blends of Gasoline, Ethanol and Methanol: Investigations into Exhaust Emissions, Blend Properties and Octane Numbers

2012-09-10
2012-01-1586
Iso-stoichiometric ternary blends - in which three-component blends of gasoline, ethanol and methanol are configured to the same stoichiometric air-fuel ratio as an equivalent binary ethanol-gasoline blend - can function as invisible "drop-in" fuels suitable for the existing E85/gasoline flex-fuel vehicle fleet. This has been demonstrated for the two principal means of detecting alcohol content in such vehicles, which are considered to be a virtual, or software-based, sensor, and a physical sensor in the fuel line. Furthermore when using such fuels the tailpipe CO₂ emissions are essentially identical to those found when the vehicle is operated on E85. Because of the fact that methanol can be made from a wider range of feed stocks than ethanol and at a cheaper price, these blends then provide opportunities to improve energy security, to reduce greenhouse gas emissions and to produce a fuel blend which could potentially be cheaper on a cost-per-unit-energy basis than gasoline or diesel.
Technical Paper

GEM Ternary Blends: Testing Iso-Stoichiometric Mixtures of Gasoline, Ethanol and Methanol in a Production Flex-Fuel Vehicle Fitted with a Physical Alcohol Sensor

2012-04-16
2012-01-1279
The paper presents vehicle-based test work using tri-component, or ternary, blends of gasoline, ethanol and methanol for which the stoichiometric air-fuel ratio (AFR) was controlled to be 9.7:1. This is the same as that of conventional "E85" alcohol-based fuel. Such ternary blends are termed "GEM" after the first initial of the three components. The present work was a continuation of an earlier successful project which established that the blends were effectively invisible to a car using a virtual alcohol sensor. The vehicle used here employed the other major technology in flex-fuel vehicles to determine the proportion of alcohol fuel in the tank, a physical alcohol sensor. Another aspect of the present work included the desire to investigate ternary blend replacements for E85 having low ethanol concentrations. Evidence from the previous work suggested that under specific conditions, ethanol was required in some amount to act as a cosolvent for the gasoline and methanol in the blend.
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