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A zero-dimensional cycle simulation model coupled with a chemical equilibrium model and a two-zone combustion model has been extended to predict nitric oxide formation and emissions from spark-ignited, lean-burn natural gas engines. It is demonstrated that using the extended Zeldovich mechanism alone, the NOx emissions from an 8.1-liter, 6-cylinder, natural gas engine were significantly under predicted. However, by combining the predicted NOx formation from both the extended Zeldovich thermal NO and the Fenimore prompt NO mechanisms, the NOx emissions were predicted with fair accuracy over a range of engine powers and lean-burn equivalence ratios. The effect of injection timing on NOx emissions was under predicted. Humidity effects on NOx formation were slightly under predicted in another engine, a 6.8-liter, 6-cylinder, natural gas engine. Engine power was well predicted in both engines, which is a prerequisite to accurate NOx predictions.

A technology path has been identified for development of a high efficiency, durable, gasoline engine, targeted at achieving performance and emissions levels necessary to meet heavy-duty, on-road standards of the foreseeable future. Initial experimental and numerical results for the proposed technology concept are presented. This work summarizes internal research efforts conducted at Southwest Research Institute. An alternative combustion system has been numerically and experimentally examined. The engine utilizes gasoline as the fuel, with a combination of enabling technologies to provide high efficiency operation at ultra-low emissions levels. The concept is based upon very highly-dilute combustion of gasoline at high compression ratio and boost levels. Results from the experimental program have demonstrated engine-out NOx emissions of 0.06 g/hp/hr, at single-cylinder brake thermal efficiencies (BTE) above thirty-four percent.

Twelve different hole shapes for diesel injector tips were characterized with DF-2 diesel fuel for spray cone angle over a range of injection pressures from 21 MPa (3 kpsi) to 69 MPa (10 kpsi). A baseline and two of the most radical designs were also tested for drop-size distribution and liquid volume fraction (liquid fuel-air ratio) over a range of pressures from 41 MPa (6 kpsi) to 103 MPa (15 kpsi). All hole shapes were circular in cross-section with minimum diameters of 0.4 mm (0.016 in.), and included converging and diverging hole shapes. Overall hole lengths were constant at 2.5 mm (0.098 in.), for an L/d of 6.2. However, the effective L/d may have been less for some of the convergent and divergent shapes.

High-speed movie films, and laser-diffraction drop sizing were used to evaluate the structure, penetration rate, cone angle, and drop size distribution of diesel sprays in a constant volume pressure vessel. As further means of evaluating the data, comparisons are made between the film measurements, and calculations from a dense gas jet model. In addition to the high-speed film data that describes the overall structure of the spray as a function of time, a laser diffraction instrument was used to measure drop size distribution through a cross-section of the spray. In terms of the growth of the total spray volume (a rough measure of the amount of air entrained in the spray), spray impingement causes an initial delay, but generally the same overall growth rate as an equivalent unimpeded spray. Agreement between measurements and calculations is excellent for a diesel spray with a 0.15 mm D orifice and relatively high injection pressures.