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Brake calipers for high-end cars are typically realized using Aluminum alloys, with Silicon as the most common alloying element. Despite the excellent castability and machinability of Aluminum-Silicon alloys (AlSix), anodization is often required in order to increase its corrosion resistance. This is particularly true in Chlorides-rich environments where Aluminum can easily corrode. Even if anodization process is known for almost 100 years, anodization of AlSix -based materials is particularly challenging due to the presence of eutectic Silicon precipitates. These show a poor electric conductivity and a slow oxidation kinetics, leading to inhomogeneous anodic layers. Continuous research and process optimization are required in order to develop anodic layers with enhanced morphological and electrochemical properties, targeting a prolonged resistance of brake calipers under endurance corrosive tests (e.g. >1000 hours Neutral Salt Spray (NSS) tests).

The work investigates the use of cathodic protection -based strategies (e.g. sacrificial anodes) with the aim of extending the corrosion resistance of Aluminum components to be used in disc brake systems. Lab-scale electrochemical measurements, including voltammetry and zero resistance ammetry (ZRA), are used to: a) define the requirements of a cathodic protection system for a 42200 Aluminum alloy; b) evaluate the protection capability of a Zn-based sacrificial anode; and c) demonstrate an extended corrosion resistance of the protected part even in the presence of a galvanic coupling, with respect to the unprotected condition.