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A zero-dimensional cycle simulation model coupled with a chemical equilibrium model and a two-zone combustion model has been extended to predict nitric oxide formation and emissions from spark-ignited, lean-burn natural gas engines. It is demonstrated that using the extended Zeldovich mechanism alone, the NOx emissions from an 8.1-liter, 6-cylinder, natural gas engine were significantly under predicted. However, by combining the predicted NOx formation from both the extended Zeldovich thermal NO and the Fenimore prompt NO mechanisms, the NOx emissions were predicted with fair accuracy over a range of engine powers and lean-burn equivalence ratios. The effect of injection timing on NOx emissions was under predicted. Humidity effects on NOx formation were slightly under predicted in another engine, a 6.8-liter, 6-cylinder, natural gas engine. Engine power was well predicted in both engines, which is a prerequisite to accurate NOx predictions.

Development of a natural gas-fueled engine capable of throttleless operation is discussed in this paper. This development was conducted under a program funded by the National Renewable Energy Laboratory to investigate methods to increase the efficiency of natural gas engines. In-cylinder fuel-air charge stratification was pursued as the mechanism for throttleless operation. Various methods of charge stratification were investigated, including direct injection, stratified charge (DISC) and a fuel injected prechamber (FIPC). The FIPC combustion system was found to be a more practical solution to the problem of charge stratification. Performance and emissions results from this engine configuration are presented and comparisons are made between current natural gas engines and the prototype FIPC engine.

Development of a heavy-duty natural gas engine to improve its lean operating characteristics is detailed in this paper. Testing to determine the lean misfire limit is described, as well as investigations into the cause of lean misfire in this engine. Details of engine modifications to improve the lean misfire limit are also included. The development process resulted in a significant improvement in the lean performance of the engine (i.e., an extended lean misfire limit, better combustion stability, and lower hydrocarbon emissions).

The effect of humidity on the lean misfire limit and emissions from a lean burn, natural gas engine is described in this paper, along with a description of a practical humidity compensation method for incorporation into an electronic control system. Experiments to determine the effects of humidity on the lean limit and emissions are described. Humidity increases were shown to decrease the rate of combustion, reduce NOx emissions, and increase the levels of unburned hydrocarbon (HC) and carbon monoxide (CO) emissions. Data and calculations are also presented which demonstrate that increases in humidity will cause enleanment in a typical closed loop control system utilizing a universal exhaust gas oxygen (UEGO) sensor. A prototype system for humidity sensing and subsequent compensation based on these findings was implemented, and the system was found, through additional testing, to compensate for humidity very effectively.