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A Study of PGM-Free Oxidation Catalyst YMnO3 for Diesel Exhaust Aftertreatment

2012-06-18
Currently, two consolidated aftertreatment technologies are available for the reduction of NOx emissions from diesel engines: Urea SCR (Selective Catalytic Reduction) systems and LNT (Lean NOx Trap) systems. Urea SCR technology, which has been widely used for many years at stationary sources, is becoming nowadays an attractive alternative also for light-duty diesel applications. However, SCR systems are much more effective in NOx reduction efficiency at high load operating conditions than light load condition, characterized by lower exhaust gas temperatures.
Journal Article

Advanced Control System of Variable Compression Ratio (VCR) Engine with Dual Piston Mechanism

2009-04-20
2009-01-1063
A dual piston Variable Compression Ratio (VCR) engine has been newly developed. This compact VCR system uses the inertia force and hydraulic pressure accompanying the reciprocating motion of the piston to raise and lower the outer piston and switches the compression ratio in two stages. For the torque characteristic enhancement and the knocking prevention when the compression ratio is being switched, it is necessary to carry out engine controls based on accurate compression ratio judgment. In order to accurately judge compression ratio switching timing, a control system employing the Hidden Markov Model (HMM) was used to analyze vibration generated during the compression ratio switching. Also, in order to realize smooth torque characteristics, an ignition timing control system that separately controls each cylinder and simultaneously performs knocking control was constructed.
Journal Article

Effects of Secondary Air Injection During Cold Start of SI Engines

2010-10-25
2010-01-2124
An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.
Journal Article

Speciated Engine-Out Organic Gas Emissions from a PFI-SI Engine Operating on Ethanol/Gasoline Mixtures

2009-11-02
2009-01-2673
Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.
Journal Article

Ash Effects on Diesel Particulate Filter Pressure Drop Sensitivity to Soot and Implications for Regeneration Frequency and DPF Control

2010-04-12
2010-01-0811
Ash, primarily derived from diesel engine lubricants, accumulates in diesel particulate filters directly affecting the filter's pressure drop sensitivity to soot accumulation, thus impacting regeneration frequency and fuel economy. After approximately 33,000 miles of equivalent on-road aging, ash comprises more than half of the material accumulated in a typical cordierite filter. Ash accumulation reduces the effective filtration area, resulting in higher local soot loads toward the front of the filter. At a typical ash cleaning interval of 150,000 miles, ash more than doubles the filter's pressure drop sensitivity to soot, in addition to raising the pressure drop level itself. In order to evaluate the effects of lubricant-derived ash on DPF pressure drop performance, a novel accelerated ash loading system was employed to generate the ash and load the DPFs under carefully-controlled exhaust conditions.
Journal Article

Detect the Imperceptible Drowsiness

2010-04-12
2010-01-0746
Prediction of drowsiness based on an objective measure is demanded in machine and vehicle operations, in which human error may cause fatal accidents. Recently, we focused on the pupil which is controlled by the autonomic nervous system, easily and non-invasively observable from the outside of the body. Prior to the large low frequency pupil-diameter fluctuation, which is known to associate with drowsiness, a Gradual Miosis was observed in most subjects. During this miosis period, the subjects were not yet aware of their drowsiness. We have developed a software system which automatically detects the Gradual Miosis in real time.
Journal Article

Study of On-Board Ammonia (NH3) Generation for SCR Operation

2010-04-12
2010-01-1071
Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.
Journal Article

A Study of Controlled Auto-Ignition in Small Natural Gas Engines

2013-10-15
2013-32-9098
Research has been conducted on Controlled Auto-Ignition (CAI) engine with natural gas. CAI engine has the potential to be highly efficient and to produce low emissions. CAI engine is potentially applicable to automobile engine. However due to narrow operating range, CAI engine for automobile engine which require various speed and load in real world operation is still remaining at research level. In comparison some natural gas engines for electricity generation only require continuous operation at constant load. There is possibility of efficiency enhancement by CAI combustion which is running same speed at constant load. Since natural gas is primary consisting of methane (CH4), high auto-ignition temperature is required to occur stable auto-ignition. Usually additional intake heat required to keep stable auto-ignition. To keep high compression temperature, single cylinder natural gas engine with high compression ratio (CR=26) was constructed.
Journal Article

Durability Design Method of New Stopper Bush Using New Theory (Friction and Spring) for Electric Power Steering

2014-04-01
2014-01-0046
In the automobile industries, weight reduction has been investigated to improve fuel efficiency together with reduction of CO2 emission. In such circumstance, it becomes necessity to make an electric power steering (EPS) more compact and lightweight. In this study, we aimed to have a smaller and lighter EPS gear size by focusing on an impact load caused at steering end. In order to increase the shock absorption energy without increase of stopper bush size, we propose new theory of impact energy absorption by not only spring function but also friction, and a new stopper bush was designed on the basis of the theory. The profile of the new stopper bush is cylinder form with wedge-shaped grooves, and when the new stopper bush is compressed by the end of rack and the gear housing at steering end, it enables to expand the external diameter and produce friction. In this study, we considered the durability in the proposed profile.
Journal Article

Fracture Prediction for Automotive Bodies Using a Ductile Fracture Criterion and a Strain-Dependent Anisotropy Model

2015-04-14
2015-01-0567
In order to reduce automobile body weight and improve crashworthiness, the use of high-strength steels has increased greatly in recent years. An optimal combination of both crash safety performance and lightweight structure has been a major challenge in automobile body engineering. In this study, the Cockcroft-Latham fracture criterion was applied to predict the fracture of high-strength steels. Marciniak-type biaxial stretching tests for high-strength steels were performed to measure the material constant of the Cockcroft-Latham fracture criterion. Furthermore, in order to improve the simulation accuracy, local anisotropic parameters based on the plastic strain (strain dependent model of anisotropy) were measured using the digital image grid method and were incorporated into Hill's anisotropic yield condition by the authors. In order to confirm the validity of the Cockcroft-Latham fracture criterion, uniaxial tensile tests were performed.
Journal Article

Study of High-Compression-Ratio Engine Combined with an Ethanol-Gasoline Fuel Separation System

2014-10-13
2014-01-2614
Bio-ethanol is used in many areas of the world as ethanol blended gasoline at low concentrations such as “E10 gasoline”. In this study, a method was examined to effectively use this small amount of ethanol within ethanol blended gasoline to improve thermal efficiency and high-load performance in a high-compression-ratio engine. Ethanol blended gasoline was separated into high-concentration ethanol fuel and gasoline using a fuel separation system employing a membrane. High-ethanol-concentration fuel was selectively used at high-load conditions to suppress knocking. In this system, a method to decrease ethanol consumption is necessary to cover the wide range of engine operation. Lower ethanol consumption could be achieved by Miller-cycle operation because decrease of the effective compression ratio suppresses knocking. However, high-load operation was limited due to the decrease in intake air volume with Miller-cycle operation.
Journal Article

Development of a New Pressure Measurement Technique and PIV to Validate CFD for the Aerodynamics of Full-scale Vehicles

2016-04-05
2016-01-1623
In the early stages of aerodynamic development of commercial vehicles, the aerodynamic concept is balanced with the design concept using CFD. Since this development determines the aerodynamic potential of the vehicle, CFD with high accuracy is needed. To improve its accuracy, spatial resolution of CFD should be based on flow phenomenon. For this purpose, to compare aerodynamic force, pressure profile and velocity vector map derived from CFD with experimental data is important, but there are some difficulties to obtain pressure profile and velocity vector map for actual vehicles. At the point of pressure measurement for vehicles, installation of pressure taps to the surface of vehicle, i.e., fuel tank and battery, is a problem. A new measurement method developed in this study enables measurement of surface pressure of any desired points. Also, the flexibility of its shape and measuring point makes the installation a lot easier than the conventional pressure measurement method.
Journal Article

Reduction of Cold-Start Emissions through Valve Timing in a GDI Engine

2016-04-05
2016-01-0827
This work examines the effect of valve timing during cold crank-start and cold fast-idle (1200 rpm, 2 bar NIMEP) on the emissions of hydrocarbons (HC) and particulate mass and number (PM/PN). Four different cam-phaser configurations are studied in detail: 1. Baseline stock valve timing. 2. Late intake opening/closing. 3. Early exhaust opening/closing. 4. Late intake phasing combined with early exhaust phasing. Delaying the intake valve opening improves the mixture formation process and results in more than 25% reduction of the HC and of the PM/PN emissions during cold crank-start. Early exhaust valve phasing results in a deterioration of the HC and PM/PN emissions performance during cold crank-start. Nevertheless, early exhaust valve phasing slightly improves the HC emissions and substantially reduces the particulate emissions at cold fast-idle.
Journal Article

Lubricant-Derived Ash Impact on Gasoline Particulate Filter Performance

2016-04-05
2016-01-0942
The increasing use of gasoline direct injection (GDI) engines coupled with the implementation of new particulate matter (PM) and particle number (PN) emissions regulations requires new emissions control strategies. Gasoline particulate filters (GPFs) present one approach to reduce particle emissions. Although primarily composed of combustible material which may be removed through oxidation, particle also contains incombustible components or ash. Over the service life of the filter the accumulation of ash causes an increase in exhaust backpressure, and limits the useful life of the GPF. This study utilized an accelerated aging system to generate elevated ash levels by injecting lubricant oil with the gasoline fuel into a burner system. GPFs were aged to a series of levels representing filter life up to 150,000 miles (240,000 km). The impact of ash on the filter pressure drop and on its sensitivity to soot accumulation was investigated at specific ash levels.
Journal Article

Assessment of Gasoline Direct Injection Engine Cold Start Particulate Emission Sources

2017-03-28
2017-01-0795
The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.
Journal Article

Analysis of Ash in Low Mileage, Rapid Aged, and High Mileage Gasoline Exhaust Particle Filters

2017-03-28
2017-01-0930
To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.
Technical Paper

Onboard Ethanol-Gasoline Separation System for Octane-on-Demand Vehicle

2020-04-14
2020-01-0350
Bioethanol is being used as an alternative fuel throughout the world based on considerations of reduction of CO2 emissions and sustainability. It is widely known that ethanol has an advantage of high anti-knock quality. In order to use the ethanol in ethanol-blended gasoline to control knocking, the research discussed in this paper sought to develop a fuel separation system that would separate ethanol-blended gasoline into a high-octane-number fuel (high-ethanol-concentration fuel) and a low-octane-number fuel (low-ethanol-concentration fuel) in the vehicle. The research developed a small fuel separation system, and employed a layout in which the system was fitted in the fuel tank based on considerations of reducing the effect on cabin space and maintaining safety in the event of a collision. The total volume of the components fitted in the fuel tank is 6.6 liters.
Journal Article

Development of a New Metal Substrate for Lean NOx Trap

2008-04-14
2008-01-0806
This paper presents a new substrate for Lean NOx Traps (LNT) which enables high NOx conversion efficiency, even after long-term aging, when using alkali metals as the NOx adsorber. When a conventional metal honeycomb is used as the LNT substrate, the chromium in the metal substrate migrates into the washcoat and reacts with the alkali metals after thermal aging. In order to help prevent this migration, we have developed a new substrate where a fine -alumina barrier is precipitated to the surface of the metal substrate. The new substrate is highly capable of preventing migration of chromium into the washcoat and greatly enhances the NOx conversion. The durability of the new substrate and emission test using a test vehicle are also examined.
Journal Article

Particulate Matter Emissions from a Direct Injection Spark Ignition Engine under Cold Fast Idle Conditions for Ethanol-Gasoline Blends

2011-04-12
2011-01-1305
The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.
Journal Article

EGR Effects on Boosted SI Engine Operation and Knock Integral Correlation

2012-04-16
2012-01-0707
The effects of cooled exhaust gas recirculation (EGR) on a boosted direct-injection (DI) spark ignition (SI) engine operating at stoichiometric equivalence ratio, gross indicated mean effective pressure of 14-18 bar, and speed of 1500-2500 rpm, are studied under constant fuel condition at each operating point. In the presence of EGR, burn durations are longer and combustion is more retard. At the same combustion phasing, the indicated specific fuel consumption improves because of a decrease in heat loss and an increase in the specific heat ratio. The knock limited spark advance increases substantially with EGR. This increase is due partly to a slower combustion which is equivalent to a spark retard, as manifested by a retarded value of the 50% burn point (CA50), and due partly to a slower ignition chemistry of the diluted charge, as manifested by the knock limited spark advance to beyond the value offered by the retarded CA50.
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