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The degradation rate of Li-ion batteries and therefore their useful life depends on many parameters, including temperature, charge/discharge rates, the chemistry and microstructure of electrodes. The importance of understanding these mechanisms explains the large interest in developing predictive electrochemical ageing models accounting for the known deterioration mechanisms, mainly related to SEI layer formation and Li-plating. Usually, these ageing models are developed and applied at cell level assuming perfect uniformity in all dimensions apart from the through-plane direction. In this work, we extend the model to all dimensions within the cell to account for intra-cell non-uniformities in terms of local temperature and current. However, the temperature distribution of a cell within a battery pack depends on the interaction with its environment, which typically involves active cooling via an external fluid circulation within a channel network.

The degradation rate of a Li-ion battery is a complex function of temperature and charge/discharge rates over its lifetime. There is obviously a keen interest in predictive electrochemical ageing models that account for known degradation mechanisms, primarily linked with the Solid Electrolyte Interface (SEI) formation and Li-plating, which are highly dependent on the cell temperature. Typically, such ageing models are formulated and employed at pack or cell level, neglecting intra-cell and cell-to-cell thermal and electrical non-uniformities. On the other hand, thermal management techniques can mitigate ageing by maintaining the battery pack within the desired temperature window either by cooling or heating. Inevitably, the cooling of the battery pack by conventional heat exchangers will introduce temperature non-uniformities that may in turn result in undesired intra-cell and/or cell-to-cell health non-uniformities.