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The impact of cold-start emissions is well known on conventional and hybrid electric vehicles. Plug-in electric vehicles offer a unique challenge in that there are opportunities for prolonged engine-off conditions which can lead to catalyst cooling and elevated emissions on engine re-start. This research investigates the development and validation of a system for controlling emissions under these conditions, with an emphasis on a catalytic converter model used for design and analysis. The model is a one-dimensional, lumped-parameter model of a three-way catalytic converter developed in Matlab/Simulink. The catalyst is divided into discrete, axial elements and each discrete element contains states for the temperatures of the gas, substrate, and can wall. Heat transfer mechanisms are modeled from physics-based equations.