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A broad range of diesel, kerosene, and gasoline-like fuels has been tested in a single-cylinder diesel engine optimized for advanced combustion performance. These fuels were selected in order to better understand the effects of ignition quality, volatility, and molecular composition on engine-out emissions, performance, and noise levels. Low-level biofuel blends, both biodiesel (FAME) and ethanol, were included in the fuel set in order to test for short-term advantages or disadvantages. The diesel engine optimized in Part 1 of this study included cumulative engine hardware enhancements that are likely to be used to meet Euro 6 emissions limits and beyond, in part by operating under conditions of Homogeneous Charge Compression Ignition (HCCI), at least over some portions of the speed and load map.

Two single-cylinder diesel engines were optimised for advanced combustion performance by means of practical and cumulative hardware enhancements that are likely to be used to meet Euro 5 and 6 emissions limits and beyond. These enhancements included high fuel injection pressures, high EGR levels and charge cooling, increased swirl, and a fixed combustion phasing, providing low engine-out emissions of NOx and PM with engine efficiencies equivalent to today's diesel engines. These combustion conditions approach those of Homogeneous Charge Compression Ignition (HCCI), especially at the lower part-load operating points. Four fuels exhibiting a range of ignition quality, volatility, and aromatics contents were used to evaluate the performance of these hardware enhancements on engine-out emissions, performance, and noise levels.

Fuels derived from biomass will most likely contain oxygen due to the high amount of hydrogen needed to remove oxygen in the production process. Today, alcohol fuels (e. g. ethanol) are well understood for spark ignition engines. The Institute for Combustion Engines at RWTH Aachen University carried out a fuel investigation program to explore the potential of alcohol fuels as candidates for future compression ignition engines to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. The soot formation and oxidation process when using alcohol fuels in diesel engines is not yet sufficiently understood. Depending on the chain length, alcohol fuels vary in cetane number and boiling temperature. Decanol possesses a diesel-like cetane number and a boiling point in the range of the diesel boiling curve. Thus, decanol was selected as an alcohol representative to investigate the influence of the oxygen content of an alcohol on the combustion performance.

This research describes the potential to adopt detailed chemical kinetics for practical and potential future fuels using tri-component surrogate mixtures capable of simulating fuel octane “sensitivity” . Since the combustion characteristics of modern fuels are routinely measured using the RON and MON of the fuel, a methodology to generate detailed chemical kinetic mechanisms for these fuels based on these data is presented. Firstly, a novel correlation between various tri-component blends (comprised of i-octane, n-heptane and toluene) and fuel RON and MON was obtained by carrying out standard octane tests. Secondly, a chemical kinetic mechanism for tri-component fuels was validated using a Stochastic Reactor Model (SRM) suite, an in-cylinder engine combustion simulator, and a series of engine experiments conducted in HCCI operating mode.