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This paper focuses on the spray and atomization characteristics of a Dual-Fuel Injector (DFI) which includes a primary and a secondary fuel inlet. Three injectors were analyzed in this study. Apart from the DFI, two conventional diesel injectors were tested as baselines for comparison - a piezo-electric and a solenoid injector. The rail pressures ranged from 200 - 500 bar for the conventional injectors. The DFI was tested first as a single-fuel injector (by sealing the secondary inlet) at pressures ranging from 100 - 300 bar, and then in its dual-fuel mode with the primary inlet pressure ranging from 100 - 300 bar, and the secondary inlet at 25 bar higher than the primary pressure. Injection duration of 0.5 ms was chosen for the experiment. High-speed Mie scattering images were recorded to capture the spray evolution. Phase Doppler Anemometry (PDA) measurements were conducted at different locations in the spray for the acquisition of droplet sizes and velocity distributions.