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Interest in natural gas as an alternative fuel source to petroleum fuels for light-duty vehicle applications has increased due to its domestic availability and stable price compared to gasoline. With its higher hydrogen-to-carbon ratio, natural gas has the potential to reduce engine out carbon dioxide emissions, which has shown to be a strong greenhouse gas contributor. For part-load conditions, the lower flame speeds of natural gas can lead to an increased duration in the inflammation process with traditional port-injection. Direct-injection of natural gas can increase in-cylinder turbulence and has the potential to reduce problems typically associated with port-injection of natural gas, such as lower flame speeds and poor dilution tolerance. A study was designed and executed to investigate the effects of direct-injection of natural gas at part-load conditions.

Interest in natural gas as a fuel for light-duty transportation has increased due to its domestic availability and lower cost relative to gasoline. Natural gas, comprised mainly of methane, has a higher knock resistance than gasoline making it advantageous for high load operation. However, the lower flame speeds of natural gas can cause ignitability issues at part-load operation leading to an increase in the initial flame development process. While port-fuel injection of natural gas can lead to a loss in power density due to the displacement of intake air, injecting natural gas directly into the cylinder can reduce such losses. A study was designed and performed to evaluate the potential of natural gas for use as a light-duty fuel. Steady-state baseline tests were performed on a single-cylinder research engine equipped for port-fuel injection of gasoline and natural gas, as well as centrally mounted direct injection of natural gas.

Gasoline direct injection (GDI) engines have improved thermodynamic efficiency (and thus lower fuel consumption) and power output compared with port fuel injection (PFI) and their penetration is expected to rapidly grow in the near future in the U.S. market. In addition, the use of alternative fuels is expanding, with a potential increase in ethanol content beyond the current 10%. Increased emphasis has been placed on butanol due to its more favorable fuel properties, as well as new developments in production processes. This study explores the influence of mid-level ethanol and iso-butanol blends on criteria emissions, gaseous air toxics, and particulate emissions from two wall-guided gasoline direct injection passenger cars fitted with three-way catalysts. Emission measurements were conducted over the Federal Test Procedure (FTP) driving cycle on a chassis dynamometer.

A model process to produce dimethylether (DME) from natural gas (NG) was simulated in a one-pass mode (no material recycle), assuming steady-state and chemical and physical equilibrium. NG conversion to synthesis gas (syngas) via steam reforming resulted in stoichiometric numbers of 2.97 along with vapor mole fraction extremes for carbon dioxide, methane, and water. These concentrations formed an eight-trial simulation grid of syngas compositions. Simulation of DME production was performed in a dual reactor configuration with methanol formation as the intermediate compound. Solutions resulting from the subsequent adiabatic dehydration of the methanol-rich phase showed a consistent DME composition (88%). The resulting solutions and unreacted syngas streams from simulation were examined for applicability to a dual-fuel NG/DME CI engine.

Optical imaging diagnostics of combustion are most often performed in the visible spectral band, in part because camera technology is most mature in this region, but operating in the infrared (IR) provides a number of benefits. These benefits include access to emission lines of relevant chemical species (e.g. water, carbon dioxide, and carbon monoxide) and obviation of image intensifiers (avoiding reduced spatial resolution and increased cost). High-speed IR in-cylinder imaging and image processing were used to investigate the relationships between infrared images, quantitative image-derived metrics (e.g. location of the flame centroid), and measurements made with in-cylinder pressure transducers (e.g. coefficient of variation of mean effective pressure). A 9.7-liter, inline-six, natural-gas-fueled engine was modified to enable exhaust-gas recirculation (EGR) and provide borescopic optical access to one cylinder for two high-speed infrared cameras.

The objective of this research was to study the effects of a CCRT®, henceforth called Diesel Oxidation Catalyst - Catalyzed Particulate Filter (DOC-CPF) system on particulate and gaseous emissions from a heavy-duty diesel engine (HDDE) operated at Modes 11 and 9 of the old Environmental Protection Agency (EPA) 13-mode test cycle Emissions characterized included: total particulate matter (TPM) and components of carbonaceous solids (SOL), soluble organic fraction (SOF) and sulfates (SO4); vapor phase organics (XOC); gaseous emissions of total hydrocarbons (HC), carbon monoxide (CO), oxides of nitrogen (NOx), nitric oxide (NO) and nitrogen dioxide (NO2), oxygen (O2) and carbon dioxide (CO2); and particle size distributions at normal dilution ratio (NDR) and higher dilution ratio (HDR). Significant reductions were observed for TPM and SOL (>90%), SOF (>80%) and XOC (>70%) across the DOC-CPF at both modes.

The objective of this research was to study the effect of a catalyzed particulate filter (CPF) with a high loading of catalyst (50 gms/ft3) and ultra low sulfur fuel (ULSF -0.57 ppm of sulfur) on the emissions from a heavy duty diesel engine. The particulate emissions were measured using two different analytical methods, i.e., the gravimetric method and the thermal optical method (TOM). The results from the two different methods of analyses were compared. The experiments were performed at four different operating conditions chosen from the old Environmental Protection Agency (EPA) 13-mode test cycle. A 1995 Cummins M11 heavy-duty engine with manually controlled exhaust gas recirculation (EGR) was used to perform the emission characterization experiments. The emission characterization included total particulate matter (TPM), which is composed of the solids (SOL), soluble organic fractions (SOF) and sulfates (SO4) analyzed using the gravimetric method.

A new diesel van with a reference weight of 1661 kg and a pre-chamber engine with a displacement of 2400cc was tested on a chassis dynamometer. The fuel consumption and emissions of carbon monoxide, unburned hydrocarbons, nitrogen oxides, carbon dioxide, particulate matter and associated organic material (SOF) as well as PAH (Polycyclic Aromatic Hydrocarbons) were measured under different driving conditions. The driving patterns used were recorded with a chase car at real traffic conditions on several roads in Copenhagen. The emissions were measured using different kind of diesel fuels as well as RME and biodiesel. CO, CO2, HC, and NOx levels generally decreased with increasing average speed of the driving cycle for all fuels tested. Cold start emissions were generally higher than for warm start.

The primary objective of this study was to evaluate the impact of three different biodiesel feedstocks on emissions compared to a baseline CARB ULSD with two heavy-duty trucks equipped with and without aftertreatment technologies. The biodiesels included a soybean oil methyl ester (SME), a waste cooking oil methyl ester (WCO), and a methyl ester obtained from animal fat (AFME), blended at a 50% level by volume with the CARB diesel. The vehicles were equipped with a 2010 Cummins ISX-15 engine with a selective catalytic reduction (SCR), diesel oxidation catalyst (DOC) and a diesel particulate filter (DPF) and with a 2002 Cummins ISX-450 engine. Both vehicles were tested over the Urban Dynamometer Driving Schedule (UDDS) on a heavy-duty chassis dynamometer. For this study, nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO2), total hydrocarbons (THC), methane (CH4), non-methane hydrocarbons (NMHC), and particulate matter (PM) were measured.

Owing to climate change issues caused by global warming, the role of alternative fuels, such as low-carbon and non-carbon fuels, is becoming increasingly important, particularly in the transportation sector. Therefore, hydrogen has emerged as a promising fuel for internal combustion engines because it does not emit carbon dioxide. Direct injection is mandatory for hydrogen-based internal combustion engines to mitigate backfires and low energy density. However, there is a lack of measurement of the equivalence ratio methodology because hydrogen has a higher diffusion rate than conventional fuels. The objective of this research is a feasibility study of laser-induced breakdown spectroscopy (LIBs) for measuring the equivalence ratio. The second harmonic ND-YAG laser was implemented to induce the atomic emission of hydrogen via the breakdown phenomenon. Simultaneously, the hydrogen jet structure was visualized in a constant volume vessel using Schlieren imaging.

Hydrogen exhibits the notable attribute of lacking carbon dioxide emissions when used in internal combustion engines. Nevertheless, hydrogen has a very low energy density per unit volume, along with large emissions of nitrogen oxides and the potential for backfire. Thus, stratified charge combustion (SCC) is used to reduce nitrogen oxides and increase engine efficiency. Although SCC has the capacity to expand the lean limit, the stability of combustion is influenced by the mixture formation time (MFT), which determines the equivalence ratio. Therefore, quantifying the equivalence ratio under different MFT is critical since it determines combustion characteristics. This study investigates the viability of using a Laser Induced Breakdown Spectroscopy (LIBS) for measuring the jet equivalence ratio. Furthermore, study was conducted to analyze the effect of MFT and the double injection parameter, namely the dwell time and split ratio, on the equivalence ratio.