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Trapped air bubbles inside coolant systems have adverse effect on the cooling performance. Hence, it is imperative to ensure an effective filling and de-aeration of the coolant system in order to have less air left before the operation of the coolant system. In the present work, a coolant/air multiphase VOF method was utilized using the commercial CFD software SimericsMP+® to study the coolant filling and subsequent de-aeration process in a Battery Electric Vehicle (BEV) cooling system. First, validations of the numerical simulations against experiments were performed for a simplified coolant recirculation system. This system uses a tequila bottle for de-aeration and the validations were performed for different coolant flow rates to examine the de-aeration efficiency. A similar trend of de-aeration was captured between simulation and experimental measurement.