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In this work a detailed model to simulate the transient behavior of catalytic converters is presented. The model is able to predict the unsteady and reacting flows in the exhaust ducts, by solving the system of conservation equations of mass, momentum, energy and transport of reacting chemical species. The en-gine and the intake system have not been included in the simulation, imposing the measured values of mass flow, gas temperature and chemical composition as a boundary condition at the inlet of the exhaust system. A detailed analysis of the diffusion stage triggering is proposed along with simplifications of the physics, finalized to the reduction of the calculation time. Submodels for water condensation and its following evaporation on the monolith surface have been taken into account as well as oxygen storage promoted by ceria oxides.

A numerical investigation on a series of Diesel spray experiments in constant-volume vessels is proposed. Non reacting conditions were used to assess the spray models and to determine the grid size required to correctly predict the fuel-air mixture formation process. To this end, not only computed liquid and vapor penetrations were compared with experimental data, but also a detailed comparison between computed and experimental mixture fraction distributions was performed at different distances from the injector. Grid dependency was reduced by introducing an Adaptive Local Mesh Refinement technique (ALMR) with an arbitrary level of refinement. Once the capabilities of the current implemented spray models have been assessed, reacting conditions at different ambient densities and temperatures were considered. A Perfectly Stirred Reactor (PSR) combustion model, based on a direct integration of complex chemistry mechanisms over a homogenous cell, was adopted.

A detailed analysis of knocking events can help improving engine performance and diagnosis strategies. The paper aim is a better understanding of the phenomena involved in knocking combustions through the combination of CFD and signals analysis tools. CFD simulations have been used in order to reproduce knock effect on the in-cylinder pressure trace. In fact, the in-cylinder pressure signal holds information about waves propagation and heat losses: for the sake of the diagnosis it is important to relate knock severity to knock indexes values. For this purpose, a CFD model has been implemented, able to predict the combustion evolution with respect to Spark Advance, from non-knocking up to heavy knocking conditions. The CFD model validation phase is crucial for a correct representation of both regular and knocking combustions: the operation has been carried out by means of an accurate statistical analysis of experimental in-cylinder pressure data.

Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

Although the application of cylinder pressure sensors to gain insight into the combustion process is not a novel topic itself, the recent availability of inexpensive in-cylinder pressure sensors has again prompted an upcoming interest for the utilization of the cylinder pressure signal within engine control and monitoring. Besides the use of the in-cylinder pressure signal for combustion analysis and control the information can also be used to determine related quantities in the exhaust or intake manifold. Within this work two different methods to estimate the pressure inside the exhaust manifold are proposed and compared. In contrary to first principle based approaches, which may require time extensive parameterization, alternative data driven approaches were pursued. In the first method a Principle Component Analysis (PCA) is applied to extract the cylinder pressure information and combined with a polynomial model approach.

The optimization of turbocharging systems for automotive applications has become crucial in order to increase engine performance and meet the requirements for pollutant emissions and fuel consumption reduction. Unfortunately, performing an optimal turbocharging system control is very difficult, mainly due to the fact that the flow through compressor and turbine is highly unsteady, while only steady flow maps are usually provided by the manufacturer. For these reasons, one of the most important quantities to be used onboard for optimal turbocharger system control is the rotational speed fluctuation, since it provides information both on turbocharger operating point and on the energy of the unsteady flow in the intake and exhaust circuits. This work presents a methodology that allows determining the instantaneous turbocharger rotational speed through a proper frequency processing of the signal coming from one accelerometer mounted on the turbocharger compressor.

Detailed chemistry and turbulence-chemistry interaction need to be properly taken into account for a realistic combustion simulation of IC engines where advanced combustion modes, multiple injections and stratified combustion involve a wide range of combustion regimes and require a proper description of several phenomena such as auto-ignition, flame stabilization, diffusive combustion and lean premixed flame propagation. To this end, different approaches are applied and the most used ones rely on the well-stirred reactor or flamelet assumption. However, well-mixed models do not describe correctly flame structure, while unsteady flamelet models cannot easily predict premixed flame propagation and triple flames. A possible alternative for them is represented by transported probability density functions (PDF) methods, which have been applied widely and effectively for modeling turbulent reacting flows under a wide range of combustion regimes.

A new multi-zone model for the simulation of HCCI engine is here presented. The model includes laminar and turbulent diffusion and conduction exchange between the zones and the last improvements on the numerical aspects. Furthermore, a new strategy for the zone discretization is presented, which allows a better description of the near-wall zones. The aim of the work is to provide a fast and reliable model for carrying out chemical analysis with detailed kinetic schemes. A preliminary sensitivity analysis allows to verify that 10 zones are a convenient number for a good compromise between the computational effort and the description accuracy. The multi-zone predictions are then compared with the CFD ones to find the effective turbulence parameters, with the aim to describe the near-wall phenomena, both in a reactive and non-reactive cases.

In this work a multilevel CFD analysis have been applied for the design of an intake air-box with improved characteristics of noise reduction and fluid dynamic response. The approaches developed and applied for the optimization process range from the 1D to fully 3D CFD simulation, exploring hybrid approaches based on the integration of a 1D model with quasi-3D and 3D tools. In particular, the quasi-3D strategy is exploited to investigate several configurations, tailoring the best trade-off between noise abatement at frequencies below 1000 Hz and optimization of engine performances. Once the best configuration has been defined, the 1D-3D approach has been adopted to confirm the prediction carried out by means of the simplified approach, studying also the impact of the new configuration on the engine performances.

Diesel engine performances are strictly correlated to the fluid dynamic characteristics of the injection system. Actual Diesel engines employ injector characterized by micro-orifices operating at injection pressure till 20MPa. These main injection characteristics resulted in the critical relation between engine performance and injector hole shape. In the present study, the authors' attention was focused on the hole geometry influence on the main injector fluid dynamic characteristics. At this purpose, three different nozzle hole shapes were considered: cylindrical, k, and ks nozzle shapes. Because of the lack of information available about ks-hole real geometry, firstly it was completely characterized by the combined use of two non-destructive techniques. Secondly, all the three nozzle layouts were characterized from the fluid dynamic point of view by a fully transient CFD multiphase simulation methodology previously validated by the authors against experimental results.

The Selective Catalytic Reduction (SCR) system installed on the exhaust line is currently widely used on Diesel heavy-duty trucks and it is considered a promising technique for light and medium duty trucks, large passenger cars and off-highway vehicles, to fulfill future emission legislation. Some vehicles of these last categories, equipped with SCR, have been already put on the market, not only in the US, where the emission legislation on Diesel vehicles is more restrictive, but also in Europe, demonstrating to be already compliant with the upcoming Euro 6. Moreover, new and more stringent emission regulations and homologation cycles are being proposed all over the world, with a consequent rapidly increasing interest for this technology. As a matter of fact, a physical model of the Diesel Exhaust Fluid (DEF) supply system is very useful, not only during the product development phase, but also for the implementation of the on-board real-time controller.

In the next years, the upcoming emission legislations are expected to introduce further restrictions on the admittable level of pollutants from vehicles measured on homologation cycles and real drive tests. In this context, the strict control of pollutant emissions at the cold start will become a crucial point to comply with the new regulation standards. This will necessarily require the implementation of novel strategies to speed-up the light-off of the reactions occurring in the after-treatment system, since the cold start conditions are the most critical one for cumulative emissions. Among the different possible technological solutions, this paper focuses on the evaluation of the potential of a burner system, which is activated before the engine start. The hypothetical burner exploits the lean combustion of an air-gasoline mixture to generate a high temperature gas stream which is directed to the catalyst section promoting a fast heating of the substrate.

The selective catalytic reduction has seen widespread adoption as the best technology to reduce the NOx emissions from internal combustion engines, particularly for Diesels. This technology uses ammonia as a reducing agent, which is obtained injecting an ammonia carrier into the exhaust gas stream. The dosing of the ammonia carrier, usually AdBlue, is the major concern during the design and engine calibration phases, since the interaction between the injected liquid and the components of the exhaust system can lead to the undesired formation of solid deposits. To avoid this, the thermal and kinematic interaction between the spray and the components of the after treatment system (ATS) must be modeled accurately. In this work, the authors developed a Conjugate Heat Transfer (CHT) framework to model the kinetic and thermal interaction among the spray, the eventual liquid layer and the pipe walls.

Modeling combustion of transportation fuels remains a difficult task due to the extremely large number of species constituting commercial gasoline and diesel. However, for this purpose, multi-component surrogate fuel models with a reduced number of key species and dedicated reaction subsets can be used to reproduce the physical and chemical traits of diesel and gasoline, also allowing to perform CFD calculations. Recently, a detailed surrogate fuel kinetic model, named C3 mechanism, was developed by merging high-fidelity sub-mechanisms from different research groups, i.e. C0-C4 chemistry (NUI Galway), linear C6-C7 and iso-octane chemistry (Lawrence Livermore National Laboratory), and monocyclic aromatic hydrocarbons (MAHs) and polycyclic aromatic hydrocarbons (PAHs) (ITV-RWTH Aachen and CRECK modelling Lab-Politecnico di Milano).

Internal combustion engines are the primary transportation mover for today society and they will likely continue to be for decades to come. Hybridization is the most common solution to reduce the petrol-fuels consumption and to respect the new raw emission limits. The gasoline engines designed for running together with an electric motor need to have a very high thermal efficiency because they must work at high loads, where engine thermal efficiency is close to the maximum one. Therefore, the technical solutions bringing to thermal efficiency enhancement were adopted on HVs (Hybrid Vehicles) prior to conventional vehicles. In these days, these solutions are going to be adopted on conventional vehicles too. The purpose of this work was to trace development guidelines useful for engine designers, based on the target power and focused on the maximization of the engine thermal efficiency, following the engine rightsizing concept.

This work focuses on the development and validation of a data-driven model capable of predicting the maximum in-cylinder pressure during the operation of an internal combustion engine, with the least possible computational effort. The model is based on two parameters, one that represents engine load and another one the combustion phase. Experimental data from four different gasoline engines, two turbocharged Gasoline Direct Injection Spark Ignition, a Naturally Aspirated SI and a Gasoline Compression Ignition engine, was used to calibrate and validate the model. Some of these engines were equipped with technologies such as Low-Pressure Exhaust Gas Recirculation and Water Injection or a compression ignition type of combustion in the case of the GCI engine. A vast amount of engine points were explored in order to cover as much as possible of the operating range when considering automotive applications and thus confirming the broad validity of the model.

In recent years, the increase of gasoline fuel injection pressure is a way to improve thermal efficiency and lower engine-out emissions in GDI homogenous combustion concept. The challenge of controlling particulate formation as well in mass and number concentrations imposed by emissions regulations can be pursued improving the mixture preparation process and avoiding mixture inhomogeneity with ultra-high injection pressure values up to 100 MPa. The increase of the fuel injection pressure in GDI homogeneous systems meets the demand for increased injector static flow, while simultaneously improves the spray atomization and mixing characteristics with consequent better combustion performance. Few studies quantify the effects of high injection pressure on transient gasoline spray evolution. The aim of this work was to simulate with OpenFOAM the spray morphology of a commercial gasoline injected in a constant volume vessel by a prototypal GDI injector.

The reliable prediction of pollutant emissions generated by IC engine powertrains during the WLTP driving cycle is a key aspect to test and optimize different configurations, in order to respect the stringent emission limits. This work describes the application of an integrated modeling tool in a co-simulation environment, coupling a 1D fluid dynamic code for engine simulation with a specific numerical code for aftertreatment modelling by means of a robust numerical approach, to achieve a complete methodology for detailed simulations of driving cycles. The main goal is to allow an accurate 1D simulation of the unsteady flows along the intake and exhaust systems and to apply advanced thermodynamic combustion models for the calculation of cylinder-out emissions.

Modern turbo-charged downsized engines reach high values of specific power, causing a significant increase of the exhaust gas temperature. Such parameter plays a key role in the overall powertrain environmental impact because it strongly affects both the catalyst efficiency and the turbine durability. In fact, common techniques to properly manage the turbine inlet gas temperature are based on mixture enrichment, which causes both a steep increase in specific fuel consumption and a decrease of catalyst efficiency. At the test bench, exhaust gas temperature is typically measured using thermocouples that are not available for on-board application, and such information is processed to calibrate open-loop look-up-tables. A real-time, reliable, and accurate exhaust temperature model would then represent a strategic tool for improving the performance of the engine control system.

Cycle-To-Cycle Variability (CCV) must be properly considered when modeling the ignition process in SI engines operating with ultra-lean mixtures. In this work, a strategy to model the impact of the ignition type on the CCV was developed using the RANS approach for turbulence modelling, performing multi-cycle simulations for the power-cycle only. The spark-discharge was modelled through a set of Lagrangian particles, introduced along the sparkgap and interacting with the surrounding Eulerian gas flow. Then, at each discharge event, the velocity of each particle was modified with a zero-divergence perturbation of the velocity field with respect to average conditions. Finally, the particles velocity was evolved according to the Simplified Langevin Model (SLM), which keeps memory of the initial perturbation and applies a Wiener process to simulate the stochastic interaction of each channel particle with the surrounding gas flow.