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The 4th Workshop of the Engine Combustion Network (ECN) was held September 5-6, 2015 in Kyoto, Japan. This manuscript presents a summary of the progress in experiments and modeling among ECN contributors leading to a better understanding of soot formation under the ECN “Spray A” configuration and some parametric variants. Relevant published and unpublished work from prior ECN workshops is reviewed. Experiments measuring soot particle size and morphology, soot volume fraction (fv), and transient soot mass have been conducted at various international institutions providing target data for improvements to computational models. Multiple modeling contributions using both the Reynolds Averaged Navier-Stokes (RANS) Equations approach and the Large-Eddy Simulation (LES) approach have been submitted. Among these, various chemical mechanisms, soot models, and turbulence-chemistry interaction (TCI) methodologies have been considered.

In order to evaluate the ventilation characteristics of car interior, a model experiment was performed. Part 1 deals with the air flow properties in a half-scale car model. In this paper, a trace gas experimental method equipped with Flame Ionization Detector (FID) systems is introduced to examine the local ventilation efficiency and inhaled air quality in the car, which was ventilated at a flow rate of 100 m3/h and kept in an isothermal environment of 28°C in the experiment. Here, ventilation efficiency was evaluated by means of the Scales for Ventilation Efficiencies (SVEs), and inhaled air quality in terms of the influences of passive smoke and foot odor was evaluated by means of the Contribution Ratio of Pollution source 1 (CRP1). Therefore, calculation methods using trace gas concentration values were suggested for these indices, which were proposed based on the Computational Fluid Dynamics (CFD) technique.

The described investigation was carried out under the umbrella of IEA Advanced Motor Fuels Agreement. The purpose was to evaluate the emissions of carbon monoxide (CO), unburned hydrocarbons (HC), nitrogen oxides (NOx), particulate matter (PM) and polycyclic aromatic hydrocarbons (PAH) from vehicles fuelled by Fischer Tropsch (FT) based diesel and gasoline fuel, compared to the emissions from ordinary diesel and gasoline. The comparison for diesel fuels was based on a literature review, whereas the gasoline comparison had to be based on our own experiments, since almost no references were found in this field. In this context measurement according to the Federal Test Procedure (FTP) and the New European Driving Cycle (NEDC) were carried out on a chassis dynamometer with a directly injected gasoline vehicle. Experiments were carried out with a reference fuel, a fuel based 70% on FT and an alkylate fuel (Aspen), which was taken to be the ultimate formula of FT gasoline.

A novel base metal-palladium catalytic coating was applied on commercial silicon carbide wall flow diesel filters and tested in an engine test bench. This catalytic coating limits the NO2 formation and even removes NO2 within a wide temperature range. Soot combustion, HC conversion and CO conversion properties are comparable to current platinum-based coatings, but at a lower cost. This paper compares the results from engine bench tests of present commercial solutions as regards NO2-, HC-, CO-removal and soot combustion with the novel coating. Furthermore, emission test results from base metal-palladium coated diesel particulate filters installed on operating taxis and related test cycle data are presented. A significant reduction in NO2 emission compared to present technology is measured.

In February 2004 NASA released “The Vision for Space Exploration.” The important goals outlined in this document include extending human presence in the solar system culminating in the exploration of Mars. Unprocessed waste poses a biological hazard to crew health and morale. The waste processing methods currently under consideration include incineration, microbial oxidation, pyrolysis and compaction. Although each has advantages, no single method has yet been developed that is safe, recovers valuable resources including oxygen and water, and has low energy and space requirements. Thus, the objective of this project is to develop a low temperature oxidation process to convert waste cleanly and rapidly to carbon dioxide and water. In the Phase I project, TDA Research, Inc. demonstrated the potential of a low temperature oxidation process using ozone. In the current Phase II project, TDA and NASA Ames Research Center are developing a pilot scale low temperature ozone oxidation system.

An innovative design that meets both Shuttle and Space Station requirements for a user-friendly, volume-efficient, portable glovebox system has been developed at Ames Research Center (ARC). The Standard Interface Glovebox (SIGB) has been designed as a two Middeck locker-sized system that mounts in a Middeck Rack Structure (MRS) or in any rack using the Standard Interface Rack (SIR) rail spacing. The MRS provides structural support for the SIGB during all aspects of the mission and is an interface consistent with NASA's desire for commonality of mechanical interfaces, allowing the SIGB to be flown on essentially any manned space platform. The SIGB provides an enclosed work volume which operates at negative pressure relative to ambient, as well as excellent lighting and ample work volume for anticipated life sciences-related experiment operations inflight.

PGBA, a plant growth facility developed for commercial space biotechnology research, successfully grew a total of 50 plants (6 species) during 10 days aboard the Space Shuttle Endeavor (STS-77), and has reflown aboard the Space Shuttle Columbia (STS-83 for 4 days and STS-94 for 16 days) with 55 plants and 10 species. The PGBA life support system provides atmospheric, thermal, and humidity control as well as lighting and nutrient supply in a 33 liter microgravity plant growth chamber. The atmosphere treatment system removes ethylene and other hydrocarbons, actively controls CO2 replenishment, and provides passive O2 control. Temperature and humidity are actively controlled.

A steady-state system mass balance calculation was performed to investigate design issues regarding the storage and/or processing of solid waste. In the initial stages of BIO-Plex, only a certain percentage of the food requirement will be satisfied through crop growth. Since some food will be supplied to the system, an equivalent amount of waste will accumulate somewhere in the system. It is a system design choice as to where the mass should accumulate in the system. Here we consider two approaches. One is to let solid waste accumulate in order to reduce the amount of material processing that is needed. The second is to process all of the solid waste to reduce solid waste storage and then either resupply oxygen or add physical/chemical (P/C) processors to recover oxygen from the excess carbon dioxide and water that is produced by the solid waste processor.

The Plant Generic BioProcessing Apparatus (PGBA), a plant growth facility developed for commercial space biotechnology research, has flown successfully on 3 spaceflight missions for 4, 10 and 16 days. The environmental control systems of this plant growth chamber (28 liter/0.075 m2) provide atmospheric, thermal, and humidity control, as well as lighting and nutrient supply. Typical performance profiles of water transpiration and dehumidification, carbon dioxide absorption (photosynthesis) and respiration rates in the PGBA unit (on orbit and ground) are presented. Data were collected on single and mixed crops. Design options and considerations for the different sub-systems are compared with those of similar hardware.

The low auto-ignition temperature, rapid evaporation and high cetane number of dimethyl ether (DME) enables the use of low-pressure direct injection in compression ignition engines, thus potentially bringing the cost of the injection system down. This in turn holds the promise of bringing CI efficiency to even the smallest engines. A 50cc crankcase scavenged two-stroke CI engine was built based on moped parts. The major alterations were a new cylinder head and a 100 bar DI system using a GDI-type injector. Power is limited by carbon monoxide emission but smoke-free operation and NOx < 200ppm is achieved at all points of operation.

The “low power-CO2 removal (LPCOR) system” is an advanced air revitalization system that is under development at NASA Ames Research Center. The LPCOR utilizes the fundamental design features of the ‘four bed molecular sieve’ (4BMS) CO2 removal technology of the International Space Station (ISS). LPCOR improves power efficiency by replacing the desiccant beds of the 4BMS with a membrane dryer and a state-of-the-art, structured adsorbent device that collectively require 25% of the thermal energy required by the 4BMS desiccant beds for regeneration. Compared to the 4BMS technology, it has the added functionality to deliver pure, compressed CO2 for oxygen recovery. The CO2 removal and recovery functions are performed in a two-stage adsorption compressor. CO2 is removed from the cabin air and partially compressed in the first stage. The second stage performs further compression and delivers the compressed CO2 to a reduction unit such as a Sabatier reactor for oxygen recovery.

Designers of future space vehicles envision simplifying the Atmosphere Revitalization (AR) system by combining the functions of trace contaminant (TC) control and carbon dioxide removal into one swing-bed system. Flow rates and bed sizes of the TC and CO2 systems have historically been very different. There is uncertainty about the ability of trace contaminant sorbents to adsorb adequately in a high-flow or short bed length configurations, and to desorb adequately during short vacuum exposures. This paper describes preliminary results of a comparative experimental investigation into adsorbents for trace contaminant control. Ammonia sorbents and low temperature catalysts for CO oxidation are the foci. The data will be useful to designers of AR systems for Constellation. Plans for extended and repeated vacuum exposure of ammonia sorbents are also presented.

Dynamic simulation of the lunar outpost habitat life support was undertaken to investigate the impact of life support failures and to investigate possible responses. Some preparatory static analysis for the Lunar Outpost life support model, an earlier version of the model, and an investigation into the impact of Extravehicular Activity (EVA) were reported previously. (Jones, 2008-01-2184, 2008-01-2017) The earlier model was modified to include possible resupply delays, power failures, recycling system failures, and atmosphere and other material storage failures. Most failures impact the lunar outpost water balance and can be mitigated by reducing water usage. Food solids and nitrogen can be obtained only by resupply from Earth. The most time urgent failure is a loss of carbon dioxide removal capability. Life support failures might be survivable if effective operational solutions are provided in the system design.

In February 2004 NASA released “The Vision for Space Exploration.” The goals outlined in this document include extending the human presence in the solar system, culminating in the exploration of Mars. A key requirement for this effort is to identify a safe and effective method to process waste. Methods currently under consideration include incineration, microbial oxidation, pyrolysis, drying, and compaction. Although each has advantages, no single method has yet been developed that is safe, recovers valuable resources including oxygen and water, and has low energy and space requirements. Thus, the objective of this work was to develop a low temperature oxidation process to convert waste cleanly and rapidly to carbon dioxide and water. TDA and NASA Ames Research Center have developed a pilot scale low temperature ozone oxidation system to convert organic waste to CO2 and H2O.

Pressure-sensitive paint (PSP) technology is a technique used to experimentally determine surface pressures on models during wind tunnel tests. The key to this technique is a specially formulated pressure-sensitive paint that responds to, and can be correlated with the local air pressure. Wind tunnel models coated with pressure-sensitive paint are able to yield quantitative pressure data on an entire model surface in the form of light intensity values in recorded images. Quantitative results in terms of pressure coefficients (Cp) are obtained by correlating PSP data with conventional pressure tap data. Only a small number of surface taps are needed to be able to obtain quantitative pressure data with the PSP method. This technique is gaining acceptance so that future automotive wind tunnel tests can be done at reduced cost by eliminating most of the expensive pressure taps from wind tunnel models.

The current CO2 removal technology of NASA is very energy intensive and contains many non-optimized subsystems. This paper discusses the concept of a next-generation, membrane-integrated, adsorption processor for CO2 removal and compression in closed-loop air revitalization systems. The membrane module removes water from the feed, passing it directly into the processor's exhaust stream; it replaces the desiccant beds in the current four-bed molecular sieve system, which must be thermally regenerated. Moreover, in the new processor, CO2 is removed and compressed in a single two-stage unit. This processor will use much less power than NASA's current CO2 removal technology and will be capable of maintaining a lower CO2 concentration in the cabin than that can be achieved by the existing CO2 removal systems.

Of the many competing technologies for resource recovery from solid wastes for long duration manned missions such as a lunar or Mars base, incineration technology is one of the most promising and certainly the most well developed in a terrestrial sense. Various factors are involved in the design of an optimum fluidized bed incinerator for inedible biomass. The factors include variability of moisture in the biomass, the ash content, and the amount of fuel nitrogen in the biomass. The crop mixture in the waste will vary; consequently the nature of the waste, the nitrogen content, and the biomass heating values will vary as well. Variation in feed will result in variation in the amount of contaminants such as nitrogen oxides that are produced in the combustion part of the incinerator. The incinerator must be robust enough to handle this variability. Research at NASA Ames Research Center using the fluidized bed incinerator has yielded valuable data on system parameters and variables.

We modeled BIO-Plex designs with separate or combined atmospheres and then simulated controlling the atmosphere composition. The BIO-Plex is the Bioregenerative Planetary Life Support Systems Test Complex, a large regenerative life support test facility under development at NASA Johnson Space Center. Although plants grow better at above-normal carbon dioxide levels, humans can tolerate even higher carbon dioxide levels. Incinerator exhaust has very high levels of carbon dioxide. An elaborate BIO-Plex design would maintain different atmospheres in the crew and plant chambers and isolate the incinerator exhaust in the airlock. This design option easily controls the crew and plant carbon dioxide levels but it uses many gas processors, buffers, and controllers. If all the crew’s food is grown inside BIO-Plex, all the carbon dioxide required by the plants can be supplied by crew respiration and the incineration of plant and food waste.

Samples of Mars surface material will return to Earth in 2014. Prior to curation and distribution to the scientific community the returned samples will be isolated in a special facility until their biological safety has been assessed following protocols established by NASA’s Planetary Protection Office. The primary requirements for the pre-release handling of the Martian samples include protecting the samples from the Earth and protecting the Earth from the sample. A testbed will be established to support the design of such a facility and to test the planetary protection protocols. One design option that is being compared to the conventional Biological Safety Level 4 facility is a double walled differential pressure chamber with airlocks and automated equipment for analyzing samples and transferring them from one instrument to another.

New variable environment Modified Energy Cascade (MEC) crop models were developed for all the Advanced Life Support (ALS) candidate crops and implemented in SIMULINK. The MEC models are based on the Volk, Bugbee, and Wheeler Energy Cascade (EC) model and are derived from more recent Top-Level Energy Cascade (TLEC) models. The MEC models were developed to simulate crop plant responses to day-to-day changes in photosynthetic photon flux, photoperiod, carbon dioxide level, temperature, and relative humidity. The original EC model allowed only changes in light energy and used a less accurate linear approximation. For constant nominal environmental conditions, the simulation outputs of the new MEC models are very similar to those of earlier EC models that use parameters produced by the TLEC models. There are a few differences. The new MEC models allow setting the time for seed emergence, have more realistic exponential canopy growth, and have corrected harvest dates for potato and tomato.