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Two oxygenated fuels were evaluated on a single-cylinder diesel engine and compared to three hydrocarbon diesel fuels. The oxygenated fuels included canola biodiesel (canola methyl esters, CME) and CME blended with dibutyl succinate (DBS), both of which are or have the potential to be bio-derived. DBS was added to improve the cold flow properties, but also reduced the cetane number and net heating value of the resulting blend. A 60-40 blend of the two (60% vol CME and 40% vol DBS) provided desirable cold flow benefits while staying above the U.S. minimum cetane number requirement. Contrary to prior vehicle test results and numerous literature reports, single-cylinder engine testing of both CME and the 60-40 blend showed no statistically discernable change in NOx emissions relative to diesel fuel, but only when constant intake oxygen was maintained.

High concentrations of diesel fuel can accumulate in the engine oil, especially in vehicles equipped with diesel particle filters. Fuel dilution can decrease the viscosity of engine oil, reducing its film thickness. Higher concentrations of fuel are believed to accumulate in oil with biodiesel than with diesel fuel because biodiesel has a higher boiling temperature range, allowing it to persist in the sump. Numerous countries are taking actions to promote the use of biodiesel. The growing interest for biodiesel has been driven by a desire for energy independence (domestically produced), the increasing cost of petroleum-derived fuels, and an interest in reducing greenhouse gas emissions. Biodiesel can affect engine lubrication (through fuel dilution), as its physical and chemical properties are significantly different from those of petrodiesel. Many risks associated with excessive biodiesel dilution have been identified, yet its actual impact has not been well quantified.

An experimental study of the effects of partially-oxidized biodiesel fuel on the degradation of fresh fuel was performed. A blend of soybean oil fatty acid methyl esters (FAMEs) in petroleum diesel fuel (30% v:v biodiesel, B30) was aged under accelerated conditions (90°C with aeration). Aging conditions focused on three different degrees of initial oxidation: 1) reduced oxidation stability (Rancimat induction period, IP); 2) high peroxide values (PV); and 3) high total acid number (TAN). Aged B30 fuel was mixed with fresh B30 fuel at two concentrations (10% and 30% m:m) and degradation of the mixtures at the above aging conditions was monitored for IP, PV, TAN, and FAME composition. Greater content of aged fuel carryover (30% m:m) corresponded to stronger effects. Oxidation stability was most adversely affected by high peroxide concentration (Scenario 2), while peroxide content was most reduced for the high TAN scenario (Scenario 3).