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Biofuel usage is increasingly expanding thanks to its significant contribution to a well-to-wheel (WTW) reduction of greenhouse gas (GHG) emissions. In addition, stringent emission standards make mandatory the use of Diesel Particulate Filter (DPF) for the particulate emissions control. The different physical properties and chemical composition of biofuels impact the overall engine behaviour. In particular, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value (LHV). More specifically, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value, respectively. The particle emissions, in fact, are lower mainly because of the higher oxygen content. Subsequently less frequent regenerations are required.

Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

The present paper describes some results of a cooperative research project between GM Powertrain Europe and Istituto Motori of CNR aimed at studying the impact of FAME and GTL fuel blends on the performance, emissions and fuel consumption of the latest-generation automotive diesel engines. The investigation was carried out on the newly released GM 2.0L 4-cylinder “torque-controlled” Euro 5 diesel engine for PC application and followed previous tests on its Euro 4 version, in order to track the interaction between the alternative fuels and the diesel engine, as the technology evolves. Various blends of first generation biodiesels (RME, SME) and GTL with a reference diesel fuel were tested, notably B20, B50 and B100. The tests were done in a wide range of engine operation points for the complete characterization of the biodiesels performance in the NEDC cycle, as well as in full load conditions.

Using alternative fuels like Natural Gas (NG) has shown good potentials on heavy duty engines. Heavy duty NG engines can be operated either lean or stoichiometric diluted with EGR. Extending Dilution limit has been identified as a beneficial strategy for increasing efficiency and decreasing emissions. However dilution limit is limited in these types of engines because of the lower burnings rate of NG. One way to extend the dilution limit of a NG engine is to run the engine on Hythane (natural gas + some percentage hydrogen). Previously effects of Hythane with 10% hydrogen by volume in a stoichiometric heavy duty NG engine were studied and no significant changes in terms of efficiency and emissions were observed. This paper presents results from measurements made on a heavy duty 6-cylinder NG engine. The engine is operated with NG and Hythane with 25% hydrogen by volume and the effects of these fuels on the engine performance are studied.

The present paper describes some results of a research project aimed at studying the impact of alternative fuels blends on the emissions and fuel consumption of an Euro 5 automotive diesel engine. Two alternative fuels were chosen for the experiments: RME and GTL. The tests were done in the three most important operating conditions for the engine emission calibration. Moreover, the NOx-PM trade-off by means of EGR sweep was performed in the same operating conditions, in order to evaluate the engine EGR tolerability when burning low sooting fuels as the RME. The investigations put in evidence that the impact of the alternative fuels on modern diesel engines remains significant. This also depends on the interaction between the alternative fuel characteristics and the engine-management strategies, as described in detail in the paper.

This paper reports the study of the effects of alternative diesel fuel and the impact for the air-fuel mixture preparation. The injection process characterization has been carried out in a non-evaporative high-density environment in order to measure the fuel injection rate and the spatial and temporal distribution of the fuel. The injection and vaporization processes have been characterized in an optically accessible single cylinder Common Rail diesel engine representing evaporative conditions similar to the real engine. The tests have been performed by means of a Bosch second generation common rail solenoid-driven fuel injection system with a 7-holes nozzle, flow number 440 cc/30s @100bar, 148deg cone opening angle (minisac type). Double injection strategy (pilot+main) has been implemented on the ECUs corresponding to operative running conditions of the commercial EURO 5 diesel engine.

Although the application of cylinder pressure sensors to gain insight into the combustion process is not a novel topic itself, the recent availability of inexpensive in-cylinder pressure sensors has again prompted an upcoming interest for the utilization of the cylinder pressure signal within engine control and monitoring. Besides the use of the in-cylinder pressure signal for combustion analysis and control the information can also be used to determine related quantities in the exhaust or intake manifold. Within this work two different methods to estimate the pressure inside the exhaust manifold are proposed and compared. In contrary to first principle based approaches, which may require time extensive parameterization, alternative data driven approaches were pursued. In the first method a Principle Component Analysis (PCA) is applied to extract the cylinder pressure information and combined with a polynomial model approach.

High pressure diesel sprays were visualized under vaporizing and combusting conditions in a constant-volume combustion vessel. Near-simultaneous visualization of vapor and liquid phase fuel distribution were acquired using a hybrid shadowgraph/Mie-scattering imaging setup. This imaging technique used two pulsed LED's operating in an alternative manner to provide proper light sources for both shadowgraph and Mie scattering. In addition, combustion cases under the same ambient conditions were visualized through high-speed combustion luminosity measurement. Two single-hole diesel injectors with same nozzle diameters (100μm) but different k-factors (k0 and k1.5) were tested in this study. Detailed analysis based on spray penetration rate curves, rate of injection measurements, combustion indicators and 1D model comparison have been performed.

In the present paper, two different methodologies are adopted and critically integrated to analyze the knock behavior of a last generation small size spark ignition (SI) turbocharged VVA engine. Particularly, two full load operating points are selected, exhibiting relevant differences in terms of knock proximity. On one side, a knock investigation is carried out by means of an Auto-Regressive technique (AR model) to process experimental in-cylinder pressure signals. This mathematical procedure is used to estimate the statistical distribution of knocking cycles and provide a validation of the following 1D-3D knock investigations. On the other side, an integrated numerical approach is set up, based on the synergic use of 1D and 3D simulation tools. The 1D engine model is developed within the commercial software GT-Power™. It is used to provide time-varying boundary conditions (BCs) for the 3D code, Star-CD™.

Detailed experimental information on the early stages of spark ignition process represent a substantial part for guiding the development of engines with higher efficiencies and reduced pollutant emissions. Flame kernel formation influences strongly combustion development inside the cylinder, especially for a direct injection spark ignition engine. This study presents the analysis of the evolution of spark-ignited flame kernels with detailed view upon cycle-to-cycle variations. Experiments are performed in a SI optical engine equipped with the cylinder head and injection system of a commercial turbocharged engine. Blend of commercial gasoline and butanol (40% by volume) is tested at stoichiometric and lean mixture conditions. Experiments are carried out at 2000 rpm through conventional tests (based on in-cylinder pressure measurements and exhaust emission analysis) and through optical diagnostics. In particular, UV-visible digital imaging and natural emission spectroscopy are applied.

The present paper reassumes the results of an experimental study focused on the effects of the nozzle injector's coking varying the flow number (FN); the performance and emissions of an automotive Euro5 diesel engine have been analyzed using diesel fuel. As the improvement of the diesel engine performance requires a continuous development of the injection system and in particular of the nozzle design, in the last years the general trend among OEMs is lowering nozzle flow number and, as a consequence, nozzle holes size. The study carried out moves from the consideration that a reduction of the nozzle holes diameter could increase the impact of their coking process. For this purpose, an experimental campaign has been realized, testing the engine in steady state in three partial load operating points, representative of the European homologation driving cycle, and in full load conditions.

An innovative quasi-dimensional multizone combustion model for the spray formation, combustion and emission formation analysis in DI diesel engines was assessed and applied to an optical single cylinder engine. The model, which has been recently presented by the authors, integrates a predictive non stationary 1D spray model developed by the Sandia National Laboratory, with a diagnostic multizone thermodynamic model. The 1D spray model is capable of predicting the equivalence ratio of the fuel during the mixing process, as well as the spray penetration. The multizone approach is based on the application of the mass and energy conservation laws to several homogeneous zones identified in the combustion chamber. A specific submodel is also implemented to simulate the dilution of the burned gases. Soot formation is modeled by an expression which derives from Kitamura et al.'s results, in which an explicit dependence on the local equivalence ratio is considered.

The ignition and flame stabilization characteristics of two synthetic fuels, having significantly different cetane numbers, are investigated in a constant volume combustion vessel over a range of ambient conditions representative of a compression ignition engine operating at variable loads. The synthetic fuel with a cetane number of 63 (S-1) is characterized by ignition delays that are only moderately longer than n-dodecane (cetane number of 87) over a range of ambient conditions. By comparison, the synthetic fuel with a cetane number of 17 (S-2) requires temperatures approximately 300 K higher to achieve the same ignition delays. The much different ignition characteristics and operating temperature range present a scenario where the lift-off stabilization may be substantially different.

High-speed OH chemiluminescence imaging is used to measure the lift-off length of diesel sprays in an optical heavy-duty diesel engine of 2 L displacement operated at 1200 rpm and 5 bar IMEP. Stereoscopic images are acquired at two different wavelengths (310 and 330 nm). Subtraction of pairwise images helps reducing the background coming from natural soot incandescence in the OH chemiluminescence images. Intake air temperature (343 to 403 K), motored top dead center density (18 to 22 kg/m3), fuel injection pressure (150 to 250 MPa), intake oxygen concentration (17 to 21 %vol) and nozzle diameter (0.1 and 0.14 mm) are varied and a nonlinear regression model is derived from the experimental results to describe stabilized lift-off length as function of the experimental factors. The lift-off length follows the general trends that are known from spray vessel investigations, but the strength of the dependence on certain variables deviates strongly from those studies.

The easiest way to identify knock conditions during the operation of a SI engine is represented by the knowledge of the in-cylinder pressure. Traditional techniques like MAPO (Maximum Amplitude Pressure Oscillation) based method rely on the frequency domain processing of the pressure data. This technique may present uncertainties due to the correct specification of some model parameters, like the band-pass frequency range and the crank angle window of interest. In this paper two innovative techniques for knock detection, which make use of the in-cylinder pressure, are explained in detail, and the results are compared with those coming from the MAPO method. The first procedure is based on the use of statistical analysis by applying an Auto Regressive (AR) technique, while the second technique makes use of the Discrete Wavelet Transform (DWT). The data useful for the analysis have been acquired on a high compression ratio four cylinder, spark ignition engine.

Partially Premixed Combustion (PPC) is used to meet the increasing demands of emission legislation and to improve fuel efficiency. PPC with gasoline fuels have the advantage of a longer premixed duration of fuel/air mixture which prevents soot formation at higher loads. The objective of this paper is to investigate the degree of stratification for low load (towards idle) engine conditions using different injection strategies and negative valve overlap (NVO). The question is, how homogenous or stratified is the partially premixed combustion (PPC) for a given setting of NVO and fuel injection strategy. In this work PRF 55 has been used as PPC fuel. The experimental engine is a light duty (LD) diesel engine that has been modified to single cylinder operation to provide optical access into the combustion chamber, equipped with a fully variable valve train system. Hot residual gases were trapped by using NVO to dilute the cylinder mixture.

Modeling combustion of transportation fuels remains a difficult task due to the extremely large number of species constituting commercial gasoline and diesel. However, for this purpose, multi-component surrogate fuel models with a reduced number of key species and dedicated reaction subsets can be used to reproduce the physical and chemical traits of diesel and gasoline, also allowing to perform CFD calculations. Recently, a detailed surrogate fuel kinetic model, named C3 mechanism, was developed by merging high-fidelity sub-mechanisms from different research groups, i.e. C0-C4 chemistry (NUI Galway), linear C6-C7 and iso-octane chemistry (Lawrence Livermore National Laboratory), and monocyclic aromatic hydrocarbons (MAHs) and polycyclic aromatic hydrocarbons (PAHs) (ITV-RWTH Aachen and CRECK modelling Lab-Politecnico di Milano).

In recent years, the increase of gasoline fuel injection pressure is a way to improve thermal efficiency and lower engine-out emissions in GDI homogenous combustion concept. The challenge of controlling particulate formation as well in mass and number concentrations imposed by emissions regulations can be pursued improving the mixture preparation process and avoiding mixture inhomogeneity with ultra-high injection pressure values up to 100 MPa. The increase of the fuel injection pressure in GDI homogeneous systems meets the demand for increased injector static flow, while simultaneously improves the spray atomization and mixing characteristics with consequent better combustion performance. Few studies quantify the effects of high injection pressure on transient gasoline spray evolution. The aim of this work was to simulate with OpenFOAM the spray morphology of a commercial gasoline injected in a constant volume vessel by a prototypal GDI injector.

The electrochemical performance of a lithium-ion battery is strongly affected by the temperature. During charge and discharge cycles, batteries are subjected to an increment of temperature that can accelerate aging and loss of efficiency if critical values are reached. Knowing the thermal parameters that affect the heat exchange between the battery surface and the surrounding environment (air, cooling fins, plates, etc…) is fundamental to their thermal management. In this work, thermal imaging is applied to a laminated lithium-polymers battery as a non-invasive temperature-indication method. Measurements are taken during the discharge phase and the following cooling down until the battery reaches the ambient temperature. The 2d images are used to analyze the homogeneity of the temperature distribution on the battery surface. Then, experimental results are coupled with mathematical correlations.

Growing concerns about the emissions of internal combustion engines have forced the adoption of aftertreatment devices to reduce the adverse impact of diesel engines on health and environment. Diesel particulate filters are considered as an effective means to reduce the particle emissions and comply with the regulations. Research activity in this field focuses on filter configuration, materials and aging, on understanding the variation of soot layer properties during time, on defining of the optimal strategy of DPF management for on-board control applications. A model was implemented in order to simulate the filtration and regeneration processes of a wall-flow particulate filter, taking into account the emission characteristic of the engine, whose architecture and operating conditions deeply affect the size distribution of soot particles.