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In this paper, we studied the accuracy of computational modeling of the ignition of a pilot injectionin the Sandia National Laboratories (SNL) light-duty optical engine facility, using the physical properties of a cetane/iso-cetane Diesel Primary Reference Fuel (DPRF) mixture and the reaction kinetics of a well-validated mechanism for primary reference fuels. Local fuel-air equivalence ratio measurements from fuel tracer based planar laser-induced fluorescence (PLIF) experiments were used to compare the mixture formation predictions with KIVA-ERC-based simulations. The effects of variations in injection mass from 1 mg to 4 mg, in-cylinder swirl ratio, and near-TDC temperatures on non-combusting mixture preparation were analyzed, to assess the accuracy of the model in capturing average jet behavior, despite its inability to model the non-negligible jet-by-jet variations seen in the experiments.

A measurement technique is described which permits quantitative, multi-point, in-cylinder fluid composition measurements in an internal combustion engine. The technique is based on spontaneous Raman scattering with broadband signal collection, and provides simultaneous determination of the mole fractions of H2O, CO2, N2, O2, and fuel (C3H8). Calibration and data reduction procedures which largely eliminate interference between the signals from the various species are discussed. Mean mole fractions obtained in an optical access engine from the beginning of the intake stroke to the end of the compression stroke are reported. The mean mole fractions of the individual species are used to obtain independent estimates of the mean mole fraction of burnt residual gases, which, in turn, are used to evaluate the accuracy and consistency of the data. An over-prediction of the CO2 mole fraction in hot exhaust gases is found to be the most significant shortcoming of the technique.