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Video

SCR Deactivation Kinetics for Model-Based Control and Accelerated Aging Applications

2012-06-18
This paper forms the third of a series and presents results obtained during the testing and development phase of a dedicated range extender engine designed for use in a compact class vehicle. The first paper in this series used real world drive logs to identify usage patterns of such vehicles and a driveline model was used to determine the power output requirements of a range extender engine for this application. The second paper presented the results of a design study. Key attributes for the engine were identified, these being minimum package volume, low weight, low cost, and good NVH. A description of the selection process for identifying the appropriate engine technology to satisfy these attributes was given and the resulting design highlights were described. The paper concluded with a presentation of the resulting specification and design highlights of the engine. This paper will present the resulting engine performance characteristics.
Video

Brief Investigation of SCR High Temperature N2O Production

2012-06-18
Nitrous Oxide (N2O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 [1,2] (298-310 times more potent than carbon dioxide (CO2)). As a result, any aftertreatment system that generates N2O must be well understood to be used effectively. Under low temperature conditions, N2O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N2O formed by the thermal decomposition of ammonium nitrate [3]. Ammonium nitrate and N2O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO2)[4]. This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO2 ratio above 1. However, N2O has also been observed at relatively high temperatures, in the region of 500°C.
Video

SCR Deactivation Study for OBD Applications

2012-06-18
Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications [1,2,3,4]. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH3) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH3 transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.
Technical Paper

Combination of Mixed Metal Oxides with Cu-Zeolite for Enhanced Soot Oxidation on an SCRoF

2021-09-05
2021-24-0071
A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.
Technical Paper

A Controls Overview on Achieving Ultra-Low NOx

2020-04-14
2020-01-1404
The California Air Resources Board (CARB)-funded Stage 3 Heavy-Duty Low NOX program focusses on evaluating different engine and after-treatment technologies to achieve 0.02g/bhp-hr of NOX emission over certification cycles. This paper highlights the controls architecture of the engine and after-treatment systems and discusses the effects of various strategies implemented and tested in an engine test cell over various heavy-duty drive cycles. A Cylinder De-Activation (CDA) system enabled engine was integrated with an advanced after-treatment controller and system package. Southwest Research Institute (SwRI) had implemented a model-based controller for the Selective Catalytic Reduction (SCR) system in the CARB Stage 1 Low-NOX program. The chemical kinetics for the model-based controller were further tuned and implemented in order to accurately represent the reactions for the catalysts used in this program.
Technical Paper

Evaluation of Cylinder Deactivation on a Class 8 Truck over Light Load Cycles

2020-04-14
2020-01-0800
Selective Catalytic Reduction (SCR) systems provide excellent NOX control for diesel engines provided the exhaust aftertreatment inlet temperature remains at 200° C or higher. Since diesel engines run lean, extended light load operation typically causes exhaust temperatures to fall below 200° C and SCR conversion efficiency diminishes. Heated urea dosing systems are being developed to allow dosing below 190° C. However, catalyst face plugging remains a concern. Close coupled SCR systems and lower temperature formulation of SCR systems are also being developed, which add additional expense. Current strategies of post fuel injection and retarded injection timing increases fuel consumption. One viable keep-warm strategy examined in this paper is cylinder deactivation (CDA) which can increase exhaust temperature and reduce fuel consumption.
Journal Article

Model-Based Estimation and Control System Development in a Urea-SCR Aftertreatment System

2008-04-14
2008-01-1324
In this paper, a model-based linear estimator and a non-linear control law for an Fe-zeolite urea-selective catalytic reduction (SCR) catalyst for heavy duty diesel engine applications is presented. The novel aspect of this work is that the relevant species, NO, NO2 and NH3 are estimated and controlled independently. The ability to target NH3 slip is important not only to minimize urea consumption, but also to reduce this unregulated emission. Being able to discriminate between NO and NO2 is important for two reasons. First, recent Fe-zeolite catalyst studies suggest that NOx reduction is highly favored by the NO 2 based reactions. Second, NO2 is more toxic than NO to both the environment and human health. The estimator and control law are based on a 4-state model of the urea-SCR plant. A linearized version of the model is used for state estimation while the full nonlinear model is used for control design.
Journal Article

Smooth In-Cylinder Lean-Rich Combustion Switching Control for Diesel Engine Exhaust-Treatment System Regenerations

2008-04-14
2008-01-0979
This paper describes an in-cylinder lean-rich combustion (no-post-injection for rich) switching control approach for modern diesel engines equipped with exhaust-treatment systems. No-post-injection rich combustion is desirable for regeneration of engine exhaust-treatment systems thanks to its less fuel penalty compared with regeneration approaches using post-injections and / or in-exhaust injections. However, for vehicle applications, it is desirable to have driver-transparent exhaust-treatment system regenerations, which challenge the in-cylinder rich-lean combustion transitions. In this paper, a nonlinear in-cylinder condition control system combined with in-cylinder condition guided fueling control functions were developed to achieve smooth in-cylinder lean-rich switching control at both steady-state and transient operation. The performance of the control system is evaluated on a modern light-duty diesel engine (G9T600).
Journal Article

Boosting Simulation of High Efficiency Alternative Combustion Mode Engines

2011-04-12
2011-01-0358
Four high-efficiency alternative combustion modes were modeled to determine the potential brake thermal efficiency (BTE) relative to a traditional lean burn compression ignition diesel engine with selective catalytic reduction (SCR) aftertreatment. The four combustion modes include stoichiometric pilot-ignited gasoline with EGR dilution (SwRI HEDGE technology), dual fuel premixed compression ignition (University of Wisconsin), gasoline partially premixed combustion (Lund University), and homogenous charge compression ignition (HCCI) (SwRI Clean Diesel IV). For each of the alternative combustion modes, zero-D simulation of the peak torque condition was used to show the expected BTE. For all alternative combustion modes, simulation showed that the BTE was very dependent on dilution levels, whether air or EGR. While the gross indicated thermal efficiency (ITE) could be shown to improve as the dilution was increased, the required pumping work decreased the BTE at EGR rates above 40%.
Journal Article

Brief Investigation of SCR High Temperature N2O Production

2012-04-16
2012-01-1082
Nitrous Oxide (N₂O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 (298-310 times more potent than carbon dioxide (CO₂)). As a result, any aftertreatment system that generates N₂O must be well understood to be used effectively. Under low temperature conditions, N₂O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N₂O formed by the thermal decomposition of ammonium nitrate. Ammonium nitrate and N₂O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO₂). This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO₂ ratio above 1. However, N₂O has also been observed at relatively high temperatures, in the region of 500°C.
Technical Paper

Preparation and Testing of an Electric Competition Vehicle

1991-08-01
911684
A Dodge Omni electric car was prepared for competition in an electric “stock car” 2-hour endurance event: the inaugural Solar and Electric 500 Race, April 7, 1991. This entry utilized a series-wound, direct-current 21-hp electric motor controlled by an SCR frequency and pulse width modulator. Two types of lead-acid batteries were evaluated and the final configuration was a set of 16 (6-volt each) deep-cycle units. Preparation involved weight and friction reduction; suspension modification; load, charge and temperature instrumentaltion; and electrical interlock and collision safety systems. Vehicle testing totalled 15 hours of operation. Ranges observed in testing with the final configuration were from 30 to 52 miles for loads of 175 to 90 amperes. These were nearly constant, continuous discharge cycles. The track qualifying speed (64mph) was near the 68 mph record set by the DEMI Honda at the event on the one-mile track.
Technical Paper

A Connected Controls and Optimization System for Vehicle Dynamics and Powertrain Operation on a Light-Duty Plug-In Multi-Mode Hybrid Electric Vehicle

2020-04-14
2020-01-0591
This paper presents an overview of the connected controls and optimization system for vehicle dynamics and powertrain operation on a light-duty plug-in multi-mode hybrid electric vehicle developed as part of the DOE ARPA-E NEXTCAR program by Michigan Technological University in partnership with General Motors Co. The objective is to enable a 20% reduction in overall energy consumption and a 6% increase in electric vehicle range of a plug-in hybrid electric vehicle through the utilization of connected and automated vehicle technologies. Technologies developed to achieve this goal were developed in two categories, the vehicle control level and the powertrain control level. Tools at the vehicle control level include Eco Routing, Speed Harmonization, Eco Approach and Departure and in-situ vehicle parameter characterization.
Technical Paper

Investigation of Alternative Combustion, Airflow-Dominant Control and Aftertreatment System for Clean Diesel Vehicles

2007-07-23
2007-01-1937
A new diesel engine system adopting alternative combustion with rich and near rich combustion, and an airflow-dominant control system for precise combustion control was used with a 4-way catalyst system with LNT (lean NOx trap) to achieve Tier II Bin 5 on a 2.2L TDI diesel engine. The study included catalyst temperature control, NOx regeneration, desulfation, and PM oxidation with and without post injection. Using a mass-produced lean burn gasoline LNT with 60,000 mile equivalent aging, compliance to Tier II Bin 5 emissions was confirmed for the US06 and FTP75 test cycles with low NVH, minor fuel penalty and smooth transient operation.
Technical Paper

AN AIRFLOW-DOMINANT CONTROL SYSTEM FOR FUTURE DIESEL ENGINES

2007-07-23
2007-01-2070
An airflow-dominant control system was developed to provide precise engine and exhaust treatment control with low air fuel ratio alternative combustion. The main elements of the control logic include a real-time state observer for in-cylinder oxygen mass estimation, a simplified packaging scheme for all air-handling and fueling parameters, a finite state machine for control mode switching, combustion control models to maintain robust alternative combustion during transients, and smooth rich/lean switching during lean NOx trap (LNT) regeneration without post injection. The control logic was evaluated on a passenger car equipped with a 4-way catalyst system with LNT and was instrumental in achieving US Tier II Bin 5 emission targets with good drivability and low NVH.
Technical Paper

Hybrid Robust Control for Engines Running Low Temperature Combustion and Conventional Diesel Combustion Modes

2007-04-16
2007-01-0770
This paper describes a hybrid robust nonlinear control approach for modern diesel engines running low temperature combustion and conventional diesel combustion modes. Using alternative combustion modes has become a promising approach to reduce engine emissions. However, due to very different in-cylinder conditions and fueling parameters for different combustion modes, control of engines operating multiple combustion modes is very challenging. It becomes difficult for conventional calibration / mapping based approaches to produce satisfactory results in terms of engine torque responses and emissions. Advanced control techniques are then demanded to accomplish the tasks. An innovative hybrid control system is designed to track different key engine operating variables at different combustion modes as well as avoid singularity which is inherent for turbocharged diesel engines running multiple combustion modes.
Technical Paper

Adequacy of Reduced Order Models for Model-Based Control in a Urea-SCR Aftertreatment System

2008-04-14
2008-01-0617
Model-based control strategies are important for meeting the dual objective of maximizing NOx reduction and minimizing NH3 slip in urea-SCR catalysts. To be implementable on the vehicle, the models should capture the essential behavior of the system, while not being computationally intensive. This paper discusses the adequacy of two different reduced order SCR catalyst models and compares their performance with a higher order model. The higher order model assumes that the catalyst has both diffusion and reaction kinetics, whereas the reduced order models contain only reaction kinetics. After describing each model, its parameter identification and model validation based on experiments on a Navistar I6 7.6L engine are presented. The adequacy of reduced order models is demonstrated by comparing the NO, NO2 and NH3 concentrations predicted by the models to their concentrations from the test data.
Technical Paper

Development of a Novel Device to Improve Urea Evaporation, Mixing and Distribution to Enhance SCR Performance

2010-04-12
2010-01-1185
A novel urea evaporation and mixing device has been developed to improve the overall performance of a urea-SCR system. The device was tested with a MY2007 Cummins ISB 6.7L diesel engine equipped with an SCR aftertreatment system. Test results show that the device effectively improved the overall NO conversion efficiency of the SCR catalyst over both steady-state and transient engine operating conditions, while NH₃ slip from the catalyst decreased.
Technical Paper

Diesel Catalyst Aging using a FOCAS® HGTR, a Diesel Burner System, to Simulate Engine-Based Aging

2010-04-12
2010-01-1218
The classical approach to prepare engine exhaust emissions control systems for evaluation and certification is to condition the fresh parts by aging the systems on an engine/dynamometer aging stand. For diesel systems this can be a very lengthy process since the estimated service life of the emissions control systems can be several hundred thousand miles. Thus full useful life aging can take thousands of engine bench aging hours, even at elevated temperatures, making aging a considerable cost and time investment. Compared to gasoline engines, diesel engines operate with very low exhaust gas temperatures. One of the major sources of catalyst deactivation is exposure to high temperature [ 1 ].
Technical Paper

Control System Development for Retrofit Automated Manual Transmissions

2009-12-13
2009-28-0001
For transmission suppliers tooled primarily for producing manual transmissions, retrofitting a manual transmission with actuators and a controller is business viable. It offers a low cost convenience for the consumer without losing fuel economy when compared to torque converter type automatics. For heavy duty truck fleets even the estimated 3% gain in fuel economy that the Automated Manual Transmission (AMT) offers over the manual transmission can result in lower operational costs. This paper provides a case study using a light duty transmission retrofitted with electric actuation for gears and the clutch. A high level description of the control algorithms and hardware is included. Clutch control is the most significant component of the AMT controller and it is addressed in detail during operations such as vehicle launch from rest, launch from coast and launch on grades.
Technical Paper

A Review of Diesel Particulate Filter Technologies

2003-06-23
2003-01-2303
Diesel particulate filters (DPF), known as traps in the mid-to late 1970s, were being developed for on-highway diesel applications. However, advanced engine design and in-cylinder engineering enabled diesel engines and vehicles to meet extremely low emission limits, including those of particulate matter (PM) without the need for DPF's or other auxiliary emission control devices. Late in 2000, the US EPA finalized its on-highway heavy-duty diesel emission standards, thus ending speculations regarding its stringency and establishing the lowest limits ever. The new nitric oxides (NOX) and PM limits are seen as technology-forcing. For NOX emissions, the debate rages on among the technical community about the merits of NOX adsorbers and urea selective catalytic reduction. On the other hand, there seems to be little doubt about DPF's as the technical solution for PM.
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