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Video

SCR Deactivation Kinetics for Model-Based Control and Accelerated Aging Applications

2012-06-18
This paper forms the third of a series and presents results obtained during the testing and development phase of a dedicated range extender engine designed for use in a compact class vehicle. The first paper in this series used real world drive logs to identify usage patterns of such vehicles and a driveline model was used to determine the power output requirements of a range extender engine for this application. The second paper presented the results of a design study. Key attributes for the engine were identified, these being minimum package volume, low weight, low cost, and good NVH. A description of the selection process for identifying the appropriate engine technology to satisfy these attributes was given and the resulting design highlights were described. The paper concluded with a presentation of the resulting specification and design highlights of the engine. This paper will present the resulting engine performance characteristics.
Video

Catalyzed Particulate Filter Passive Oxidation Study with ULSD and Biodiesel Blended Fuel

2012-06-18
The development of PM and NOx reduction system with the combination of DOC included DPF and SCR catalyst in addition to the AOC sub-assembly for NH3 slip protection is described. DPF regeneration strategy and manual regeneration functionality are introduced with using ITH, HCI device on the EUI based EGR, VGT 12.3L diesel engine at the CVS full dilution tunnel test bench. With this system, PM and NOx emission regulation for JPNL was satisfied and DPF regeneration process under steady state condition and transient condition (JE05 mode) were successfully fulfilled. Manual regeneration process was also confirmed and HCI control strategy was validated against the heat loss during transient regeneration mode. Presenter Seung-il Moon
Video

Brief Investigation of SCR High Temperature N2O Production

2012-06-18
Nitrous Oxide (N2O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 [1,2] (298-310 times more potent than carbon dioxide (CO2)). As a result, any aftertreatment system that generates N2O must be well understood to be used effectively. Under low temperature conditions, N2O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N2O formed by the thermal decomposition of ammonium nitrate [3]. Ammonium nitrate and N2O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO2)[4]. This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO2 ratio above 1. However, N2O has also been observed at relatively high temperatures, in the region of 500°C.
Video

SCR Deactivation Study for OBD Applications

2012-06-18
Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications [1,2,3,4]. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH3) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH3 transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.
Journal Article

Realization of Ground Effects on Snowmobile Pass-by Noise Testing

2009-05-19
2009-01-2229
Noise concerns regarding snowmobiles have increased in the recent past. Current standards, such as SAE J192 are used as guidelines for government agencies and manufacturers to regulate noise emissions for all manufactured snowmobiles. Unfortunately, the test standards available today produce results with variability that is much higher than desired. The most significant contributor to the variation in noise measurements is the test surface. The test surfaces can either be snow or grass and affects the measurement in two very distinct ways: sound propagation from the source to the receiver and the operational behavior of the snowmobile. Data is presented for a known sound pressure speaker source and different snowmobiles on various test days and test surfaces. Relationships are shown between the behavior of the sound propagation and track interaction to the ground with the pass-by noise measurements.
Journal Article

Emissions of PCDD/Fs, PCBs, and PAHs from a Modern Diesel Engine Equipped with Selective Catalytic Reduction Filters

2013-04-08
2013-01-1778
Exhaust emissions of seventeen 2,3,7,8-substituted chlorinated dibenzo-p-dioxin/furan (CDD/F) congeners, tetra-octa CDD/F homologues, twelve WHO 2005 chlorinated biphenyls (CB) congeners, mono-nona CB homologues, and nineteen polycyclic aromatic hydrocarbons (PAHs) from a model year 2008 Cummins ISB engine equipped with aftertreatment including a diesel oxidation catalyst (DOC) and wall flow copper or iron urea selective catalytic reduction filter (SCRF) were investigated. These systems differ from a traditional flow through urea selective catalytic reduction (SCR) catalyst because they place copper or iron catalyst sites in close proximity to filter-trapped particulate matter. These conditions could favor de novo synthesis of dioxins and furans. The results were compared to previously published results of modern diesel engines equipped with a DOC, catalyzed diesel particulate filter (CDPF) and flow through urea SCR catalyst.
Journal Article

Emissions Performance and In-Use Durability of Retrofit After-Treatment Technologies

2014-09-30
2014-01-2347
In-use testing of diesel emission control technologies is an integral component of EPA's verification program. Device manufacturers are required to complete in-use testing once 500 units have been sold. Additionally, EPA conducts test programs on randomly selected retrofit devices from installations completed with grants by the National Clean Diesel Campaign. In this test program, EPA identified and recovered a variety of retrofit devices, including diesel particulate filters (DPFs) and diesel oxidation catalysts (DOCs), installed on heavy-duty diesel vehicles (on-highway and nonroad). All of the devices were tested at Southwest Research Institute in San Antonio, Texas. This study's goal was to evaluate the durability, defined here as emissions performance as a function of time, of retrofit technologies aged in real-world applications. A variety of operating and emissions criteria were measured to characterize the overall performance of the retrofit devices on an engine dynamometer.
Journal Article

In-Situ Emissions Performance of EPA2010-Compliant On-Highway Heavy-Duty Diesel Engines

2013-09-24
2013-01-2430
Implementation of EPA's heavy-duty engine NOx standard of 0.20 g/bhp-hr has resulted in the introduction of a new generation of emission control systems for on-highway heavy-duty diesel engines. These new control systems are predominantly based around aftertreatment systems utilizing urea-based selective catalytic reduction (SCR) techniques, with only one manufacturer relying solely on in-cylinder NOx emission reduction techniques. As with any new technology, EPA is interested in evaluating whether these systems are delivering the expected emissions reductions under real-world conditions and where areas for improvement may lie. To accomplish these goals, an in-situ gaseous emissions measurement study was conducted using portable emissions measurement devices. The first stage of this study, and subject of this paper, focused on engines typically used in line-haul trucking applications (12-15L displacement).
Technical Paper

Combination of Mixed Metal Oxides with Cu-Zeolite for Enhanced Soot Oxidation on an SCRoF

2021-09-05
2021-24-0071
A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.
Technical Paper

Evaluating the Performance of a Conventional and Hybrid Bus Operating on Diesel and B20 Fuel for Emissions and Fuel Economy

2020-04-14
2020-01-1351
With ongoing concerns about the elevated levels of ambient air pollution in urban areas and the contribution from heavy-duty diesel vehicles, hybrid electric vehicles are considered as a potential solution as they are perceived to be more fuel efficient and less polluting than their conventional engine counterparts. However, recent studies have shown that real-world emissions may be substantially higher than those measured in the laboratory, mainly due to operating conditions that are not fully accounted for in dynamometer test cycles. At the U.S. EPA National Fuel and Vehicle Emissions Laboratory (NVFEL) the in-use criteria emissions and energy efficiency of heavy-duty class 8 vehicles (up to 36280 kg) can be evaluated under controlled conditions in the heavy-duty chassis dynamometer test.
Technical Paper

A Controls Overview on Achieving Ultra-Low NOx

2020-04-14
2020-01-1404
The California Air Resources Board (CARB)-funded Stage 3 Heavy-Duty Low NOX program focusses on evaluating different engine and after-treatment technologies to achieve 0.02g/bhp-hr of NOX emission over certification cycles. This paper highlights the controls architecture of the engine and after-treatment systems and discusses the effects of various strategies implemented and tested in an engine test cell over various heavy-duty drive cycles. A Cylinder De-Activation (CDA) system enabled engine was integrated with an advanced after-treatment controller and system package. Southwest Research Institute (SwRI) had implemented a model-based controller for the Selective Catalytic Reduction (SCR) system in the CARB Stage 1 Low-NOX program. The chemical kinetics for the model-based controller were further tuned and implemented in order to accurately represent the reactions for the catalysts used in this program.
Journal Article

Solid Particle Emissions from Vehicle Exhaust during Engine Start-Up

2015-04-14
2015-01-1077
Human exposure to vehicle exhaust during engine start-up can be encountered on a daily basis in parking lots, home garages, and vehicle stop/star traffic environment. This work is the first pilot study to characterize solid particle number and size distribution during engine start-up using various light-duty vehicles with different technology engines. A total of 84 vehicles were tested in this pilot study, consisting of post-2007 diesel engines equipped with high efficiency diesel particulate filters (DPFs) as well as modern gasoline port fuel injected (PFI) and gasoline direct injected (GDI) engines equipped with three-way-catalysts (TWCs). Particle concentration from DPF equipped diesel engines were found to be the lowest, while GDI and 8-cylinder PFI engines had the highest particle emissions.
Journal Article

Extension of Analytical Methods for Detailed Characterization of Advanced Combustion Engine Emissions

2016-10-17
2016-01-2330
Advanced combustion strategies used to improve efficiency, emissions, and performance in internal combustion engines (IC) alter the chemical composition of engine-out emissions. The characterization of exhaust chemistry from advanced IC engines requires an analytical system capable of measuring a wide range of compounds. For many years, the widely accepted Coordinating Research Council (CRC) Auto/Oil procedure[1,2] has been used to quantify hydrocarbon compounds between C1 and C12 from dilute engine exhaust in Tedlar polyvinyl fluoride (PVF) bags. Hydrocarbons greater than C12+ present the greatest challenge for identification in diesel exhaust. Above C12, PVF bags risk losing the higher molecular weight compounds due to adsorption to the walls of the bag or by condensation of the heavier compounds. This paper describes two specialized exhaust gas sampling and analytical systems capable of analyzing the mid-range (C10 - C24) and the high range (C24+) hydrocarbon in exhaust.
Technical Paper

Evaluation of an On-Board, Real-Time Electronic Particulate Matter Sensor Using Heavy-Duty On-Highway Diesel Engine Platform

2020-04-14
2020-01-0385
California Air Resources Board (CARB) has instituted requirements for on-board diagnostics (OBD) that makes a spark-plug sized exhaust particulate matter (PM) sensor a critical component of the OBD system to detect diesel particulate filter (DPF) failure. Currently, non-real-time resistive-type sensors are used by engine OEMs onboard vehicles. Future OBD regulations are likely to lower PM OBD thresholds requiring higher sensitivity sensors with better data yield for OBD decision making. The focus of this work was on the experimental evaluation of a real-time PM sensor manufactured by EmiSense Technologies, LLC that may offer such benefits. A 2011 model year on-highway heavy-duty diesel engine fitted with a diesel oxidation catalyst (DOC) and a catalyzed DPF followed by urea-based selective catalytic reducer (SCR) and ammonia oxidation (AMOX) catalysts was used for this program.
Technical Paper

Development of a Burner-Based Test System to Produce Controllable Particulate Emissions for Evaluation of Gasoline Particulate Filters

2020-04-14
2020-01-0389
Gasoline Direct Injection (GDI) engines have been widely adopted by manufacturers in the light-duty market due to their fuel economy benefits. However, several studies have shown that GDI engines generate higher levels of particulate matter (PM) emissions relative to port fuel injected (PFI) engines and diesel engines equipped with optimally functioning diesel particulate filters (DPF). With stringent particle number (PN) regulations being implemented in both, the European Union and China, gasoline particulate filters (GPF) are expected to be widely utilized to control particulate emissions. Currently, evaluating GPF technologies on a vehicle can be challenging due to a limited number of commercially available vehicles that are calibrated for a GPF in the United States as well as the costs associated with vehicle procurement and evaluations utilizing a chassis dynamometer facility.
Technical Paper

Evaluation of Cylinder Deactivation on a Class 8 Truck over Light Load Cycles

2020-04-14
2020-01-0800
Selective Catalytic Reduction (SCR) systems provide excellent NOX control for diesel engines provided the exhaust aftertreatment inlet temperature remains at 200° C or higher. Since diesel engines run lean, extended light load operation typically causes exhaust temperatures to fall below 200° C and SCR conversion efficiency diminishes. Heated urea dosing systems are being developed to allow dosing below 190° C. However, catalyst face plugging remains a concern. Close coupled SCR systems and lower temperature formulation of SCR systems are also being developed, which add additional expense. Current strategies of post fuel injection and retarded injection timing increases fuel consumption. One viable keep-warm strategy examined in this paper is cylinder deactivation (CDA) which can increase exhaust temperature and reduce fuel consumption.
Journal Article

Model-Based Estimation and Control System Development in a Urea-SCR Aftertreatment System

2008-04-14
2008-01-1324
In this paper, a model-based linear estimator and a non-linear control law for an Fe-zeolite urea-selective catalytic reduction (SCR) catalyst for heavy duty diesel engine applications is presented. The novel aspect of this work is that the relevant species, NO, NO2 and NH3 are estimated and controlled independently. The ability to target NH3 slip is important not only to minimize urea consumption, but also to reduce this unregulated emission. Being able to discriminate between NO and NO2 is important for two reasons. First, recent Fe-zeolite catalyst studies suggest that NOx reduction is highly favored by the NO 2 based reactions. Second, NO2 is more toxic than NO to both the environment and human health. The estimator and control law are based on a 4-state model of the urea-SCR plant. A linearized version of the model is used for state estimation while the full nonlinear model is used for control design.
Journal Article

Boosting Simulation of High Efficiency Alternative Combustion Mode Engines

2011-04-12
2011-01-0358
Four high-efficiency alternative combustion modes were modeled to determine the potential brake thermal efficiency (BTE) relative to a traditional lean burn compression ignition diesel engine with selective catalytic reduction (SCR) aftertreatment. The four combustion modes include stoichiometric pilot-ignited gasoline with EGR dilution (SwRI HEDGE technology), dual fuel premixed compression ignition (University of Wisconsin), gasoline partially premixed combustion (Lund University), and homogenous charge compression ignition (HCCI) (SwRI Clean Diesel IV). For each of the alternative combustion modes, zero-D simulation of the peak torque condition was used to show the expected BTE. For all alternative combustion modes, simulation showed that the BTE was very dependent on dilution levels, whether air or EGR. While the gross indicated thermal efficiency (ITE) could be shown to improve as the dilution was increased, the required pumping work decreased the BTE at EGR rates above 40%.
Journal Article

Brief Investigation of SCR High Temperature N2O Production

2012-04-16
2012-01-1082
Nitrous Oxide (N₂O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 (298-310 times more potent than carbon dioxide (CO₂)). As a result, any aftertreatment system that generates N₂O must be well understood to be used effectively. Under low temperature conditions, N₂O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N₂O formed by the thermal decomposition of ammonium nitrate. Ammonium nitrate and N₂O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO₂). This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO₂ ratio above 1. However, N₂O has also been observed at relatively high temperatures, in the region of 500°C.
Journal Article

Diesel Cold-Start Emission Control Research for 2015-2025 LEV III Emissions

2013-04-08
2013-01-1301
The diesel engine can be an effective solution to meet future greenhouse gas and fuel economy standards, especially for larger segment vehicles. However, a key challenge facing the diesel is the upcoming LEV III emissions standard which will require significant reductions of hydrocarbon (HC) and oxides of nitrogen (NOx) from current levels. The challenge stems from the fact that diesel exhaust temperatures are much lower than gasoline engines so the time required to achieve effective emissions control with current aftertreatment devices is considerably longer. The objective of this study was to determine the potential of a novel diesel cold-start emissions control strategy for achieving LEV III emissions. The strategy combines several technologies to reduce HC and NOx emissions before the start of the second hill of the FTP75.
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