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Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

The selective catalytic reduction has seen widespread adoption as the best technology to reduce the NOx emissions from internal combustion engines, particularly for Diesels. This technology uses ammonia as a reducing agent, which is obtained injecting an ammonia carrier into the exhaust gas stream. The dosing of the ammonia carrier, usually AdBlue, is the major concern during the design and engine calibration phases, since the interaction between the injected liquid and the components of the exhaust system can lead to the undesired formation of solid deposits. To avoid this, the thermal and kinematic interaction between the spray and the components of the after treatment system (ATS) must be modeled accurately. In this work, the authors developed a Conjugate Heat Transfer (CHT) framework to model the kinetic and thermal interaction among the spray, the eventual liquid layer and the pipe walls.

The friction estimation at the tire-ground contact is crucial for the active safety of vehicles. Friction estimation is a key problem of vehicle dynamics and the ultimate solution is still unknown. However the proposed approach, based on a simple idea and on a simple hardware, provides an actual solution. The idea is to compare the tire characteristic at a given friction (nominal characteristic) with the actual characteristic that the tire has while running. The comparison among these two characteristics (the nominal one and the actual one) gives the desired friction coefficient. The friction coefficient is expressed in vector form and a number of running parameters are identified. The mentioned comparison is an efficient but complex algorithm based on a mathematical formulation of the tire characteristic. The actual tire characteristic is somehow measured in real time by a relatively simple smart wheel which is able to detect the three forces and the three moments acting at the hub.

The injection process of urea-water solution (AdBlue) determines initial conditions for reactions and catalysis and is fundamentally responsible for optimal operation of selective catalytic reduction (SCR) systems. The spray characteristics of four, commercially available, injectors (one air-assisted and three pressure-driven with different nozzle-hole configurations) are investigated with non-intrusive measuring techniques. Injection occurred in the crossflow of a channel blowing preheated air in an exhaust duct similar configuration. The effect of several gas temperatures and flows on the spray propagation and entrainment has been extensively studied by shadow imaging. Shadow images, in addition, show that the spray of the pressure-driven injectors is only marginally affected by the gas crossflow. In contrast, the air assisted spray is strongly deflected by the gas, the effect increasing with increasing gas flow.

Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

The paper investigates the interaction between soil and tractor tires through a 2D numerical model. The tire is schematized as a rigid ring presenting a series of rigid tread bars on the external circumference. The outer profile of the tire is divided into a series of elements, each one able to exchange a normal and a tangential contact force with the ground. A 2D soil model was developed to compute the forces at the ground-tire interface: the normal force is determined on the basis of the compression of the soil generated by the sinking of the tire. The soil is modeled through a layer of springs characterized by two different stiffness for the loading (lower stiffness) and unloading (higher stiffness) condition. This scheme allows to introduce a memory effect on the soil which results stiffer and keeps a residual sinking after the passage of the tire. The normal contact force determines the maximum value of tangential force provided before the soil fails.

The application of liquid aqueous Urea Solution (AUS) as reductant in SCR exhaust after-treatment systems is now a commonly accepted industry standard. Unfortunately, less acceptable are the associated difficulties caused by incomplete decomposition of the liquid, resulting in solid deposits which accumulate in the exhaust pipe downstream of the dosing components. The correct prediction of the spray pattern and, therefore, the spray impact on the walls is a key feature for the system optimization. A mechanical patternator, designed on the basis of CFD performance assessment, involving a Lagrangian representation of the dispersed liquid fully coupled with a 3D Eulerian description of the carrier phase, has been built and used to measure the spray mass distribution.

While the Diesel Particulate Filter (DPF) is actually a quasi-standard equipment in the European Diesel passenger cars market, an interesting solution to fulfill NOx emission limits for the next EU 6 legislation is the application of a Selective Catalytic Reduction (SCR) system on the exhaust line, to drastically reduce NOx emissions. In this context, one of the main issues is the performance of the SCR system during cold start and warm up phases of the engine. The exhaust temperature is too low to allow thermal activation of the reactor and, consequently, to promote high conversion efficiency and significant NOx concentration reduction. This is increasingly evident the smaller the engine displacement, because of its lower exhaust system temperature (reduced gross power while producing the same net power, i.e., higher efficiency).

In the last years the number of electronic controllers of vehicle dynamics applied to chassis components has increased dramatically. They use lookup table of the primary order vehicle global parameters as yaw rate, lateral acceleration, steering angle, car velocity, that define the ideal behavior of the vehicle. They are usually based on PID controllers which compare the actual behavior of every measured real vehicle data to the desired behavior, from look up table. The controller attempts to keep the measured quantities the same as the tabled quantities by using ESP, TC (brakes and throttle), CDC (control shocks absorbers), EDIFF(active differential) and 4WS (rear wheels active toe). The performances of these controls are good but not perfect. The improvement can be achieved by replacement of the lookup tables with a fast vehicle model running in parallel to the real vehicle.

This study examines the impact of slip in aero-thermal conditions of supercooled large droplets (SLD) produced in an Icing Wind Tunnel (IWT) on the ice accretion characteristics. The study identifies potential biases in the SLD model development based on IWT data and numerical predictions that assume the SLD to be in aerothermal equilibrium with the IWT airflow. To obtain realistic temperature and velocity data for each droplet size class in the test section of the Braunschweig Icing Wind Tunnel (BIWT), a Lagrangian droplet tracking solver was used within a Monte Carlo framework. Results showed that SLDs experience considerable slips in velocity and temperature due to their higher inertia and short residence time in the Braunschweig IWT. Large droplets were found to be warmer and slower than the flow in the test section, with larger droplets experiencing larger aerothermal slips.

Aqueous Urea is a non-toxic and stable ammonia carrier and its injection and mixing represent the basis for the most common de-NOx technology for mobile applications. The reactant feed preparation process is defined by evaporation, thermolysis and hydrolysis of the liquid mixture upstream the Selective Catalytic Reduction reactor, and it is strongly dependent on the interaction between spray and gaseous flow. Low-pressure driven injectors are the common industrial standard for these applications, and their behavior in almost-ambient pressure cross flows is significantly different from any in-cylinder application. For this reason, two substantially different injectors in terms of geometry and design are experimentally studied, characterizing drop sizes and velocities through Phase Doppler Anemometry (PDA) and liquid mass spatial distribution through Shadow Imaging (SI).

Aim of this study is to analyze the benefits of the measures provided by smart tyres on tyre-road friction coefficient and vehicle sideslip angle estimation. In particular, a smart tyre constituted by 2 tri-axial accelerometers glued on the tyre inner liner is considered which is able to provide the measures of the tyre-road contact forces once per wheel turn. These measures are added to the ones usually present onboard vehicle (steer angle, lateral acceleration and yaw rate) and following included into an Extended Kalman Filter (EKF) based on a single-track vehicle model. Performance of the proposed observer is evaluated on a series of handling maneuvers and its robustness to road bank angle, tyre and vehicle parameters variation is discussed.

For passenger cars, individual tyre model parameters, used in vehicle models able to simulate vehicle handling behavior, are traditionally derived from expensive component indoor laboratory tests as a result of an identification procedure minimizing the error with respect to force and slip measurements. Indoor experiments on agricultural tyres are instead more challenging and thus generally not performed due to tyre size and applied forces. However, the knowledge of their handling characteristics is becoming more and more important since in the next few years, all agricultural vehicles are expected to run on ordinary asphalt roads at a speed of 80km/h. The present paper presents a methodology to identify agricultural tyres' handling characteristics based only on the measurements carried out on board vehicle (vehicle sideslip angle, yaw rate, lateral acceleration, speed and steer angle) during standard handling maneuvers (step-steers, J-turns, etc.), instead than during indoor tests.

The accurate prediction of pollutant emissions generated by IC engines is a key aspect to guarantee the respect of the emission regulation legislation. This paper describes the approach followed by the authors to achieve a strict numerical coupling of two different 1D modeling tools in a co-simulation environment, aiming at a reliable calculation of engine-out and tailpipe emissions. The main idea is to allow an accurate 1D simulation of the unsteady flows and wave motion inside the intake and exhaust systems, without resorting to an over-simplified geometrical discretization, and to rely on advanced thermodynamic combustion models and kinetic sub-models for the calculation of cylinder-out emissions. A specific fluid dynamic approach is then used to track the chemical composition along the exhaust duct-system, in order to evaluate the conversion efficiency of after-treatment devices, such as TWC, GPF, DPF, DOC, SCR and so on.

NH₃/urea SCR is a very effective and widely used technology for the abatement of NOx from diesel exhaust. The SCR mechanism is well understood and the catalyst behavior can be predicted by mathematical models - as long as operation above the temperature limit for AdBlue® injection is considered. The behavior below this level is less understood. During the first seconds up to minutes after cold start, complete NOx abatement can be observed over an SCR catalyst in test bench experiments, together with a significant increase in temperature after the converter (ca. 100 K). In this work these effects have been investigated over a monolith Cu-zeolite SCR catalyst. Concentration step experiments varying NO, NO₂ and H₂O have been carried out in lab scale, starting from room temperature. Further, the interaction of C₃H₆ and CO with NOx over the SCR has been investigated.