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Combustion of a lean air-fuel mixture diluted with a large amount of air or Exhaust Gas Recirculation (EGR) gas is one of the important technologies that can reduce thermal NOx and improve gasoline engine fuel economy by reducing cooling loss. On the other hand, lean combustion increases unburned Hydro Carbon (HC) and unburned loss compared to stoichiometric combustion. This is because lean combustion reduces the burning rate of the air-fuel mixture and forms a thick quenching layer near the wall surface. In this study, the relationship between the thickness of the unburned HC and the excess air ratio is analyzed using Laser Induced Fluorescence (LIF) method and Computational Fluid Dynamic (CFD) of combustion. The HC distribution near the engine liner when the excess air ratio is increased is investigated by LIF. As a result, it is found that the quenching distance of the flame in the cylinder is larger for lean conditions than the general single-wall quenching relationship.

In order to enhance the catalytic performance of the NOx Storage-Reduction Catalyst (NSR Catalyst), the sulfur tolerance of the NSR catalyst was improved by developing new support and NOx storage materials. The support material was developed by nano-particle mixing of ZrO2-TiO2 and Al2O3 in order to increase the Al2O3-TiO2 interface and to prevent the ZrO2-TiO2 phase from sintering. A Ba-Ti oxide composite material was also developed as a new NOx storage material containing highly dispersed Ba. It was confirmed that the sulfur tolerance and activity of the developed NSR catalyst are superior to that of the conventional one.

Diesel particulate and NOx reduction system (DPNR) is an effective technology for the diesel after-treatment system, which can reduce particulate matter (PM) and nitrogen oxides (NOx) simultaneously. The DPNR has been developed under the Toyota D-CAT (Diesel Clean Advanced Technology) concept. Further improvement of the DPNR is hoped for cleaner air in the future. This paper reviews the results of our study to improve the NOx purification performance on the DPNR. The NOx reduction performance of the catalysts deteriorates due to thermal deterioration and sulfur poisoning. In order to improve the thermal resistance of the catalysts, the suppression of precious metal sintering in the catalyst has been studied. As a result, higher catalytic activity after aging especially under lower temperature conditions was obtained. On the other hands, improvement of desulfurization performance is one of the key technologies in order to keep the high NOx reduction capability of the catalyst.

Our two types of NOx storage-reduction (NSR) catalyst have been tested under various conditions of thermal endurance; the performance of these catalysts have been regressed to give the formulas that enable to estimate the performance after thermal endurance; and we have found the method to simplify (shorten the duration of) the thermal endurance tests and that the thermal deterioration of NSR catalysts is controlled by the worst condition of endurance (at least approximately). The regression formula for the amount of potassium that contributes to the catalyst performance (active K) after the endurance has also been obtained. These formulas predict that the amount of active K is the least for the worst condition of endurance and suggest a difference in deterioration mechanism that reflects the performance between low and high temperatures and the portion of worse deterioration (front or rear).

A new after-treatment system called DPNR (Diesel Particulate-NOx Reduction System) has been developed for simultaneous and continuous reduction of particulate matter (PM) and nitrogen oxides (NOx) in diesel exhaust gas. This system consists of both a new catalytic technology and a new diesel combustion technology which enables rich operating conditions in diesel engines. The catalytic converter for the DPNR has a newly developed porous ceramic structure coated with a NOx storage reduction catalyst. A fresh DPNR catalyst reduced more than 80 % of both PM and NOx. This paper describes the concept and performance of the system in detail. Especially, the details of the PM oxidation mechanism in DPNR are described.

A highly efficient new 2.8-liter inline 4-cylinder diesel engine has been developed in response to growing demand for diesel engines and to help save energy while providing high-torque performance. Engine efficiency was improved by reducing cooling loss based on an innovative combustion concept applied across the whole engine. Cooling loss was reduced by restricting in-cylinder gas flows and improving combustion chamber insulation. To prevent the restricted gas flows from affecting emissions, a new combustion chamber shape was developed that increased air utilization in the cylinder through optimizing the in-cylinder fuel distribution. Combustion chamber insulation was improved by a new insulation coat that changes the wall surface temperature in accordance with the gas temperature. This reduces cooling loss and avoids the trade-off effect of intake air heating.

Exhaust emissions are well known to have adverse impacts on human health. Studies have demonstrated that there is an association between ambient particulate matter (PM) levels and various harmful cardiopulmonary conditions. Soot exhaust from diesel engines can be a significant contributor to airborne pollutants. A key component in PM level control for a diesel engine is a diesel particulate filter (DPF). This device traps soot while allowing other exhaust gases to pass unhindered. However, the performance of diesel particulate filters can change with increasing soot loadings and thus may require regeneration or replacement. Improved understanding of diesel particulate filters is dependent upon the knowledge of the actual soot loading and the soot distribution within the DPF. Neutron radiography (NR) has been identified as an effective means of non-destructively identifying hydrogen or carbon adsorbed in PM.

Low pressure loop (LPL) EGR systems are effective means of simultaneously reducing the NOx emissions and fuel consumption of diesel engines. Further lower emission levels can be achieved by adopting a system that combines LPL EGR with a NOx storage and reduction (NSR) catalyst. However, this combined system has to overcome the issue of combustion fluctuations resulting from changes in the air-fuel ratio due to EGR gas recirculation from either NOx reduction control or diesel particulate filter (DPF) regeneration. The aim of this research was to reduce combustion fluctuations by developing LPL EGR control logic. In order to control the combustion fluctuations caused by LPL EGR, it is necessary to estimate the recirculation time. First, recirculation delay was investigated. It was found that recirculation delay becomes longer when the LPL EGR flow rate or engine speed is low.

From the point of global and local environment, internal combustion engine is facing the need for significant improvement of exhaust emission. Especially, important is the reduction of unburned hydrocarbon (HC) from fuel film on liner under cold condition. In this study, at first, quantitative fuel film measurement technique by using Laser Induced Exciplex Fluorescence (LIEF) was developed. For the light source, 4th harmonic pulse yttrium aluminum garnet (YAG) laser (266nm) was used. For the tracer, the combination of N,N-Dimethylaniline (DMA) and naphthalene was used and quantitative concentration was decided by calibration test. With LIEF, the distribution of fuel film can be obtained by measuring the fluorescence only from the liquid phase. In order to evaluate the effect of fuel film on exhaust HC emission from engine, the film distribution was measured using quartz glass liner. For the injector, a prototype 6-hole gasoline injector was used.