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Catalyzed Particulate Filter Passive Oxidation Study with ULSD and Biodiesel Blended Fuel

2012-06-18
The development of PM and NOx reduction system with the combination of DOC included DPF and SCR catalyst in addition to the AOC sub-assembly for NH3 slip protection is described. DPF regeneration strategy and manual regeneration functionality are introduced with using ITH, HCI device on the EUI based EGR, VGT 12.3L diesel engine at the CVS full dilution tunnel test bench. With this system, PM and NOx emission regulation for JPNL was satisfied and DPF regeneration process under steady state condition and transient condition (JE05 mode) were successfully fulfilled. Manual regeneration process was also confirmed and HCI control strategy was validated against the heat loss during transient regeneration mode. Presenter Seung-il Moon
Technical Paper

Experimental Investigation of the Compression Ignition Process of High Reactivity Gasoline Fuels and E10 Certification Gasoline using a High-Pressure Direct Injection Gasoline Injector

2020-04-14
2020-01-0323
Gasoline compression ignition (GCI) technology shows the potential to obtain high thermal efficiencies while maintaining low soot and NOx emissions in light-duty engine applications. Recent experimental studies and numerical simulations have indicated that high reactivity gasoline-like fuels can further enable the benefits of GCI combustion. However, there is limited empirical data in the literature studying the gasoline compression ignition process at relevant in-cylinder conditions, which are required for further optimizing combustion system designs. This study investigates the temporal and spatial evolution of the compression ignition process of various high reactivity gasoline fuels with research octane numbers (RON) of 71, 74 and 82, as well as a conventional RON 97 E10 gasoline fuel. A ten-hole prototype gasoline injector specifically designed for GCI applications capable of injection pressures up to 450 bar was used.
Journal Article

Impact of Biodiesel Impurities on the Performance and Durability of DOC, DPF and SCR Technologies

2011-04-12
2011-01-1136
It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil-derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter.
Technical Paper

High Performance Biodegradable Fluid Requirements for Mobile Hydraulic Systems

1998-04-08
981518
Technical groups worldwide have been actively developing specifications and requirements for biodegradable hydraulic fluids for mobile applications. These groups have recognized that an industry-wide specification is necessary due to the increase in environmental awareness in the agriculture, construction, forestry, and mining industries, and to the increasing number of local regulations primarily throughout Europe. Caterpillar has responded to this need by publishing a requirement, Caterpillar BF-1, that may be used by Caterpillar dealers, customers, and industry to help select high-performance biodegradable hydraulic fluids. This requirement was written with the input of several organizations that are known to be involved with the development of similar types of specifications and requirements.
Technical Paper

The Calculation of Mass Fraction Burn of Ethanol-Gasoline Blended Fuels Using Single and Two-Zone Models

2008-04-14
2008-01-0320
One-dimensional single-zone and two-zone analyses have been exercised to calculate the mass fraction burned in an engine operating on ethanol/gasoline-blended fuels using the cylinder pressure and volume data. The analyses include heat transfer and crevice volume effects on the calculated mass fraction burned. A comparison between the two methods is performed starting from the derivation of conservation of energy and the method to solve the mass fraction burned rates through the results including detailed explanation of the observed differences and trends. The apparent heat release method is used as a point of reference in the comparison process. Both models are solved using the LU matrix factorization and first-order Euler integration.
Technical Paper

Development of an In-Service Snowmobile Emission Test Procedure For the SAE Clean Snowmobile Challenge

2009-11-02
2009-01-2625
As concerns over air pollution continue to increase, all vehicles are subject to greater scrutiny for their emissions levels. Snowmobiles and other off-road recreational vehicles are now required to meet emissions regulations enacted by the United States Environmental Protection Agency (EPA). Currently these vehicles are certified using a stationary test procedure with the engine operating attached to a dynamometer and following a five-mode test cycle. The five modes range from idle to wide open throttle and are chosen to represent the typical operation regime of a vehicle. In addition, the EPA five-mode stationary emissions test has been traditionally used for scoring competition snowmobiles at the SAE Clean Snowmobile Challenge (CSC). For the 2009 CSC, in-service emission testing was added to the competition to score the teams on actual, in-use emissions during operation of their competition snowmobile operated on a controlled test course.
Technical Paper

On-Site DME Generation from Methanol for Pilot Injection in CI Engines

2003-10-27
2003-01-3198
Dual fuel (CI) engines provide an excellent means of maintaining high thermal efficiency and power while reducing emissions, particularly in situations where the primary fuel does not exhibit good auto-ignition characteristics. This is especially true of diesel engines operating on natural gas; usually in stationary applications such as distributed power generation. However, because two fuels are needed, the reliability of the engine is compromised. Therefore, this paper describes the first phase of a project that is to eventually manufacture dimethyl ether (DME) from natural gas and supply it to the pilot injector of a dual fuel engine. A chemical pilot plant has been built and operated, demonstrating an intermediate step in the production of DME from natural gas. DME is manufactured from methanol for pilot injection into a dual fuel engine operating with natural gas as the main fuel.
Technical Paper

Plasma-Facilitated SCR of NOx in Heavy-Duty Diesel Exhaust

2001-09-24
2001-01-3570
This paper describes two independent studies on γ-alumina as a plasma-activated catalyst. γ-alumina (2.5 - 4.3 wt%) was coated onto the surface of mesoporous silica to determine the importance of aluminum surface coordination on NOx conversion in conjunction with nonthermal plasma. Results indicate that the presence of 5- and 6- fold aluminum coordination sites in γ-alumina could be a significant factor in the NOx reduction process. A second study examined the effect of changing the reducing agent on NOx conversion. Several hydrocarbons were examined including propene, propane, isooctane, methanol, and acetaldehyde. It is demonstrated that methanol was the most effective reducing agent of those tested for a plasma-facilitated reaction over γ-alumina.
Technical Paper

Oxidation Catalytic Converter and Emulsified Fuel Effects on Heavy-Duty Diesel Engine Particulate Matter Emissions

2002-03-04
2002-01-1278
The effects of an oxidation catalytic converter (OCC), an emulsified fuel, and their combined effects on particle number and volume concentrations compared to those obtained when using a basefuel were studied. Particle size and particulate emission measurements were conducted at three operating conditions; idle (850 rpm, 35 Nm), Mode 11 (1900 rpm, 277 Nm) and Mode 9 (1900 rpm, 831 Nm) of the EPA 13 mode cycle. The individual effects of the emulsified fuel and the OCC as well as their combined effects on particle number and volume concentrations were studied at two different particle size ranges; the nuclei (less than or equal to 50 nm) and accumulation (greater than 50 nm) modes. An OCC loaded with 10 g/ft3 platinum metal (OCC1) and a 20% emulsified fuel were used for this study and a notable influence on the particle size with respect to number and volume distributions was observed.
Technical Paper

Experimental and Simulated Results Detailing the Sensitivity of Natural Gas HCCI Engines to Fuel Composition

2001-09-24
2001-01-3609
Natural gas quality, in terms of the volume fraction of higher hydrocarbons, strongly affects the auto-ignition characteristics of the air-fuel mixture, the engine performance and its controllability. The influence of natural gas composition on engine operation has been investigated both experimentally and through chemical kinetic based cycle simulation. A range of two component gas mixtures has been tested with methane as the base fuel. The equivalence ratio (0.3), the compression ratio (19.8), and the engine speed (1000 rpm) were held constant in order to isolate the impact of fuel autoignition chemistry. For each fuel mixture, the start of combustion was phased near top dead center (TDC) and then the inlet mixture temperature was reduced. These experimental results have been utilized as a source of data for the validation of a chemical kinetic based full-cycle simulation.
Technical Paper

HEUI Injector Modeling and ROI Experiments for High Injection Pressure of Diesel and Dimethyl Ether (DME)

2016-04-05
2016-01-0855
Dimethyl Ether (DME) is considered a clean alternative fuel to diesel due to its soot-free combustion characteristics and its capability to be produced from renewable energy sources rather than fossil fuels such as coal or petroleum. To mitigate the effect of strong wave dynamics on fuel supply lines caused due to the high compressibility of DME and to overcome its low lubricity, a hydraulically actuated electronic unit injector (HEUI) with pressure intensification was used. The study focuses on high pressure operation, up to 2000 bar, significantly higher than pressure ranges reported previously with DME. A one-dimensional HEUI injector model is built in MATLAB/SIMULINK graphical software environment, to predict the rate of injection (ROI) profile critical to spray and combustion characterization.
Technical Paper

Numerical Investigation of Spark Ignition Events in Lean and Dilute Methane/Air Mixtures Using a Detailed Energy Deposition Model

2016-04-05
2016-01-0609
It is beneficial but challenging to operate spark-ignition engines under highly lean and dilute conditions. The unstable ignition behavior can result in downgraded combustion performance in engine cylinders. Numerical approach is serving as a promising tool to identify the ignition requirements by providing insight into the complex physical/chemical phenomena. An effort to simulate the early stage of flame kernel initiation in lean and dilute fuel/air mixture has been made and discussed in this paper. The simulations are set to validate against laboratory results of spark ignition behavior in a constant volume combustion vessel. In order to present a practical as well as comprehensive ignition model, the simulations are performed by taking into consideration the discharge circuit analysis, the detailed reaction mechanism, and local heat transfer between the flame kernel and spark plug.
Technical Paper

Simulation of One-pass Dimethylether Production from Natural Gas for Potential Use in a NG/DME Dual-fuel CI Engine

2006-10-16
2006-01-3358
A model process to produce dimethylether (DME) from natural gas (NG) was simulated in a one-pass mode (no material recycle), assuming steady-state and chemical and physical equilibrium. NG conversion to synthesis gas (syngas) via steam reforming resulted in stoichiometric numbers of 2.97 along with vapor mole fraction extremes for carbon dioxide, methane, and water. These concentrations formed an eight-trial simulation grid of syngas compositions. Simulation of DME production was performed in a dual reactor configuration with methanol formation as the intermediate compound. Solutions resulting from the subsequent adiabatic dehydration of the methanol-rich phase showed a consistent DME composition (88%). The resulting solutions and unreacted syngas streams from simulation were examined for applicability to a dual-fuel NG/DME CI engine.
Technical Paper

Investigation of Combustion Knock Distribution in a Boosted Methane-Gasoline Blended Fueled SI Engine

2018-04-03
2018-01-0215
The characteristics of combustion knock metrics over a number of engine cycles can be an essential reference for knock detection and control in internal combustion engines. In a Spark-Ignition (SI) engine, the stochastic nature of combustion knock has been shown to follow a log-normal distribution. However, this has been derived from experiments done with gasoline only and applicability of log-normal distribution to dual-fuel combustion knock has not been explored. To evaluate the effectiveness and accuracy of log-normal distributed knock model for methane-gasoline blended fuel, a sweep of methane-gasoline blend ratio was conducted at two different engine speeds. Experimental investigation was conducted on a single cylinder prototype SI engine equipped with two fuel systems: a direct injection (DI) system for gasoline and a port fuel injection (PFI) system for methane.
Technical Paper

Catalyzed Particulate Filter Passive Oxidation Study with ULSD and Biodiesel Blended Fuel

2012-04-16
2012-01-0837
A 2007 Cummins ISL 8.9L direct-injection common rail diesel engine rated at 272 kW (365 hp) was used to load the filter to 2.2 g/L and passively oxidize particulate matter (PM) within a 2007 OEM aftertreatment system consisting of a diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF). Having a better understanding of the passive NO₂ oxidation kinetics of PM within the CPF allows for reducing the frequency of active regenerations (hydrocarbon injection) and the associated fuel penalties. Being able to model the passive oxidation of accumulated PM in the CPF is critical to creating accurate state estimation strategies. The MTU 1-D CPF model will be used to simulate data collected from this study to examine differences in the PM oxidation kinetics when soy methyl ester (SME) biodiesel is used as the source of fuel for the engine.
Technical Paper

Blend Ratio Optimization of Fuels Containing Gasoline Blendstock, Ethanol, and Higher Alcohols (C3-C6): Part II - Blend Properties and Target Value Sensitivity

2013-04-08
2013-01-1126
Higher carbon number alcohols offer an opportunity to meet the Renewable Fuel Standard (RFS2) and improve the energy content, petroleum displacement, and/or knock resistance of gasoline-alcohol blends from traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part II of this paper builds upon the alcohol selection, fuel implementation scenarios, criteria target values, and property prediction methodologies detailed in Part I. For each scenario, optimization schemes include maximizing energy content, knock resistance, or petroleum displacement. Optimum blend composition is very sensitive to energy content, knock resistance, vapor pressure, and oxygen content criteria target values. Iso-propanol is favored in both scenarios' suitable blends because of its high RON value.
Technical Paper

Blend Ratio Optimization of Fuels Containing Gasoline Blendstock, Ethanol, and Higher Alcohols (C3-C6): Part I - Methodology and Scenario Definition

2013-04-08
2013-01-1144
The U.S. Renewable Fuel Standard (RFS2) requires an increase in the use of advanced biofuels up to 36 billion gallons by 2022. Longer chain alcohols, in addition to cellulosic ethanol and synthetic biofuels, could be used to meet this demand while adhering to the RFS2 corn-based ethanol limitation. Higher carbon number alcohols can be utilized to improve the energy content, knock resistance, and/or petroleum displacement of gasoline-alcohol blends compared to traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part I of this paper focuses on the development of scenarios by which to compare higher alcohol fuel blends to traditional ethanol blends. It also details the implementation of fuel property prediction methods adapted from literature. Possible combinations of eight alcohols mixed with a gasoline blendstock were calculated and the properties of the theoretical fuel blends were predicted.
Technical Paper

Multivariate Regression and Generalized Linear Model Optimization in Diesel Transient Performance Calibration

2013-10-14
2013-01-2604
With stringent emission regulations, aftertreatment systems with a Diesel Particulate Filter (DPF) and a Selective Catalytic Reduction (SCR) are required for diesel engines to meet PM and NOx emissions. The adoption of aftertreatment increases the back pressure on a typical diesel engine and makes engine calibration a complicated process, requiring thousands of steady state testing points to optimize engine performance. When configuring an engine to meet Tier IV final emission regulations in the USA or corresponding Stage IV emission regulations in Europe, this high back pressure dramatically impacts transient performance. The peak NOx, smoke and exhaust temperature during a diesel engine transient cycle, such as the Non-Road Transient Cycle (NRTC) defined by the US Environmental Protection Agency (EPA), will in turn affect the performance of the aftertreatment system and the tailpipe emissions level.
Technical Paper

The Effects of Fuel Sulfur Concentration on Regulated and Unregulated Heavy-Duty Diesel Emissions

1993-03-01
930730
The effects of fuel sulfur concentration on heavy-duty diesel emissions have been studied at two EPA steady-state operating conditions, mode 9 (1900 RPM, 75% Load) and mode 11(1900 RPM, 25% Load). Data were obtained using one fuel at two sulfur levels (Low Sulfur, LS = 0.01 wt% S and Doped Low Sulfur DS = 0.29 wt% S). All tests were conducted using a Cummins LTA10-300 heavy-duty diesel engine. No significant changes were found for the nitrogen oxides (NOx), soluble organic fractions (SOF) and XAD-2 (a copolymer of styrene and divinylbenzene) organic component (XOC) due to the fuel sulfur level increase at either engine mode. The hydrocarbon (HC) levels were not significantly affected by sulfur at mode 9; however, at mode 11 the HC levels were reduced by 16%. The total particulate matter (TPM) levels increased by 17% at mode 11 and by 24% at mode 9 (both significantly different).
Technical Paper

An Experimental Investigation into Particulate Matter Oxidation in a Catalyzed Particulate Filter with Biodiesel Blends on an Engine during Active Regeneration

2013-04-08
2013-01-0521
Active regeneration experiments were carried out on a production 2007 Cummins 8.9L ISL engine and associated diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF) aftertreatment system. The effects of SME biodiesel blends were investigated to determine the particulate matter (PM) oxidation reaction rates for active regeneration. The experimental data from this study will also be used to calibrate the MTU-1D CPF model [1]. The experiments covered a range of CPF inlet temperatures using ULSD, B10, and B20 blends of biodiesel. The majority of the tests were performed at a CPF PM loading of 2.2 g/L with in-cylinder dosing, although 4.1 g/L and a post-turbo dosing injector were also investigated. The PM reaction rate was shown to increase with increasing percent biodiesel in the test fuel as well as increasing CPF temperature.
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