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Biofuel usage is increasingly expanding thanks to its significant contribution to a well-to-wheel (WTW) reduction of greenhouse gas (GHG) emissions. In addition, stringent emission standards make mandatory the use of Diesel Particulate Filter (DPF) for the particulate emissions control. The different physical properties and chemical composition of biofuels impact the overall engine behaviour. In particular, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value (LHV). More specifically, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value, respectively. The particle emissions, in fact, are lower mainly because of the higher oxygen content. Subsequently less frequent regenerations are required.

The paper will discuss the design and development of heavy-duty diesel engines to meet the US EPA 2010 on-highway standards - 0.2 g/HP-hr NOx and 0.01 g/HP-hr particulate matter (PM). In meeting these standards a combination of in-cylinder control and aftertreatment control for both NOx and particulate has been used. For NOx control, a combination of cooled exhaust gas recirculation (EGR) and selective catalytic reduction (SCR) is used. The SCR catalyst uses copper zeolite to achieve high levels of NOx conversion efficiency with minimal ammonia slip and unparalleled thermal durability. For particulate control, a diesel particulate filter (DPF) with upstream oxidation catalyst (DOC) is used. While the DPF may be actively regenerated when required, it operates predominantly with passive regeneration - enabled by the high NOx levels between the engine and the DPF, associated with high efficiency SCR systems and NO₂ production across the DOC.

Cu- and Fe-zeolite SCR catalysts emerged in recent years as the primary candidates for meeting the increasingly stringent lean exhaust emission regulations, due to their outstanding activity and durability characteristics. It is commonly known that Cu-zeolite catalysts possess superior activity to Fe-zeolites, in particular at low temperatures and sub-optimal NO₂/NOx ratios. In this work, we elucidate some underlying mechanistic differences between these two classes of catalysts, first based on their NO oxidation abilities, and then based on the relative properties of the two types of exchanged metal sites. Finally, by using the ammonia coverage-dependent NOx performance, we illustrate that state-of-the-art Fe-zeolites can perform better under certain transient conditions than in steady-state.

The world-wide commercial vehicle industry is faced with numerous challenges to reduce oil consumption and greenhouse gases, meet stringent emissions regulations, provide customer value, and improve safety. This work focuses on the new U.S. regulation of greenhouse gas (GHG) emissions from commercial vehicles and diesel engines and the most likely technologies to meet future anticipated standards while improving transportation freight efficiency. In the U.S., EPA and NHTSA have issued a joint proposed GHG rule that sets limits for CO2 and other GHGs from pick-up trucks and vans, vocational vehicles, semi-tractors, and heavy duty diesel engines. This paper discusses and compares different technologies to meet GHG regulations for diesel engines based on considerations of cost, complexity, real-world fidelity, and environmental benefit.

In recent years, the increase of gasoline fuel injection pressure is a way to improve thermal efficiency and lower engine-out emissions in GDI homogenous combustion concept. The challenge of controlling particulate formation as well in mass and number concentrations imposed by emissions regulations can be pursued improving the mixture preparation process and avoiding mixture inhomogeneity with ultra-high injection pressure values up to 100 MPa. The increase of the fuel injection pressure in GDI homogeneous systems meets the demand for increased injector static flow, while simultaneously improves the spray atomization and mixing characteristics with consequent better combustion performance. Few studies quantify the effects of high injection pressure on transient gasoline spray evolution. The aim of this work was to simulate with OpenFOAM the spray morphology of a commercial gasoline injected in a constant volume vessel by a prototypal GDI injector.

Cooled EGR continues to be a key technology to meet emission regulations, with EGR coolers performing a critical role in the EGR system. Designing EGR coolers that reliably manage thermal loads is a challenge with thermal fatigue being a top concern. The ability to estimate EGR cooler thermal fatigue life early in the product design and validation cycle allows for robust designs that meet engine component reliability requirements and customer expectations. This paper describes a process to create an EGR cooler thermal fatigue life model. Components which make up the EGR cooler have differing thermal responses, consequently conjugate transient CFD must be used to accurately model metal temperatures during heating and cooling cycles. Those metal temperatures are then imported into FEA software for structural analysis. Results from both the CFD and FEA are then used in a simplified numerical model to estimate the virtual strain of the EGR cooler.

A 1-dimensional analytic solution has been developed to evaluate the pressure drop and filtration performance of ceramic wall-flow partial diesel particulate filters (PFs). An axially resolved mathematical model for the static pressure and velocity profiles prevailing inside wall-flow filters, with such unique plugging configurations, is being proposed for the first time. So far, the PF models that have been developed are either iterative/numerical in nature [1], or based on commercial CFD packages [7]. In comparison, an analytic solution approach is a transparent and computationally inexpensive tool that is capable of accurately predicting trends as well as, offering explanations to fundamental performance behavior. The simple mathematical expressions that have been obtained facilitate rational decision-making when designing partial filters, and could also reduce the complexity of OBD logic necessary to control onboard filter performance.

Future light duty vehicles in the United States are required to be certified on the FTP-75 cycle to meet Tier 3 or LEV III emission standards [1, 2]. The cold phase of this cycle is heavily weighted and mitigation of emissions during this phase is crucial to meet the low tail pipe emission targets [3, 4]. In this work, a novel aftertreatment architecture and controls to improve Nitrogen Oxides (NOx) and Hydrocarbon (HC) or Non Methane Organic gases (NMOG) conversion efficiencies at low temperatures is proposed. This includes a passive NOx & HC adsorber, termed the diesel Cold Start Concept (dCSC™) catalyst, followed by a Selective Catalytic Reduction catalyst on Filter (SCRF®) and an under-floor Selective Catalytic Reduction catalyst (SCR). The system utilizes a gaseous ammonia delivery system capable of dosing at two locations to maximize NOx conversion and minimize parasitic ammonia oxidation and ammonia slip.

Regeneration of diesel particulate filters poses major challenges in developing the particulate matter emission control technology to meet EPA 2007/2010 emissions regulations. The problem areas are multifold due to the complexity involved in designing the filter system, developing regeneration strategies and controlling the regeneration process. This paper discusses the need for active regeneration systems. It also addresses several key limitations and trade-offs between the regeneration strategy, chemical kinetics, exhaust gas temperature and the regeneration efficiency. Passive regeneration of diesel particulate filter systems is known to be highly dependent on the engine-out [NOx/PM] ratio as well as exhaust temperature over the duty cycle. Using catalytic oxidation of auxiliary fuel injected into the system, the exhaust gas temperature can be successfully enhanced for filter regeneration.

To meet the future stringent emission standards, innovative diesel engine technology, exhaust gas after-treatment, and clean alternative fuels are required. Oxygenated fuels have showed a tendency to decrease internal combustion engine emissions. In the same time, advanced fuel injection modes can promote a further reduction of the pollutants at the exhaust without penalty for the combustion efficiency. One of the more interesting solutions is provided by the premixed low temperature combustion (LTC) mechanism jointly to lower-cetane, higher-volatility fuels. In this paper, to understand the role played by these factors on soot formation, cycle resolved visualization, UV-visible optical imaging and visible chemiluminescence were applied in an optically accessed high swirl multi-jets compression ignition engine. Combustion tests were carried out using three fuels: commercial diesel, a blend of 80% diesel with 20% gasoline (G20) and a blend of 80% diesel with 20% n-butanol (BU20).

In August of 2011, the US Environmental Protection Agency issued new Green House Gas (GHG) emissions regulations for heavy duty vehicles. These regulations included new procedures for the evaluation of hybrid powertrains and vehicles. One of the hybrid options allows for the evaluation of an engine plus a hybrid transmission (a powertrain). For this type of testing, EPA has proposed simulating a vehicle following the hybrid vehicle test procedures, including the use of the vehicle cycles and the A to B comparison testing - as required for the full vehicle evaluation option. This paper proposes an alternative approach by defining a powertrain cycle. The powertrain cycle is based on the heavy duty engine emissions cycle - the transient FTP cycle. Simulation and test results are presented showing similar performance over the engine and vehicle cycles. This approach offers several advantages as compared to the procedure described in EPA's GHG rule.

Light duty vehicle emission standards are getting more stringent than ever before as stipulated by US EPA Tier 2 Standards and LEV III regulations proposed by CARB. The research in this paper sponsored by US DoE is focused towards developing a Tier 2 Bin 2 Emissions compliant light duty pickup truck with class leading fuel economy targets of 22.4 mpg “City” / 34.3 mpg “Highway”. Many advanced technologies comprising both engine and after-treatment systems are essential towards accomplishing this goal. The objective of this paper would be to discuss key engine technology enablers that will help in achieving the target emission levels and fuel economy. Several enabling technologies comprising air-handling, fuel system and base engine design requirements will be discussed in this paper highlighting both experimental and analytical evaluations.

Pending reductions in light duty vehicle PM emissions standards from 10 to 3 mg/mi and below will push the limits of the gravimetric measurement method. At these levels the PM mass collected approaches the mass of non-particle gaseous species that adsorb onto the filter from exhaust and ambient air. This introduces an intrinsic lower limit to filter based measurement that is independent of improvements achieved in weighing metrology. The statistical variability of back-up filter measurements at these levels makes them an ineffective means for correcting the adsorption artifact. The proposed subtraction of a facility based estimate of the artifact will partially alleviate the mass bias from adsorption, but its impact on weighing variability remains a problem that can reach a significant fraction of the upcoming 3 and future 1 mg/mi standards. This paper proposes an improved PM mass method that combines the gravimetric filter approach with real time aerosol measurement.

Mitigation of ammonia slip from SCR system is critical to meeting the evolving NH₃ emission standards, while achieving maximum NOx conversion efficiency. Ammonia slip catalysts (ASC) are expected to balance high activity, required to oxidize ammonia across a broad range of operating conditions, with high selectivity of converting NH₃ to N₂, thus avoiding such undesirable byproducts as NOx or N₂O. In this work, new insights into the behavior of an advanced ammonia slip catalyst have been developed by using accelerated progressive catalyst aging as a tool for catalyst property interrogation. The overall behavior was deconstructed to several underlying functions, and referenced to an active but non-selective NH₃ oxidation function of a diesel oxidation catalyst (DOC) and to the highly selective but minimally active NH₃ oxidation function of an SCR catalyst.

In order to meet more stringent evaporative emissions requirements, multiple advancements in vehicle fuel system and carbon canister technologies have been made. Regardless of technological advancements, the vapor pressure of the fuel remains a vital property in controlling evaporative emissions. A series of tests were performed to explore the effects of vapor pressure on multiday diurnal evaporative emissions for 9 and 10 psi Reid Vapor Pressure (RVP) 10% ethanol (E10) gasoline-blend fuels, followed by tests with 7 psi RVP E10 gasoline on a subset of the same vehicles. A test procedure was developed to monitor evaporative emissions, canister loading profiles and breakthrough emissions for each of the fuels. A total of five vehicles were tested on all 3 fuels, blended to represent 7, 9, and 10 psi at sea level. Tests were run over 14 days using the United States (U.S.)

Over the last two decades, global emission regulations have become more stringent and have required the use of more advanced fuel injection systems. This includes the use of tighter tolerances, more rapid injections and internal components actuated by weaker injection forces. Unfortunately, these design features make the entire system more susceptible to fuel contaminants. Over the last six years, the composition of these contaminants has evolved from hard insoluble debris, such as dust and rocks, to soluble chemical contaminants. Recent research by the diesel engine manufacturers, fuel injection equipment suppliers and the fuel and fuel additive industry has discovered a major source of the soluble chemical contaminant that leads to injector deposits to be derived from cost effective and commonly used additives used to protect against pipeline corrosion.

Within the context of environmental impact reduction for small size spark ignition (SI) engines, especially green-house gas emissions, this study looked at laminar flame speed as an optimization parameter for hydrogen-methane fueled micro-generators. To this aim, SI engine operation was modeled in a 0D/1D simulation framework, so as to identify the best choice of methane-hydrogen ratios in different conditions. Starting from experimental data recorded on a small size engine, an optimization method was implemented for achieving the proposed goal. One of the main conclusions is that high concentrations of hydrogen and resulting fast burn rates are beneficial at high engine speed settings, while the opposite is true at low engine speed. Hydrogen addition was also considered as an additional control margin during lean operation, given that stable combustion can be achieved even with very low equivalence ratios.

The paper covers the design and development of Heavy-Duty (HD) Diesel engines that meet the 2007 HD US EPA emission standards. These standards are the most stringent standards in the world for on-highway HD diesel engines, and have driven the application of new technologies, which includes: particulate aftertreatment, crankcase ventilation systems, and second generation cooled EGR. The paper emphasizes the importance of designing the product to meet the tough expectations of the trucking industry - for lowest total cost of ownership, lowest operating costs, high uptime, ease of maintenance, high performance and durability. A key objective was that these new low emission engines should meet or exceed the performance, reliability and fuel economy standards set by the products they replace. Additionally, these engines were designed to be fully compatible and emissions compliant with bio-diesel B20 blends that meet the ASTM and EMA fuel standards.

The capability to detect combustion in a diesel engine has the potential of being an important control feature to meet increasingly stringent emission regulations and for the development of alternative combustion strategies such as HCCI and PCCI. In this work, block mounted accelerometers are investigated as potential feedback sensors for detecting combustion characteristics in a high-speed, high pressure common rail (HPCR), 1.9L diesel engine. Accelerometers are positioned in multiple placements and orientations on the engine, and engine testing is conducted under motored, single and pilot-main injection conditions. Engine tests are then conducted at varying injection timings to observe the resulting time and frequency domain changes of both the pressure and acceleration signals.

Optimal fuel injection strategies are obtained with a micro-genetic algorithm and an adaptive gradient method for a nonroad, medium-speed DI diesel engine equipped with a multi-orifice, asynchronous fuel injection system. The gradient optimization utilizes a fast-converging backtracking algorithm and an adaptive cost function which is based on the penalty method, where the penalty coefficient is increased after every line search. The micro-genetic algorithm uses parameter combinations of the best two individuals in each generation until a local convergence is achieved, and then generates a random population to continue the global search. The optimizations have been performed for a two pulse fuel injection strategy where the optimization parameters are the injection timings and the nozzle orifice diameters.